Lubricant formulations with silicon-containing compounds
A lubricating oil composition including a major amount of a base oil, one or more calcium-containing detergents to provide at least 1000 ppmw of calcium, and one or more silicon-containing compound(s) to provide at least 50 ppmw of silicon to the lubricating oil composition, all based on the total weight of the lubricating oil composition, wherein a ratio of ppmw of silicon provided by the one or more silicon-containing compound(s) to the lubricating oil composition to the ppmw of calcium provided by the one or more calcium-containing detergent(s) to the lubricating oil composition is from 0.02 to 1. Methods of using these compositions and silicon-containing detergents are also described.
1. A lubricating oil composition formulated for use in a turbocharged gasoline direct-injection engine comprising:
greater than 50 wt. % of a base oil of lubricating viscosity, based on a total weight of the lubricating oil composition, and an additive composition prepared by mixing:
a) an amount of one or more overbased calcium sulfonate detergents to provide at least 1200 ppmw to about 2400 ppmw of calcium to the lubricating oil composition, based on the total weight of the lubricating oil composition, and
b) an amount of one or more silicon-containing compound(s) of formula (IA) to provide at least 170 ppmw to about 550 ppmw of silicon to the lubricating oil composition, based on the total weight of the lubricating oil composition:
wherein R 1 , R 2 , R 3 , are each independently selected from an alkyl group comprising from 1 to 20 carbon atoms, and m is an integer from 1 to less than 50; and
wherein a ratio of ppmw of silicon provided by the one or more silicon-containing compound(s) to the lubricating oil composition to the ppmw of calcium provided by the one or more calcium-containing detergent(s) to the lubricating oil composition is at least 0.0389 to 0.1; and
the lubricating oil composition is devoid of a calcium salicylate detergent.
2. The lubricating oil composition of claim 1 , wherein R 1 , R 2 and R 3 are methyl groups.
3. The lubricating oil composition of claim 1 , wherein the compound of the Formula (IA) is a polydimethylsiloxane.
4. The lubricating oil composition of claim 1 , wherein the compound of Formula (IA) has an elemental ratio of hydrogen atoms to silicon atoms of from 6.115 to 9.
5. The lubricating oil composition of claim 1 , wherein the compound of Formula (IA) has an elemental ratio of carbon atoms to silicon atoms of from 2.038 to 3.
6. The lubricating oil composition of claim 1 , wherein the lubricating oil composition is effective to reduce the number of low-speed pre-ignition events relative to the number of low-speed pre-ignition events in the same engine lubricated with the same lubricating oil composition absent the additive composition, as determined in a GM 2.0 Liter, 4 cylinder Ecotec turbocharged gasoline direct injection engine operated at an engine speed of 2,000 rpm and a brake mean effective pressure (BMEP) of about 18 bar for 6 segments of 25,000 cycles per segment.
7. A method for reducing low-speed pre-ignition (LSPI) events in a turbocharged gasoline direct-injection engine comprising lubricating the engine with the lubricating oil composition of claim 1 , wherein the number of low-speed pre-ignition (LSPI) events is reduced relative to a number of low speed pre-ignition events in the same engine lubricated with the same lubricating oil composition absent the additive composition.
8. A method for providing corrosion protection, comprising lubricating an engine with the lubricating oil composition of claim 1 .
9. The lubricating oil composition of claim 1 , wherein the overbased calcium sulfonate detergent is present in an amount sufficient to provide from about 1200 ppmw to about 2000 ppmw of calcium, based on the total weight of the lubricating oil composition.
10. The lubricating oil composition of claim 1 , wherein the compound of the Formula (I) is a polydimethylsiloxane terminated with an alkyl group comprising from 1 to 18 carbon atoms.