Process for producing geothermal power, selective removal of silica and iron from brines, and improved injectivity of treated brines
This invention relates to a method for producing geothermal power using geothermal brines while producing a reduced silica and iron brine having improved injectivity. The resulting compositions include a composition with reduced silica, iron, and lithium having reduced quantity of total suspended solids.
1. A method for producing geothermal power using geothermal brines and producing a brine with reduced silica and iron concentrations having improved injectivity, the method comprising:
providing a geothermal brine comprising silica and iron (II);
flashing the geothermal brine to generate electrical power, wherein the flashing produces precipitated silica and a flashed brine having a reduced silica concentration;
separating the precipitated silica from the flashed brine and returning the precipitated silica to the flashing step;
reducing a temperature of the flashed brine to less than 150° C.;
oxidizing the flashed brine to oxidize iron (II) to iron (III) to produce an oxidized brine, wherein the oxidized brine comprises less than 20 ppm of silica and less than 20 ppm of iron;
adding a base to the oxidized brine to react the iron (III) and silica to produce precipitated silica-iron solids;
separating the precipitated silica-iron solids from the oxidized brine, wherein the oxidized brine comprises less than 20 ppm of silica and less than 20 ppm of iron; and
injecting the oxidized brine underground.
2. The method of claim 1 , further comprising removing lithium from the oxidized brine before injecting the oxidized brine underground.
3. The method of claim 1 , further comprising removing manganese from the oxidized brine before injecting the oxidized brine underground.
4. The method of claim 1 , further comprising removing zinc from the oxidized brine before injecting the oxidized brine underground.
5. The method of claim 1 , wherein the flashing a geothermal brine containing silica and iron to generate electrical power step is performed using a crystallizer reactor clarifier process.
6. The method of claim 1 , wherein the flashing a geothermal brine containing silica and iron to generate electrical power step is performed using a pH modification flashing process.
7. The method of claim 1 , wherein the base comprises NaOH, Ca(OH) 2 , or limestone.