Passivating agents for electrochemical cells
Articles and methods involving electrochemical cells and/or electrochemical cell preproducts comprising passivating agents are generally provided. In certain embodiments, an electrochemical cell includes first and second passivating agents. In some embodiments, an electrochemical cell may include a first electrode comprising a first surface, a second electrode (e.g., a counter electrode with respect to the first electrode) comprising a second surface, a first passivating agent configured and arranged to passivate the first surface, and a second passivating agent configured and arranged to passivate the second surface.
1. An electrochemical cell, comprising:
a first electrode comprising lithium, the first electrode comprising a first surface;
a second electrode, the second electrode comprising a second surface;
an electrolyte;
a first passivating agent, wherein the first passivating agent comprises a carbamate group, wherein the first passivating agent comprises polycarbamate, lithium carbamate, lithium dithiocarbamate, lithium diethyldithiocarbamate, lithium N,N-dimethyldithiocarbamate, potassium carbamate, potassium dithiocarbamate, and/or potassium diethyldithiocarbamate; and
a second passivating agent, wherein the second passivating agent comprises an (oxalato)borate group, and wherein the second passivating agent is present in the electrolyte at greater than or equal to 0.2 wt %.
2. An electrochemical cell, comprising:
a first electrode comprising lithium, the first electrode comprising a first surface;
a second electrode, the second electrode comprising a second surface;
an electrolyte;
a first passivating agent, wherein the first passivating agent comprises a carbamate group, wherein the first passivating agent comprises polycarbamate, lithium carbamate, lithium dithiocarbamate, lithium diethyldithiocarbamate, lithium N,N-dimethyldithiocarbamate, potassium carbamate, potassium dithiocarbamate, and/or potassium diethyldithiocarbamate; and
a second passivating agent, wherein the second passivating agent comprises one or more of lithium difluoro(oxalato)borate, a species that is capable of undergoing polymerization to form a layer on the cathode during cell cycling, and a species absent a vinyl group but is capable of developing a vinyl group upon electrochemical cell cycling.
3. An electrochemical cell, comprising:
a first electrode comprising lithium, the first electrode comprising a first surface;
a second electrode, the second electrode comprising a second surface;
an electrolyte;
a first passivating agent, wherein the first passivating agent comprises polycarbamate, lithium carbamate, lithium dithiocarbamate, lithium diethyldithiocarbamate, lithium N,N-dimethyldithiocarbamate, potassium carbamate, potassium dithiocarbamate, and/or potassium diethyldithiocarbamate; and
a second passivating agent, wherein the second passivating agent comprises one or more of a species comprising an (oxalato)borate group, a species that is capable of undergoing polymerization to form a layer on the cathode during cell cycling, a species which comprises a vinyl group, and a species absent a vinyl group but is capable of developing a vinyl group upon electrochemical cell cycling.
4. An electrochemical cell as in claim 1 , wherein the second passivating agent comprises an (oxalato)borate salt.
5. An electrochemical cell as in claim 4 , wherein the (oxalato)borate salt comprises lithium bis(oxalato)borate.
6. An electrochemical cell as in claim 1 , wherein the first passivating agent comprises a lithium salt.
7. An electrochemical cell as in claim 1 , wherein the first passivating agent comprises lithium carbamate, potassium carbamate, and/or polycarbamate.
8. An electrochemical cell as in claim 1 , wherein the electrolyte further comprises fluoroethylene carbonate and/or difluoroethylene carbonate.
9. An electrochemical cell as in claim 1 , wherein the first passivating agent is an additive that is soluble or miscible with the electrolyte.
10. An electrochemical cell as in claim 1 , wherein the first passivating agent is derived from a first passivating agent precursor.
11. An electrochemical cell as in claim 1 , wherein the second electrode has a voltage with respect to lithium of greater than or equal to 2.8 V and less than or equal to 4.5 V.
12. An electrochemical cell as in claim 1 , wherein the second electrode is a lithium-intercalation electrode.
13. An electrochemical cell as in claim 1 , wherein the electrolyte comprises a solvent.
14. An electrochemical cell as in claim 13 , wherein the solvent comprises a carbonate group.
15. An electrochemical cell as in claim 13 , wherein the solvent comprises a mixture of dimethyl carbonate and ethylene carbonate.
16. An electrochemical cell as in claim 1 , wherein the first passivating agent, in the absence of the second passivating agent, reduces cycle life of an electrochemical cell, compared to a control electrochemical cell that does not include the first or the second passivating agents, all other factors being equal, and wherein the presence of the first and second passivating agents increases cycle life of an electrochemical cell compared to the control electrochemical cell, all other factors being equal.
17. An electrochemical cell as in claim 1 , wherein the second passivating is configured and arranged to reduce or prevent decomposition of the first passivating agent during cycling of the electrochemical cell and/or to reduce or prevent decomposition of an electrolyte component promoted by the first passivating agent during cycling of the electrochemical cell, compared to decomposition in a similar electrochemical cell that does not include the second passivating agent, all other factors being equal.
18. An electrochemical cell as in claim 2 , wherein the electrolyte further comprises fluoroethylene carbonate and/or difluoroethylene carbonate.
19. An electrochemical cell as in claim 2 , wherein the first passivating agent is derived from a first passivating agent precursor.
20. An electrochemical cell as in claim 2 , wherein the first passivating agent is an additive that is soluble or miscible with the electrolyte.