Positive electrode for rechargeable lithium battery, method of preparing the same, and rechargeable lithium battery including the same
A positive electrode for a rechargeable lithium battery includes a positive active material including small particle diameter monolith particles having a particle diameter of about 1 μm to about 8 μm and including a first nickel-based lithium metal oxide, and large particle diameter secondary particles having a particle diameter of about 10 μm to about 20 μm and including a second nickel-based lithium metal oxide. An X-ray diffraction peak intensity ratio (I(003)/I(104)) of the positive electrode is greater than or equal to about 3. A rechargeable lithium battery includes the positive electrode.
1. A positive electrode for a rechargeable lithium battery, the positive electrode comprising:
a positive active material, comprising
small particle diameter monolith particles having a particle diameter of about 1 μm to about 8 μm and comprising a first nickel-based lithium metal oxide; and
large particle diameter secondary particles having a particle diameter of about 10 μm to about 20 μm and comprising a second nickel-based lithium metal oxide,
wherein the positive electrode has a mixture density of greater than or equal to about 3.45 g/cc, and
wherein an X-ray diffraction peak intensity ratio (I(003)/I(104)) of the positive electrode is greater than or equal to about 3.
2. The positive electrode of claim 1 , wherein the X-ray diffraction peak intensity ratio (I(003)/I(104)) of the positive electrode is greater than or equal to about 3.4.
3. The positive electrode of claim 1 , wherein the small particle diameter monolith particles and the large particle diameter secondary particles are included in a weight ratio of about 10:90 to about 60:40.
4. The positive electrode of claim 1 , wherein the small particle diameter monolith particles have a particle diameter of about 3 μm to about 6 μm.
5. The positive electrode of claim 1 , wherein the large particle diameter secondary particles have a particle diameter of about 12 μm to about 20 μm.
6. The positive electrode of claim 1 , wherein the large particle diameter secondary particles have a form in which two or more primary particles are aggregated, and the primary particles have a particle diameter of about 20 nm to about 500 nm.
7. The positive electrode of claim 1 , wherein the large particle diameter secondary particles are about 90 mol % or more of nickel based on 100 mol % of the total amount of transition metals in the second nickel-based lithium metal oxide.
8. The positive electrode of claim 1 , wherein the large particle diameter secondary particles are a compound represented by Chemical Formula 1:
Li a Ni x Q 1 1-x O 2 , and Chemical Formula 1
wherein, in Chemical Formula 1,
0.9≤a≤1.05, 0.9≤x≤0.98, and Q 1 is at least one element selected from Co, Mn, Al, Cr, Fe, Ca, B, V, Mg, Nb, Rb, Mo, Ta, W, Cu, Zn, Ga, In, La, Ce, Pr, Sn, Zr, Te, Ru, Ti, Pb, and Hf.
9. The positive electrode of claim 1 , wherein the small particle diameter monolith particles are a compound represented by Chemical Formula 2:
Li b Ni y Q 2 1-y O 2 , and Chemical Formula 2
wherein, in Chemical Formula 2,
0.9≤b≤1.05, 0.3≤y≤0.98, and Q 2 is at least one element selected from Co, Mn, Al, Cr, Fe, Ca, B, V, Mg, Nb, Rb, Mo, Ta, W, Cu, Zn, Ga, In, La, Ce, Pr, Sn, Zr, Te, Ru, Ti, Pb, and Hf.
10. A rechargeable lithium battery comprising the positive electrode of claim 1 .
11. A method of preparing a positive electrode for a rechargeable lithium battery, the method comprising:
preparing a positive active material to comprise small particle diameter monolith particles having a particle diameter of about 1 μm to about 8 μm and comprising a first nickel-based lithium metal oxide, and large particle diameter secondary particles having a particle diameter of about 10 μm to about 20 μm and comprising a second nickel-based lithium metal oxide;
mixing the positive active material, a conductive agent, and a binder in a solvent to prepare a positive active material slurry,
coating the positive active material slurry on a current collector and drying it to form the positive electrode; and
compressing the positive electrode to have a density of greater than or equal to about 3.45 g/cc,
wherein an X-ray diffraction peak intensity ratio (I(003)/I(104)) of the positive electrode is greater than or equal to about 3.
12. The method of claim 11 , wherein in the positive active material, the small particle diameter monolith particles and the large particle diameter secondary particles are included in a weight ratio of about 10:90 to about 60:40.
13. The method of claim 11 , wherein the preparing of the positive active material slurry is performed by mixing about 90 wt % to about 98 wt % of the positive active material, about 1 wt % to about 5 wt % of the conductive agent, and about 1 wt % to about 5 wt % of the binder.