IP Library Granted Patent US 11,319,504
Granted Patent B2
US 11,319,504 · App. 17/146,396 · Granted May 3, 2022

Lubricant with nanoparticulate additive

Inventors: Craig Bailey (Rapid City, SD); Greg Christensen (Hermosa, SD); Haiping Hong (Rapid City, SD)
Assignees: Novum Nano LLC; South Dakota Board of Regents
C10M169/04C10M125/02C10M125/26B82Y30/00B82Y40/00C10M2201/041C10M2201/082C10M2201/14C10M2203/003C10N2020/06C10N2040/25C10N2070/02
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Quick Facts
Patent No.
US 11,319,504
App. No.
17/146,396
Granted
May 3, 2022
Kind
B2
Abstract

An engine oil additive includes carbon nanotubes and boron nitride particulates dispersed within a fluid. The additive is configured to be mixed with a quantity of oil such that the quantity of oil has a concentration from 0.05 to 0.5 grams of carbon nanotubes and of boron nitride particulates per quart of oil to improve the lubricity of the oil. The additive improves the horsepower and torque of the engine while reducing fuel consumption. The carbon nanotubes have an —OH functionalized exterior surface. The carbon nanotubes have a diameter from 1 nanometer to 50 nanometers and have a length from 1 micron to 1000 microns. The boron nitride particulates are hex-boron nitride structures having an average size from 30 nanometers to 500 nanometers.

Claims (23)

1. A fluid comprising:

an oil;

a plurality of carbon nanotubes dispersed within the oil and each having a diameter between 1 nanometer and 80 nanometers, wherein at least 0.76 percent of the plurality of carbon nanotubes have OH functionalized surfaces; and

a plurality of boron nitride particulates dispersed within the oil, wherein each of the plurality of boron nitride particulates are separate from each of the plurality of carbon nanotubes and have an average particle size between 50 nanometers and 90 nanometers; and

wherein a concentration of the plurality of carbon nanotubes is between 0.08 grams and 0.4 grams per 946 milliliters of the oil and wherein a concentration of the plurality of boron nitride particulates is between 0.08 grams and 0.4 grams per 946 milliliters of the oil.

2. The fluid of claim 1 wherein at least some of the plurality of carbon nanotubes are multi-walled carbon nanotubes.

3. The fluid of claim 1 wherein an average length of the plurality of carbon nanotubes is between 1 micron and 1000 microns.

4. The fluid of claim 1 wherein the boron nitride particulates are hex-boron nitride, cubic boron nitride or wurtzite boron nitride particulates.

5. A concentrate comprising:

a fluid;

a plurality of carbon nanotubes dispersed within the fluid, wherein each carbon nanotube of the plurality of carbon nanotubes has a diameter between 1 nanometer and 80 nanometers and wherein at least 0.76 percent of the plurality of carbon nanotubes have OH functionalized surfaces; and

a plurality of boron nitride particulates dispersed within the fluid, wherein each of the plurality of boron nitride particulates are separate from each of the plurality of carbon nanotubes, and wherein the plurality of boron nitride particulates have an average particle size between 50 nanometers and 90 nanometers; and

wherein the concentrate is configured to be mixed with a predetermined quantity of oil such that the mixture of the predetermined quantity of oil and the concentrate has a carbon nanotube concentration between 0.08 grams and 0.4 grams per 946 milliliters of the oil and a boron nitride particulate concentration between 0.08 grams and 0.4 grams per 946 milliliters of the oil.

6. The concentrate of claim 5 wherein at least some of the plurality of carbon nanotubes are multi-walled carbon nanotubes.

7. The concentrate of claim 5 wherein an average length of the plurality of carbon nanotubes is between 1 micron and 1000 microns.

8. The concentrate of claim 5 wherein each of the boron nitride particulates of the plurality of boron nitride particulates are hex-boron nitride, cubic boron nitride or wurtzite boron nitride particulates.

9. An engine oil additive comprising:

a plurality of unitary carbon nanotubes each having a diameter between 1 nanometer and 80 nanometers, wherein at least 0.76 percent of the plurality of carbon nanotubes have an OH functionalized surface; and

a plurality of unitary boron nitride particulates having an average particle size between 50 nanometers and 90 nanometers;

wherein the additive is configured to be mixed with a predetermined quantity of engine oil such that the mixture has a carbon nanotube concentration between 0.08 grams and 0.4 grams per 946 milliliters of the engine oil and a boron nitride particulate concentration between 0.08 grams and 0.4 grams per 946 milliliters of the engine oil.

10. The engine oil additive of claim 9 wherein at least some of the plurality of carbon nanotubes are multi-walled carbon nanotubes.

11. The engine oil additive of claim 9 wherein an average length of the plurality of carbon nanotubes is between 1 micron and 1000 microns.

12. The engine oil additive of claim 9 wherein each of the boron nitride particulates of the plurality of boron nitride particulates are hex-boron nitride, cubic boron nitride or wurtzite boron nitride particulates.

Assignments (4)
CONFIRMATORY LICENSE Recorded Aug 10, 2022
From: NOVUM NANO LLC.
To: THE GOVERNMENT OF THE UNITED STATES AS REPRESENTED BY THE SECRETARY OF THE AIR FORCE
Reel/Frame 061132/0236 →
CORRECTIVE ASSIGNMENT TO CORRECT THE EXPUNGED THIRD INVENTOR'S NAME PREVIOUSLY RECORDED AT REEL: 059160 FRAME: 0860. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT . Recorded Mar 18, 2022
From: BAILEY, CRAIG; CHRISTENSEN, GREG
To: NOVUM NANO LLC
Reel/Frame 059436/0635 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 3, 2022
From: HONG, HAIPING
To: SOUTH DAKOTA BOARD OF REGENTS
Reel/Frame 059160/0752 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 3, 2022
From: BAILEY, CRAIG; CHRISTENSEN, GREG; HONG, HAIPING
To: NOVUM NANO LLC
Reel/Frame 059160/0860 →
Continuity (2)
Provisional Application 63039862 · Jun 16, 2020
Related Publication 20210388285A1 · Dec 16, 2021