In-situ polymerized type thermoplastic prepreg, thermoplastic composite, and methods of manufacturing the same
An in-situ polymerized type thermoplastic prepreg is provided, which is excellent in productivity, has tack properties and drape properties that allow easy shaping in a mold, is excellent in handling properties, and allows a molded product obtained by curing to have both mechanical properties as high as those of a thermosetting composite and the features of the thermoplastic composite. An in-situ polymerized type thermoplastic prepreg 1 includes reinforcing fibers 2 and an in-situ polymerized type thermoplastic epoxy resin 3 as a matrix resin. The in-situ polymerized type thermoplastic epoxy resin 3 is cured to B-stage, with the weight-average molecular weight being 6,000 or less, and has tack properties and drape properties at 30° C. or less, and the in-situ polymerized type thermoplastic epoxy resin after curing has a weight-average molecular weight of 30,000 or more.
1. A method of manufacturing an in-situ polymerized type thermoplastic prepreg comprising reinforcing fibers and a partially polymerized thermoplastic epoxy resin as a matrix resin, the method comprising:
(a) preparing a precursor composition of the partially polymerized thermoplastic epoxy resin comprising a first bifunctional compound having two epoxy groups, a second bifunctional compound having two functional groups of at least one type selected from the group consisting of a phenolic hydroxyl group, an amino group, a carboxyl group, a mercapto group, an isocyanate group, and a cyanate ester group, and a catalyst;
(b) preparing a resin film by uniformly applying the precursor composition onto a release sheet while adjusting a temperature of the precursor composition within a range of 40° C. to 70° C.;
(c) performing a partial polymerization reaction of the resin film on the release sheet, with a weight-average molecular weight of the partially polymerized thermoplastic epoxy resin being not more than 6,000, while maintaining a temperature of the resin film at 20° C. to 40° C. for 50 hr to 240 hr; and
(d) impregnating the partially polymerized thermoplastic epoxy resin as a matrix resin into the reinforcing fibers.
2. The method of manufacturing an in-situ polymerized type thermoplastic prepreg according to claim 1 , wherein the catalyst is selected from imidazole-based catalysts, aliphatic polyamine-based catalysts, aromatic amine-based catalysts, and phosphorus-based catalysts.
3. The method of manufacturing an in-situ polymerized type thermoplastic prepreg according to claim 1 , wherein the precursor composition has a viscosity of 100 Pa·s to 1,000 Pa·s at 25° C. before polymerization.
4. The method of manufacturing an in-situ polymerized type thermoplastic prepreg according to claim 1 , wherein the in-situ polymerized type thermoplastic prepreg has a resin content ratio of 20 wt % to 40 wt %.
5. The method of manufacturing an in-situ polymerized type thermoplastic prepreg according to claim 1 , wherein the reinforcing fibers have a weight per unit area of 50 g/m 2 to 500 g/m 2 .
6. The method of manufacturing an in-situ polymerized type thermoplastic prepreg according to claim 1 , wherein the reinforcing fibers comprise uni-directional continuous fibers having a tensile modulus of not less than 40 GPa and paralleled in one direction.
7. A method of manufacturing a thermoplastic composite, the method comprising:
manufacturing an in-situ polymerized type thermoplastic prepreg by performing the method according to claim 1 ; and
further polymerizing the matrix resin until the matrix resin has a weight-average molecular weight of not less than 30,000, thereby forming a thermoplastic composite.