IP Library Granted Patent US 11,664,413
Granted Patent B2
US 11,664,413 · App. 17/142,813 · Granted May 30, 2023

Semiconductor device including multilayer stack including seed layer and high-k dielectric layer

Inventors: Dong Ik Suh (Icheon-si, KR); Se Ho Lee (Icheon-si, KR)
Assignee: SK hynix Inc.
H01L28/40H01L29/513H01L29/517H10B12/315
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Quick Facts
Patent No.
US 11,664,413
App. No.
17/142,813
Granted
May 30, 2023
Kind
B2
Abstract

A semiconductor device may include: a first electrode; a second electrode; and a multilayer stack that is interposed between the first electrode and the second electrode and includes a seed layer and a high-k dielectric layer, wherein each of the seed layer and the high-k dielectric layer may have a rocksalt crystal structure, and wherein the high-k dielectric layer may exhibit a dielectric constant (k) of fifty (50) or higher.

Claims (61)

1. A semiconductor device, comprising:

a first electrode;

a second electrode; and

a multilayer stack that is interposed between the first electrode and the second electrode and includes a seed layer and a high-k dielectric layer,

wherein each of the seed layer and the high-k dielectric layer has a rocksalt crystal structure,

wherein the high-k dielectric layer exhibits a dielectric constant (k) of fifty (50) or higher,

wherein the multilayer stack further includes an additional high-k dielectric layer disposed over the high-k dielectric layer, and

wherein the additional high-k dielectric layer exhibits a dielectric constant (k) lower than the high-k dielectric layer.

2. The semiconductor device of claim 1 , wherein the seed layer includes a first seed layer and a second seed layer, wherein the first seed layer includes magnesium oxide (MgO) having a rocksalt crystal structure, and the second seed layer is disposed over the first seed layer and includes beryllium oxide (BeO) having a rocksalt crystal structure.

3. The semiconductor device of claim 1 , wherein the seed layer includes beryllium-magnesium oxide (BexMg1-xO, 0<x<0.5) having a rocksalt crystal structure.

4. The semiconductor device of claim 1 , wherein the seed layer exhibits a dielectric constant (k) of fifteen (15) to twenty (20).

5. The semiconductor device of claim 1 , wherein the high-k dielectric layer includes BeO having a rocksalt crystal structure that is stable under room temperature and atmospheric pressure.

6. The semiconductor device of claim 1 , wherein the high-k dielectric layer includes a single-layer structure or a multilayer structure containing two or more layers,

wherein, when the high-k dielectric layer includes the multilayer structure, each layer included in the multilayer structure includes BeO having a rocksalt crystal structure, and

wherein the high-k dielectric layer including the multilayer structure has a thickness greater than the high-k dielectric layer including the single-layer structure.

7. The semiconductor device of claim 1 , further comprising an interface layer disposed between the second electrode and the multilayer stack.

8. A semiconductor device, comprising:

a first electrode;

a second electrode; and

a multilayer stack that is interposed between the first electrode and the second electrode and includes a seed layer and a high-k dielectric layer structure,

wherein the high-k dielectric layer structure includes at least two high-k dielectric layers and at least one strain applying layer,

wherein the multilayer stack further includes an additional high-k dielectric layer disposed over the high-k dielectric layer that is adjacent to the second electrode from among the at least two high-k dielectric layers,

wherein the additional high-k dielectric layer exhibits a dielectric constant (k) that is lower than the dielectric constant (k) of the at least two high-k dielectric layers, and

wherein the strain applying layer is interposed between adjacent high-k dielectric layers.

9. The semiconductor device of claim 8 , wherein the strain applying layer is configured to stabilize a rocksalt crystal structure of the at least two high-k dielectric layers by applying strain to the at least two high-k dielectric layers.

10. The semiconductor device of claim 8 , wherein the strain applying layer includes magnesium oxide (MgO), beryllium-magnesium oxide (BexMg1-xO, 0<x<0.5), or a combination thereof.

11. The semiconductor device of claim 8 , wherein the seed layer includes a first seed layer and a second seed layer, wherein the first seed layer includes magnesium oxide (MgO) having a rocksalt crystal structure, and the second seed layer is disposed over the first seed layer and includes beryllium oxide (BeO) having a rocksalt crystal structure.

12. The semiconductor device of claim 8 , wherein the seed layer includes beryllium-magnesium oxide (BexMg1-xO, 0<x<0.5) having a rocksalt crystal structure.

13. The semiconductor device of claim 8 , wherein the seed layer exhibits a dielectric constant (k) of 15 to 20.

14. The semiconductor device of claim 8 , wherein each of the at least two high-k dielectric layers includes beryllium oxide (BeO) having a rocksalt crystal structure that is stable under room temperature and atmospheric pressure.

15. The semiconductor device of claim 8 , wherein each of the at least two high-k dielectric layers exhibits a dielectric constant (k) of fifty (50) or higher.

16. The semiconductor device of claim 8 , further comprising an interface layer disposed between the second electrode and the multilayer stack.

17. A semiconductor device, comprising:

a first electrode;

a second electrode; and

a multilayer stack that is interposed between the first electrode and the second electrode and includes a seed layer and a high-k dielectric layer,

wherein the seed layer includes beryllium-magnesium oxide (Be x Mg 1-x O, 0<x<0.5) having a rocksalt crystal structure, and

wherein the high-k dielectric layer includes BeO having a rocksalt crystal structure that is stable under room temperature and atmospheric pressure and exhibits a dielectric constant (k) of fifty (50) or higher.

18. The semiconductor device of claim 17 , wherein the seed layer includes a first seed layer and a second seed layer, wherein the first seed layer includes magnesium oxide (MgO) having a rocksalt crystal structure, and the second seed layer is disposed over the first seed layer and includes beryllium oxide (BeO) having a rocksalt crystal structure.

19. The semiconductor device of claim 17 , wherein the seed layer exhibits a dielectric constant (k) of fifteen (15) to twenty (20).

20. The semiconductor device of claim 17 , wherein the high-k dielectric layer includes a single-layer structure or a multilayer structure containing two or more layers,

wherein, when the high-k dielectric layer includes the multilayer structure, each layer included in the multilayer structure includes BeO having a rocksalt crystal structure, and

wherein the high-k dielectric layer including the multilayer structure has a thickness greater than the high-k dielectric layer including the single-layer structure.

21. The semiconductor device of claim 17 , wherein the multilayer stack further includes an additional high-k dielectric layer disposed over the high-k dielectric layer.

22. The semiconductor device of claim 21 , wherein the additional high-k dielectric layer exhibits a dielectric constant (k) lower than the high-k dielectric layer.

23. The semiconductor device of claim 17 , further comprising an interface layer disposed between the second electrode and the multilayer stack.

24. A semiconductor device, comprising:

a first electrode;

a second electrode; and

a multilayer stack that is interposed between the first electrode and the second electrode and includes a seed layer and a high-k dielectric layer structure,

wherein the seed layer includes beryllium-magnesium oxide (Be x Mg 1-x O, 0<x<0.5) having a rocksalt crystal structure,

wherein the high-k dielectric layer structure includes at least two high-k dielectric layers and at least one strain applying layer,

wherein each of the at least two high-k dielectric layers includes beryllium oxide (BeO) having a rocksalt crystal structure that is stable under room temperature and atmospheric pressure, and

wherein the strain applying layer is interposed between adjacent high-k dielectric layers.

25. The semiconductor device of claim 24 , wherein the strain applying layer is configured to stabilize a rocksalt crystal structure of the at least two high-k dielectric layers by applying strain to the at least two high-k dielectric layers.

26. The semiconductor device of claim 24 , wherein the strain applying layer includes magnesium oxide (MgO), beryllium-magnesium oxide (Be x Mg 1-x O, 0<x<0.5), or a combination thereof.

27. The semiconductor device of claim 24 , wherein the seed layer exhibits a dielectric constant (k) of 15 to 20.

28. The semiconductor device of claim 24 , wherein each of the at least two high-k dielectric layers exhibits a dielectric constant (k) of fifty (50) or higher.

29. The semiconductor device of claim 24 , wherein the multilayer stack further includes an additional high-k dielectric layer disposed over the high-k dielectric layer that is adjacent to the second electrode from among the at least two high-k dielectric layers.

30. The semiconductor device of claim 29 , wherein the additional high-k dielectric layer exhibits a dielectric constant (k) that is lower than the dielectric constant (k) of the at least two high-k dielectric layers.

31. The semiconductor device of claim 24 , further comprising an interface layer disposed between the second electrode and the multilayer stack.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 6, 2021
From: SUH, DONG IK; LEE, SE HO
To: SK HYNIX INC.
Reel/Frame 054913/0847 →
Priority Claims (1)
KR 10-2020-0078253 · Jun 26, 2020 · national
Continuity (1)
Related Publication 20210408222A1 · Dec 30, 2021