IP Library Granted Patent US 12,092,602
Granted Patent B2
US 12,092,602 · App. 17/206,935 · Granted Sep 17, 2024

Nano-sized boron-doped diamond (BDD) enabled electrodes

Inventors: Paul K. Westerhoff (Scottsdale, AZ); Sergio Garcia-Segura (Tempe, AZ); Shahnawaz Sinha (Chandler, AZ); Rishabh Bansal (Tempe, AZ); Rafael Verduzco (Houston, TX); Michael S. Wong (Houston, TX)
Assignees: Arizona Board of Regents on behalf of Arizona State University; William Marsh Rice University
G01N27/308C02F1/46109C02F2001/46147
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Quick Facts
Patent No.
US 12,092,602
App. No.
17/206,935
Granted
Sep 17, 2024
Kind
B2
Abstract

An electrode includes an electrically conductive substrate with a coating containing boron-doped diamond (BDD) nanoparticles. Fabricating the electrode can include dispersing BDD nanoparticles in a solvent to yield a suspension, coating a conductive substrate with the suspension, and drying the suspension to yield the electrode. In some cases, fabricating the electrode includes combining BDD nanoparticles with a polymeric resin precursor to yield a mixture including a metal oxide, coating a conductive substrate with the mixture to yield a coated substrate, and calcining the coated substrate to yield a metal oxide coating including BDD nanoparticles. In certain cases, fabricating the electrode includes combining powdered activated carbon with polymeric linkers to yield a polymeric precursor solution, combining BDD nanoparticles with the polymeric precursor solution to yield a mixture, coating a conductive substrate with the mixture to yield a coated substrate, and crosslinking the polymeric linkers to yield the electrode.

Claims (11)

1. An electrode comprising:

an electrically conductive substrate; and

a coating on the electrically conductive substrate, wherein the coating comprises a polymer, powdered activated carbon, and boron-doped diamond nanoparticles comprising between about 10 and about 80,000 ppm boron.

2. The electrode of claim 1 , wherein the boron-doped diamond nanoparticles have a diameter in a range between about 10 nm and about 200 nm.

3. The electrode of claim 2 , wherein the boron-doped diamond nanoparticles have a diameter in a range between about 50 nm and about 60 nm.

4. The electrode of claim 1 , wherein a thickness of the coating is in a range between one nanoparticle and five nanoparticles.

5. The electrode of claim 1 , wherein the polymer further comprises polypyrrole.

6. The electrode of claim 1 , wherein the polymer comprises polyaniline.

7. The electrode of claim 1 , wherein the polymer comprises polyphenylene vinylene.

8. The electrode of claim 1 , wherein the polymer comprises polyvinyl alcohol.

9. The electrode of claim 8 , wherein the polymer further comprises glutaraldehyde linkers.

Assignments (3)
CONFIRMATORY LICENSE Recorded Jan 10, 2024
From: ARIZONA STATE UNIVERSITY-TEMPE CAMPUS
To: NATIONAL SCIENCE FOUNDATION
Reel/Frame 066255/0746 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 12, 2021
From: VERDUZCO, RAFAEL; WONG, MICHAEL S.
To: WILLIAM MARSH RICE UNIVERSITY
Reel/Frame 056215/0279 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 8, 2021
From: WESTERHOFF, PAUL K.; GARCIA-SEGURA, SERGIO; SINHA, SHAHNAWAZ; BANSAL, RISHABH
To: ARIZONA BOARD OF REGENTS ON BEHALF OF ARIZONA STATE UNIVERSITY
Reel/Frame 055866/0533 →
Continuity (2)
Provisional Application 62992628 · Mar 20, 2020
Related Publication 20210293741A1 · Sep 23, 2021