IP Library Granted Patent US 12,521,320
Granted Patent B2
US 12,521,320 · App. 17/151,897 · Granted Jan 13, 2026

Oral care compositions comprising fluoride ions

Inventors: Arif Ali Baig (Mason, OH); Min Mao (Deerfield Township, OH); Gregory Charles Gordon (Loveland, OH); Melissa Cherie Payne (West Chester, OH); Holly Balasubramanian Rauckhorst (Ft. Thomas, KY); Paul Albert Sagel (Maineville, OH); Jeanette Marie Swartz (Loveland, OH); Paul Dennis Trokhan (Hamilton, OH); Brian Patrick Croll (Hamilton, OH); Dinah Achola Nyangiro (Mason, OH); Samuel James St. John (Cincinnati, OH)
Assignee: The Procter & Gamble Company
A61K8/0204A61K8/046A61K8/19A61K8/20A61K8/21A61K8/25A61K8/27A61K8/345A61K8/416A61K8/442A61K8/463A61K8/60A61K8/8129A61Q11/00A46B2200/1066A61K8/24A61K8/347A61K8/36A61K2800/28A61K2800/882A61K2800/92A61K2800/95
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Quick Facts
Patent No.
US 12,521,320
App. No.
17/151,897
Granted
Jan 13, 2026
Kind
B2
Abstract

Oral care compositions and/or unit-dose oral care compositions with a fluoride ion source. Oral care compositions and/or unit-dose oral care compositions with a high average fluoride ion uptake. Oral care compositions with one or more web forming materials, a calcium ion source, and a fluoride ion source with a high average fluoride uptake.

Claims (25)

1 . A solid unit-dose oral care composition comprising:

(a) a fibrous composition comprising a polyvinyl alcohol polymer and a fluoride ion source comprising stannous fluoride, wherein the fibrous composition has a mean void volume of about 15% to about 75%; and

(b) an abrasive disposed in a nonfibrous composition or a second fibrous composition that is free of fluoride,

wherein the solid unit dose oral care composition has a dissolution time of about 50 seconds to about 250 seconds.

2 . The unit-dose oral care composition of claim 1 , wherein the fluoride ion source comprises sodium fluoride, sodium monofluorophosphate, amine fluoride, or combinations thereof.

3 . The unit-dose oral care composition of claim 1 , wherein the composition comprises from about 0.01% to about 10%, by weight of the unit-dose oral care composition, of metal selected from tin, zinc and combinations thereof.

4 . A solid unit-dose oral care composition comprising:

(a) a first fibrous composition layer comprising fluoride;

(b) a second fibrous composition layer comprising fluoride, wherein at least one of the first or second fiber compositions comprise a polymer; and

(c) a non-fibrous composition disposed between the first and second fibrous composition layers, wherein the non-fibrous composition comprises a calcium abrasive, and

wherein the first and second fibrous composition layers are bonded together along an edge to encase the non-fibrous composition.

5 . The unit-dose oral care composition of claim 1 , wherein the unit-dose oral care composition has from about 2% to about 10%, by weight of the unit-dose oral care composition, of the fluoride ion source.

6 . The unit-dose oral care composition of claim 1 , wherein the unit-dose oral care composition has at least about a 1500 ppm fluoride uptake.

7 . The unit-dose oral care composition of claim 1 , wherein the unit-dose oral care composition comprises from about 0.01% to about 40%, by weight of the unit-dose oral care composition, of calcium selected from calcium abrasive, calcium salt, and combinations thereof.

8 . The unit-dose oral care composition of claim 7 , wherein the unit-dose oral care composition has at least about a 1000 ppm average fluoride uptake.

9 . The unit-dose oral care composition of claim 7 , wherein the unit-dose oral care composition has at least about a 2000 ppm average fluoride uptake.

10 . The unit-dose oral care composition of claim 1 , wherein the unit-dose oral care composition comprises from about 0.01% to less than 10%, by weight of the unit-dose oral care composition, of the polyvinyl alcohol.

11 . The solid unit-dose oral care composition of claim 1 , wherein the abrasive comprises calcium and wherein the solid unit-dose oral care composition has an average fluoride uptake of at least about 1000 ppm.

12 . The unit-dose oral care composition of claim 11 , further comprising calcium salt.

13 . The unit-dose oral care composition of claim 11 , wherein the unit-dose oral care composition comprises from about 10% to about 50%, by weight of the unit-dose oral care composition, of the polyvinyl alcohol.

14 . The unit-dose oral care composition of claim 11 , wherein the unit-dose oral care composition comprises from about 0.01% to about 10%, by weight of the unit-dose oral care composition, of the fluoride ion source.

15 . The unit-dose oral care composition of claim 11 , wherein the unit-dose oral care composition comprises from about 0.01% to about 40%, by weight of the unit-dose oral care composition, of the calcium.

16 . The unit-dose oral care composition of claim 11 , wherein the fluoride comprises sodium fluoride, sodium monofluorophosphate, amine fluoride, or combinations thereof.

17 . The unit-dose oral care composition of claim 4 , wherein the polymer comprises starch, polyvinyl alcohol, polyvinyl pyrrolidone, polyethylene oxide, carboxymethylcellulose, polyacrylic acid, polyvinyl ether maleic acid copolymer, or combinations thereof.

18 . The solid unit dose oral care composition of claim 4 , wherein the first and second fibrous composition layers are pressure bonded.

Continuity (6)
Continuation 16411181 · May 14, 2019
Provisional Application 62671072 · May 14, 2018
Provisional Application 62671078 · May 14, 2018
Provisional Application 62671083 · May 14, 2018
Provisional Application 62671066 · May 14, 2018
Related Publication 20210137797A1 · May 13, 2021
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