Pressure regulation system for silicon dominant anode lithium-ion cell
The disclosure herein pertains to a pressure regulation system for use in a silicon dominate anode lithium-ion cell. The pressure regulation system regulates a lifetime pressure on the lithium-ion cell in order to correct for capacity loss and mechanical failure due the expansion of silicon during operation. The pressure regulation system along with a housing maintains a certain pressure range on the lithium-ion cells during the cycling and the operational life of the energy storage device.
1. A battery comprising: a plurality of lithium-ion cells each comprising a silicon-dominant anode having an active material with greater than 50% silicon; a housing surrounding the plurality of lithium-ion cells; a first silicone spring layer arranged between the housing and one of the plurality of lithium-ion cells, wherein a heat-sink layer is positioned between at least one pair of the plurality of lithium-ion cells;
wherein a surface of the first silicone spring layer and the heat sink layer that contacts a cell of the plurality of lithium-ion cells has a same area as a cell surface in contact with the first silicone spring layer and the heat sink layer; and a second silicone spring layer between pairs of the lithium-ion cells, wherein the second silicone spring layer has a first compression level corresponding to a first predefined range of states of charge, and a second compression level corresponding to a second predefined range of states of charge during lithiation/delithiation cycling, wherein the first and second compression levels are based on a thickness and density of the second silicone spring layer and a pressure from the housing, and wherein the second silicone spring layer has spring back behavior of less than 15% of its original thickness of the second silicone spring layer between the pairs of lithium-ion cells after lithiation/delithiation cycling based on the first compression level.
2. The battery according to claim 1 , wherein the first or second silicone spring layer comprises an open pore silicone foam.
3. The battery according to claim 1 , wherein the first or second silicone spring layer has a spring back behavior with a compression of less than about 8% after cycling.
4. The battery according to claim 1 , wherein a pressure exerted on the plurality of cells during cycling is at least 30 kPa.
5. The battery according to claim 1 , wherein the first or second silicone spring layer has a density from about 0.05 g/cc to about 1 g/cc.
6. The battery according to claim 1 , wherein the lithium-ion cells have a cycle expansion of between about 3% and about 15%.
7. The battery according to claim 1 , wherein the lithium-ion cells have a lifetime expansion of about 5% to about 30% measured at 100% state of charge.
8. The battery according to claim 1 , wherein the first or second silicone spring layer has a thickness of from about 0.5 mm to about 3.5 mm.
9. A method of energy storage, the method comprising: providing a plurality of lithium-ion cells each comprising a silicon-dominant anode having an active material with greater than 50% silicon; providing a housing surrounding the plurality of lithium-ion cells; providing a silicone spring layer between pairs of the lithium-ion cells, wherein a heat-sink layer is positioned between at least one pair of the plurality of lithium-ion cells;
wherein a surface of the silicone spring layer and the heat sink layer that contacts a cell of the plurality of lithium-ion cells has a same area as a cell surface in contact with the silicone spring layer and the heat sink layer; compressing the silicone spring layer to a first compression level corresponding to a first predefined range of states of charge during an initial stage; and compressing the silicone spring layer to a second compression level corresponding to a second predefined range of states of charge during lithiation/delithiation cycling, wherein the first and second compression levels are based on a thickness and density of the silicone spring layer and a pressure from the housing, and wherein the silicone spring layer has spring back behavior of less than 15% of its original thickness between the pairs of lithium-ion cells after lithiation/delithiation cycling based on the first compression level.
10. The method according to claim 9 , wherein the silicone spring layer comprises an open pore silicone foam.
11. The method according to claim 9 , wherein the silicone spring layer has a spring back behavior with a compression of less than about 8% after cycling.
12. The method according to claim 9 , wherein a pressure exerted on the plurality of cells during cycling is at least 30 kPa.
13. The method according to claim 9 , wherein at least one silicone spring layers is between the housing and one of the plurality of lithium-ion cells.
14. The method according to claim 9 , wherein the silicone spring layer has a density from about 0.05 g/cc to about 1 g/cc.
15. The method according to claim 9 , wherein the lithium-ion cells have a cycle expansion of between about 3% and about 15%.
16. The method according to claim 9 , wherein the lithium-ion cells have a lifetime expansion of about 5% to about 30% measured at 100% state of charge.
17. A battery comprising: a plurality of lithium-ion cells each comprising a silicon-dominant anode having an active material with greater than 50% silicon; a housing surrounding the plurality of lithium-ion cells; a first silicone spring layer arranged between the housing and one of the plurality of lithium-ion cells, wherein a heat-sink layer is positioned between at least one pair of the plurality of lithium-ion cells; wherein a surface of the first silicone spring layer and the heat sink layer that contacts a cell of the plurality of lithium-ion cells has a same area as a cell surface in contact with the first silicone spring layer and the heat sink layer; and a second silicone spring layer between pairs of the lithium-ion cells, wherein the first silicone spring layer has a first compression level corresponding to a first predefined range of states of charge, and a second compression level corresponding to a second predefined range of states of charge during lithiation/delithiation cycling, wherein the first and second compression levels are based on a thickness and density of the first silicone spring layer and a pressure from the housing, and wherein the first silicone spring layer has spring back behavior of less than 15% of an original thickness of the first silicone spring layer between the pairs of lithium-ion cells after lithiation/delithiation cycling based on the first compression level.
18. The battery according to claim 1 , wherein the predefined range of states of charge is between about 30-50%.