Oxidized mixture of bio-based material and asphalt, a bio-based asphaltic material, and methods of making the same
A method of forming an asphalt mixture can include mixing a bio-source material and a bitumen source to form a bitumen mixture. The bitumen mixture can be mixed with a catalyst to form the asphalt mixture. Particles can be added to the asphalt mixture to form a roofing-grade asphalt mixture. In an embodiment, the bitumen source material can have a softening point of at least approximately 93° C. and a penetration distance no greater than approximately 25 dmm. In another embodiment, the roofing-grade asphalt mixture can have a softening point of at least approximately 104° C., a penetration distance no greater than approximately 12 dmm, a viscosity of at least approximately 3000 cps at a temperature of 204° C., or any combination thereof. The asphalt mixture can be applied to a base material to form a roofing product. The asphalt mixture can be applied as a pavement product.
1. A roofing product comprising:
a base material; and
a roofing-grade asphalt mixture comprises:
a bitumen mixture including a bio-source material and bitumen source material;
a catalyst residue comprising a metal salt, the metal salt comprising the salt of an acid, the acid comprising octanoic acid, 2-ethylhexanoic acid, ethylenediaminetetraacetic acid (EDTA), ethylene glycol tetracetic acid (EGTA), or any combination thereof; and
a filler.
2. The roofing product of claim 1 , wherein the bitumen mixture comprises a portion of the bio-source material being covalently bonded to the bitumen source material.
3. The roofing product of claim 1 , wherein the bitumen source material has a softening point of at least approximately 90° C. and a penetration distance no greater than approximately 30 dmm.
4. The roofing product of claim 1 , wherein the bitumen source material has a softening point of not greater than approximately 110° C., and the penetration distance of the bitumen source material is at least approximately 10 dmm.
5. The roofing product of claim 1 , wherein the bitumen source comprises a petroleum-based asphalt.
6. The roofing product of claim 1 , wherein the roofing-grade asphalt mixture has a softening point of at least approximately 104° C., a penetration distance no greater than approximately 12 dmm, a viscosity of at least approximately 3000 cps at a temperature of 177° C., or any combination thereof.
7. The roofing product of claim 1 , wherein the bio-source material comprises a partially oxidized oil, the oil including cooking oil, vegetable oil, animal oil, recycled cooking oil, recycled vegetable oil, recycled animal fat, modified vegetable oil, modified animal fat, or any combination thereof.
8. The roofing product of claim 1 , wherein the roofing-grade asphalt mixture has a total bitumen content, wherein the bio-source material is at least approximately 5 wt % of the total bitumen content.
9. The roofing product of claim 1 , wherein the roofing-grade asphalt mixture has a total bitumen content, wherein the bio-source material has a content of no greater than approximately 50 wt % of the total bitumen content.
10. The roofing product of claim 1 , wherein at 204° C., the roofing-grade asphalt mixture has a viscosity of at least approximately 3000 cps.
11. The roofing product of claim 1 , wherein at 204° C., the roofing-grade asphalt mixture has a viscosity no greater than approximately 5000 cps.
12. The roofing product of claim 1 , wherein the filler comprise particles.
13. The roofing product of claim 12 , wherein the particles comprise limestone, dolomite, talc, clay, coal fines, gypsum, calcite, fly ash, or any combination thereof.
14. The roofing product of claim 1 , wherein the base material comprises a fiberglass mat, a cellulose-based material, a ceramic base material, or a polymer.
15. The roofing product of claim 1 , wherein the roofing-grade asphalt mixture substantially fills an open structure of the base material.
16. The roofing product of claim 1 , wherein at least 50% of the roofing-grade asphalt material is outside of an open structure of the base material.
17. The roofing product of claim 1 , wherein the roofing-grade asphalt mixture further comprises a plasticizer.
18. The roofing product of claim 1 , wherein the bio-source material comprises unsaturated fatty acids, triglycerides, or a combination thereof.
19. The roofing product of claim 1 , wherein the roofing grade asphalt comprises a reaction product of the bio-source material and a catalyst.
20. The roofing product of claim 1 , wherein the metal of the metal salt comprises cobalt, manganese, zirconium, vanadium, iron, calcium, nickel, copper, zinc, osmium, rhodium, rhenium, hafnium, or any combination thereof.