Light emitting layer including quantum dots with improved charge carrier mobility
A light emitting device comprises a first electrode, a second electrode, and an emissive layer (EML) between the first electrode and the second electrode and electrically connected to the first electrode and the second electrode. The EML comprises a charge transport matrix of a first polarity, a plurality of quantum dots in the charge transport matrix, and a plurality of charge transport nanoparticles of a second polarity in the charge transport matrix.
1. A light emitting device comprising:
a first electrode;
a second electrode; and
an emissive layer (EML) between the first electrode and the second electrode and electrically connected to the first electrode and the second electrode, the EML comprising:
a charge transport matrix of a first polarity;
a plurality of quantum dots in the charge transport matrix; and
a plurality of charge transport nanoparticles of a second polarity dispersed in the charge transport matrix, wherein
the EML is phase-separated into a lower emitting layer closer to the first electrode than the second electrode and an upper emitting layer closer to the second electrode than the first electrode, and
the lower emitting layer comprises higher in quantity of the plurality of charge transport nanoparticles than the quantity of charge transport nanoparticles in the upper emitting layer, and the upper emitting layer comprises higher in quantity of the plurality of quantum dots than the quantity of quantum dots in the lower emitting layer.
2. The light emitting device of claim 1 , wherein the plurality of charge transport nanoparticles conducts charge carriers opposite to charge carriers conducted by the charge transport matrix.
3. The light emitting device of claim 1 , further comprising an electron transport layer (ETL) between the EML and the first electrode, wherein the first electrode is a cathode.
4. The light emitting device of claim 3 , wherein the ETL comprises metal oxide nanoparticles.
5. The light emitting device of claim 4 , wherein the plurality of charge transport nanoparticles in the EML and the metal oxide nanoparticles in the ETL are identical in composition.
6. The light emitting device of claim 1 , further comprising a hole transport layer (HTL) between the EML and the first electrode, wherein the first electrode is an anode.
7. The light emitting device of claim 6 , wherein the HTL comprises hole transport organic molecules.
8. The light emitting device of claim 7 , wherein the hole transport organic molecules are arranged in a matrix comprising long chain polymers.
9. The light emitting device of claim 7 , wherein the charge transport matrix in the EML includes organic molecules identical in composition as the hole transport organic molecules in the HTL.
10. The light emitting device of claim 1 , wherein:
the first electrode is a cathode disposed between a substrate and the EML; and
the second electrode is an anode.
11. The light emitting device of claim 1 , wherein:
the first electrode is an anode disposed between a substrate and the EML; and
the second electrode is a cathode.
12. The light emitting device of claim 1 , wherein:
the first electrode is disposed between a substrate and the EML;
the first electrode reflects light; and
the second electrode transmits light.
13. The light emitting device of claim 1 , wherein:
the first electrode is disposed between a substrate and the EML;
the first electrode transmits light; and
the second electrode reflects light.
14. A display device comprising:
a substrate; and
a plurality of the light emitting devices of claim 1 on the substrate;
wherein each of the light emitting devices emits one of:
a red light with a wavelength between 600 nm and 700 nm,
a green light with a wavelength between 500 nm and 600 nm, and
a blue light with a wavelength between 400 nm and 500 nm.
15. The light emitting device of claim 1 , wherein an average separation distance between two adjacent ones of the plurality of charge transport nanoparticles is less than an average diameter of the plurality of charge transport nanoparticles.
16. The light emitting device of claim 1 , wherein an average diameter of the plurality of charge transport nanoparticles is greater than an average diameter of the plurality of quantum dots.
17. An emissive layer (EML) of a light emitting device, the EML comprising:
a charge transport matrix of a first polarity;
a plurality of quantum dots in the charge transport matrix; and
a plurality of charge transport nanoparticles of a second polarity dispersed in the charge transport matrix, wherein
the EML is phase-separated into a lower emitting layer and an upper emitting layer that is a layer above the lower emitting layer, and
the lower emitting layer comprises higher in quantity of the plurality of charge transport nanoparticles than the quantity of charge transport nanoparticles in the upper emitting layer, and the upper emitting layer comprises higher in quantity of the plurality of quantum dots than the quantity of quantum dots in the lower emitting layer.
18. The EML of claim 17 , wherein the plurality of charge transport nanoparticles conducts charge carriers opposite to charge carriers conducted by the charge transport matrix.
19. The EML of claim 17 , wherein an average separation distance between two adjacent charge transport nanoparticles of the plurality of charge transport nanoparticles is less than an average diameter of the plurality of charge transport nanoparticles.
20. The EML of claim 17 , wherein an average diameter of the plurality of charge transport nanoparticles is greater than an average diameter of the plurality of quantum dots.