IP Library Granted Patent US 11,859,092
Granted Patent B2
US 11,859,092 · App. 17/213,950 · Granted Jan 2, 2024

Printable non-curable thixotropic hot melt composition

Inventors: Lei Wang (San Jose, CA); Martin W. Bayes (Hopkinton, MA); Ting Gao (Palo Alto, CA); Philip Singer (Greensboro, NC); James Zeigler (Harrisburg, PA)
Assignee: TE CONNECTIVITY SOLUTIONS GMBH
C09D11/34C08K3/36C08L91/06C23F1/02
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Quick Facts
Patent No.
US 11,859,092
App. No.
17/213,950
Granted
Jan 2, 2024
Kind
B2
Abstract

A printable non-curable thixotropic hot melt composition is described. The composition comprises non-curable holt melt waxes transformed into a thixotropic composition by the use of thickeners. The thickeners can be added separately to the hot melt wax or formed in-situ. A process of forming such printable non-curable thixotropic hot melt composition is described.

Claims (19)

1. A printable non-curable thixotropic hot melt composition for use as a resist during a plating process comprising:

one or more hot melt waxes with acid functional groups, anhydride groups, or an amine functional group; and

a thickener comprising fumed silica, polymeric particles having a melting point higher than a mixing temperature and a printing temperature of the composition, or metallic complexes, such metallic complexes comprising lithium or aluminum.

2. The printable non-curable thixotropic hot melt composition as set forth in claim 1 , wherein the printable non-curable thixotropic hot melt composition can be stripped off in a bath during a plating process.

3. The printable non-curable thixotropic hot melt composition as set forth in claim 1 , wherein the printable non-curable thixotropic hot melt composition has a melting temperature above 50° C. and below 90° C.

4. The printable non-curable thixotropic hot melt composition as set forth in claim 1 , wherein the printable non-curable thixotropic hot melt composition is stable during said plating process and withstands the plating solution.

5. The printable non-curable thixotropic hot melt composition as set forth in claim 1 , wherein said thickener has a particle size that is less than ten microns.

6. The printable non-curable thixotropic hot melt composition as set forth in claim 1 , wherein the amount of thickener is between approximately 0.50% to approximately 30% by weight of said composition.

7. A printable non-curable thixotropic hot melt composition used for plating resists using an inkjet printer comprising:

a mixture of waxes with acid functional groups, anhydride groups or amine functional groups; and

a thickener component that is miscible or partially miscible with the mixture of waxes.

8. The printable non-curable thixotropic hot melt composition as recited in claim 7 , wherein the inkjet printable non-curable thixotropic hot melt composition can be stripped off in solution stripping bath during the plating process.

9. The printable non-curable thixotropic hot melt composition recited in claim 7 , wherein said hot melt composition has a melting temperature above approximately 50° C. and below approximately 90° C.

10. The printable non-curable thixotropic hot melt composition as recited in claim 7 , wherein said composition is stable during a plating process and withstands the plating solution.

11. A process to form fine and uniformly dispersed thickener particles in a mixture of waxes comprising:

heating the mixture of waxes and a thickener component to a temperature to achieve complete mixing; and

cooling down the mixture of waxes and thickener component under high speed rotation, stirring, shaking, vibration or shear, wherein said thickener component will precipitate from the mixture forming uniformly dispersed thickener particles.

12. The process as recited in claim 11 , wherein the mixture of waxes and said thickener component is heated to a temperature between approximately 10° C. to approximately 30° C. above the melting temperature of the thickener component.

13. The process as recited in claim 11 , wherein the thickener component is miscible or partially miscible with the waxes at a temperature sufficiently high to melt the thickener component.

Assignments (2)
MERGER Recorded Mar 21, 2022
From: TE CONNECTIVITY SERVICES GMBH
To: TE CONNECTIVITY SOLUTIONS GMBH
Reel/Frame 059328/0367 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 15, 2021
From: WANG, LEI; BAYES, MARTIN W.; GAO, TING; SINGER, PHILIP; ZEIGLER, JAMES
To: TE CONNECTIVITY SERVICES GMBH
Reel/Frame 056592/0547 →
Continuity (1)
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