METHOD FOR SEPARATING AND RECOVERING LIGNIN AND MELTABLE FLOWABLE BIOLIGNIN POLYMERS
Lignin is recovered from biomass or byproducts from biomass processing through the use of organic solvents and water while modifying the form or composition of the lignin. During the separation and recovery process, the lignin can be modified or integrated into a form which is more suitable for its intended use. As the lignin is suspended or is soluble within the organic solvent, the integration of materials or reactants may be more easily blended or dispersed within the lignin to improve performance, quality and overall production efficiency.
1 . A hydrophobic melt flowable lignin thermoplastic comprising: a) a separated alcohol soluble lignin, b) a carrier fluid, and c) a functional material.
2 . A hydrophobic melt flowable lignin thermoplastic of claim 1 wherein the melt flowable lignin thermoplastic is solid at room temperature and has a controlled melting point at an elevated temperature.
3 . A hydrophobic melt flowable lignin thermoplastic of claim 1 wherein the melt flowable lignin thermoplastic has thermoplastic properties of melting, melt flow index, re-meltable, recyclable, and highly hydrophobic.
4 . A hydrophobic melt flowable lignin thermoplastic of claim 1 wherein the alcohol soluble lignin is produced using an organosolv process with a hydrophobic lignin solvent or blend thereof.
5 . A hydrophobic melt flowable lignin thermoplastic of claim 4 wherein the alcohol soluble lignin is derived from kraft lignin, organosolv lignin, lignosulfonate lignin, Biomass, wood, baggasse, bamboo, agricultural fibers, or blends thereof
6 . A hydrophobic melt flowable lignin thermoplastic of claim 4 wherein the alcohol soluble lignin comprises one or more butanol, n-butanol, water, furfural, butyl acetate, butyl esters, acid, alcohol, glycerin, glycol, lactide, methanol, ethanol or blend thereof
7 . A hydrophobic melt flowable lignin thermoplastic of claim 1 wherein the alcohol soluble lignin includes an alcohol portion that has been substantially removed.
8 . A hydrophobic melt flowable lignin thermoplastic of claim 1 wherein the carrier fluid is butyl acetate, butyl esters, furfural, glycol, glycerin, polyol, oils, fatty acids, esters, acids, butanol, or blends thereof
9 . A hydrophobic melt flowable lignin thermoplastic of claim 1 wherein the carrier fluid reacts with the alcohol soluble lignin portion and is about 1-49% of the melt flowable lignin biopolymer by weight
10 . A hydrophobic melt flowable lignin thermoplastic of claim 1 wherein the functional material includes furfural or furfural derivatives and butyl acetate/butyl ester.
11 . A hydrophobic melt flowable lignin thermoplastic of claim 10 comprising wherein a further functional component comprising one or more of a filler, plasticizer, cross linker, modifier, polymer, thermoplastic, oil, plasticizers, thermoplastic additive, wood, thermally modified wood filler, ground wood, wood flour, carbon powder, minerals, glass, metal, celulosic fiber, resin, polymer, polyol, cross linker, plastic modifier, impact modifier or blends thereof.
12 . A hydrophobic melt flowable lignin thermoplastic composition that is suitable as is or modified to produce a bioplastic, adhesive binder, biofuels, bioelastomer, and biobased solid energy product.
13 . A hydrophobic melt flowable lignin thermoplastic composition that is suitable as ingredients that can be used as is, or combined with other existing formulations including thermoplastics, rubbers, thermoplastic elastomer, thermosetting resins, fiber-reinforced composites, adhesives of wood and paperboard products, wood stain/paint, surface sizing and coating of wood, paper, and paperboard products, engineered wood composites, paper and wood impregnation, UV protection material or coating, antioxidant material or coating, carbon fiber precursors, and to make already premixed compositions or master batches.
14 . A method of making a hydrophobic melt flowable lignin thermoplastic composition comprising:
a) blending a hydrophobic alcohol with lignin rich biomass to form a mixture;
b) providing heat and pressure sufficient to the mixer to convert a hemicellulose fraction within the mixture to a functional material and to separate the lignin into alcohol soluble and water soluble fractions;
c) filtering and removal of solids;
d) gravity phase separating of the liquid fraction into a hydrophobic alcohol soluble organic layer and a water soluble aqueous layer;
e) separating the hydrophobic alcohol soluble organic layer and the water soluble aqueous layer; and
f) processing the hydrophobic alcohol soluble layer by removal of a significant portion of the hydrophobic alcohol to create the hydrophobic melt flowable lignin thermoplastic that retains at least one or more hydrophobic alcohol soluble lignin fraction, furfural, and butyl acetate/ester.
15 . A method of making a hydrophobic melt flowable lignin thermoplastic composition of claim 14 wherein the functional materials are furfural, furfural derivatives, butyl acetate, butyl ester and acetic acid.
16 . A method of making a hydrophobic melt flowable lignin thermoplastic composition of claim 14 wherein the material is solid at room temperature and can be melted or remelted at elevated temperatures with thermoplastic processing melt flowable characteristics.