IP Library Granted Patent US 11,845,107
Granted Patent B2
US 11,845,107 · App. 17/225,588 · Granted Dec 19, 2023

Methods for protecting oilfield operational components from damage from fluid flow

Inventors: Greg Andrews (Wilmington, DE); George D. Andrews (Wilmington, DE); Jeff Capell (Wilmington, DE)
Assignee: S+S INDUSTRIES TECHNOLOGY LLC
B05D7/586B05D1/02B05D1/08B05D1/38B05D3/12B05D5/00B05D7/14B05D7/16B05D7/22B05D7/222B05D7/225B05D7/26B05D7/544B05D7/546B05D7/584C08G77/08C08G77/20C08K3/22C08K5/5425C09D5/002C09D5/082C09D5/084C09D7/20C09D7/61C09D7/62C09D7/63C09D159/00C09D163/04C09D183/04C09D183/06C23F11/18E21B33/03E21B34/04E21B34/06E21B41/00E21B43/2607B05D2202/00B05D2202/10B05D2254/00B05D2350/60B05D2401/10B05D2504/00C08G59/022C08G59/063C08K3/11C08K3/36C08K5/541C08K5/544C08K5/5415C08K5/5435C08K2003/2241C08K2003/2265C09D163/00E21B17/02E21B43/26
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Quick Facts
Patent No.
US 11,845,107
App. No.
17/225,588
Granted
Dec 19, 2023
Kind
B2
Abstract

Coating compositions for coating an oilfield operational component, and related methods, may include in some aspects a coating composition having a trifunctional silane, a silanol, and a filler. The coating composition may be applied to a surface of the oilfield operational component that is configured to be exposed to a fluid. The coating composition may be applied to at least partially cover or coat the surface. The coating composition may be configured to chemically bond with a cured primer composition that includes an epoxy.

Claims (71)

1. A method for protecting an oilfield operational component exposed to flow of an oilfield fluid, the method comprising:

applying a primer composition to the oilfield operational component;

curing the primer composition, at least partially, so as to form a primer layer, such that the primer layer at least partially mechanically bonds to the oilfield operational component;

applying a first coating composition to the primer layer, the first coating composition including trifunctional silane, silanol fluid, fillers, and titanium dioxide;

curing the first coating composition, at least partially, such that the first coating composition forms a first coating layer at least partially chemically bonded to the primer layer;

applying one or more additional coatings to the first coating layer; and

curing the one or more additional coatings, at least partially, so as to form a second coating layer at least partially chemically bonded to the first coating layer thereby to enhance wear resistance of the oilfield operational component and so that the primer layer, the first coating layer, and the second coating layer when applied to the oilfield operational component collectively define a coated oilfield operational component, the first coating layer including T- resin units each of which forms one or more bonds with one or more of other T-resin units, silanol fluid, fillers, or the titanium dioxide, such that the coated oilfield operational component exhibits a comparison factor indicative of an increased resistance to wear greater than about 2, the comparison factor being indicative of a first amount of time during which the coated oilfield operational component wears to a first depth divided by a second amount of time during which a portion of the oilfield operational component without the second coating layer, the first coating layer, and the primer layer collectively wears to a second depth equal to the first depth.

2. The method of claim 1 , wherein applying the primer composition, the first coating composition, and the one or more additional coatings comprises applying the primer composition, the first coating composition, and the one or more additional coatings to an interior surface of the oilfield operational component.

3. The method of claim 1 , wherein the oilfield operational component comprises at least a portion of a goat head, and the comparison factor ranges from about 5 to about 30.

4. The method of claim 1 , wherein the oilfield operational component comprises at least a portion of a fluid end, and the comparison factor ranges from about 3 to about 12.

5. The method of claim 1 , wherein the oilfield operational component comprises at least a portion of a frac iron component, and the comparison factor ranges from about 2 to about 20.

6. The method of claim 1 , wherein the one or more additional coatings comprise:

trifunctional silane, silanol fluid, pigment, and filler, and

the trifunctional silane and the silanol fluid are selected to, upon cure, form oligomers, polymers, copolymers, and T-resin units, each of the T-resin units forms two or more bonds with one or more of other T-resin units, silanol fluid, fillers, or pigments.

7. The method of claim 1 , wherein composition of the primer layer comprises at least one of an aliphatic amine, epichlorohydrin, a bisphenol, silane adhesion promoter, trimethoxysilane, triethoxysilane, or 3-glycidoxypropyltrimethoxysilane.

8. The method of claim 1 , wherein applying the primer composition comprises at least one of spraying the primer composition onto the component, brushing the primer composition onto the component, spreading the primer composition onto the component, or dipping the oilfield operational component into the primer composition.

9. The method of claim 8 , wherein applying the primer composition comprises spraying the primer composition onto the oilfield operational component via an atomizing sprayer.

10. The method of claim 1 , wherein applying the first coating composition comprises at least one of spraying the first coating composition onto the primer layer, brushing the first coating composition onto the primer layer, spreading the first coating composition onto the primer layer, or dipping the primer layer into the first coating composition.

11. The method of claim 10 , wherein applying the first coating composition comprises spraying the first coating composition onto the primer layer via an atomizing sprayer.

12. The method of claim 1 , further comprising:

at least partially drying the second coating layer, such that the coated oilfield operational component exhibits a comparison factor indicative of an increased resistance to wear ranging from about 2 to about 30.

13. The method of claim 12 , further comprising:

applying the first coating composition to the second coating layer so as to form a third coating layer; and

at least partially drying the third coating layer, such that the coated oilfield operational component exhibits a comparison factor indicative of an increased resistance to wear ranging from about 2 to about 30.

14. A method for dissipating energy generated via cavitation associated with fluid flow in relation to an oilfield operational component exposed to an oilfield fluid, the method comprising:

applying a primer composition to the oilfield operational component;

curing the primer composition, at least partially, so as to form a primer layer, such that the primer layer at least partially mechanically bonds to the oilfield operational component;

applying a first coating composition to the primer layer, the first coating composition including trifunctional silane, silanol fluid, fillers, and titanium dioxide;

curing the first coating composition, at least partially, such that the first coating composition forms a first coating layer at least partially chemically bonded to the primer layer;

applying one or more additional coatings to the first coating layer; and

curing the one or more additional coatings, at least partially, so as to form a second coating layer at least partially chemically bonded to the first coating layer thereby to enhance wear resistance of the oilfield operational component, and so that the primer layer, the first coating layer, and the second coating layer when applied to the oilfield operational component collectively define a coated oilfield operational component, the first coating layer including T-resin units each of which forms one or more bonds with one or more of other T-resin units, silanol fluid, fillers, or the titanium dioxide, such that the coated oilfield operational component exhibits a comparison factor indicative of an increased resistance to wear greater than about 2, the comparison factor being indicative of a first amount of time during which the coated oilfield operational component wears to a first depth divided by a second amount of time during which a portion of the oilfield operational component without the second coating layer, the first coating layer, and the primer layer collectively wears to a second depth equal to the first depth.

15. The method of claim 14 , wherein the one or more additional coatings comprise:

trifunctional silane, silanol fluid, pigment, and filler,

the trifunctional silane and the silanol fluid are selected to, upon cure, form oligomers, polymers, copolymers, and T-resin units, each of the T-resin units forms two or more bonds with one or more of other T-resin units, silanol fluid, fillers, or pigments, and

the one or more additional coatings comprising an amount of T-resin units ranging from about 1.5 wt % to about 5.0 wt % of the one or more additional coatings on the basis of non-solvent components.

16. The method of claim 14 , wherein the primer composition comprises at least one of an aliphatic amine, epichlorohydrin, a bisphenol, silane adhesion promoter, trimethoxysilane, triethoxysilane, or 3-glycidoxypropyltrimethoxysilane.

17. The method of claim 14 , wherein applying the primer composition comprises at least one of spraying the primer composition onto the oilfield operational component, brushing the primer composition onto the oilfield operational component, spreading the primer composition onto the oilfield operational component, or dipping the oilfield operational component into the primer composition.

18. The method of claim 17 , wherein applying the primer composition comprises spraying the primer composition onto the oilfield operational component via an atomizing sprayer.

19. The method of claim 14 , wherein applying the first coating composition comprises at least one of spraying the first coating composition onto the primer layer, brushing the first coating composition onto the primer layer, spreading the first coating composition onto the primer layer, or dipping the primer layer into the first coating composition.

20. The method of claim 19 , wherein applying the first coating composition comprises spraying the first coating composition onto the primer layer via an atomizing sprayer.

21. The method of claim 14 , further comprising at least partially drying the one or more additional coatings, such that the coated oilfield operational component exhibits a comparison factor indicative of resistance to wear ranging from about 2 to about 30.

22. The method of claim 21 , further comprising:

applying the first coating composition to the second coating layer so as to form a third coating layer, and

at least partially drying the third coating layer, such that the coated oilfield operational component exhibits a comparison factor indicative of an increased resistance to wear ranging from about 2 to about 30.

23. A method for dissipating kinetic energy associated with particles impact in an oilfield fluid in contact with an oilfield operational component, the method comprising:

applying a primer composition to the oilfield operational component;

curing the primer composition, at least partially, to form a primer layer, such that the primer layer is at least partially mechanically bonded to the oilfield operational component;

applying a first coating composition to the primer layer, the first coating composition including trifunctional silane, silanol fluid, fillers, and titanium dioxide;

curing the first coating composition, at least partially, such that the first coating composition forms a first coating layer at least partially chemically bonded to the primer layer;

applying one or more additional coatings to the first coating layer; and

curing the one or more additional coatings, at least partially, so as to form a second coating layer at least partially chemically bonded to the first coating layer thereby to enhance wear resistance of the oilfield operational component, and so that the primer layer, the first coating layer, and the second coating layer when applied to the oilfield operational component collectively define a coated oilfield operational component, the first coating layer including T-resin units each of which forms one or more bonds with one or more of other T-resin units, silanol fluid, fillers, or the titanium dioxide, such that the oilfield operational component exhibits a comparison factor indicative of an increased resistance to wear greater than about 2, the comparison factor being indicative of a first amount of time during which the coated oilfield operational component wears to a first depth divided by a second amount of time during which a portion of the oilfield operational component without the second coating layer, the first coating layer, and the primer layer collectively wears to a second depth equal to the first depth.

24. The method of claim 23 , wherein the first coating composition further comprises blue pigment in an amount ranging from about 1.0 wt % to about 5.0 wt % of the first coating composition on the basis of non-solvent components.

25. The method of claim 23 , wherein the primer composition comprises at least one of an aliphatic amine, epichlorohydrin, a bisphenol, silane adhesion promoter, trimethoxysilane, triethoxysilane, or 3-glycidoxypropyltrimethoxysilane.

26. The method of claim 23 , wherein applying the primer composition comprises at least one of spraying the primer composition onto the oilfield operational component, brushing the primer composition onto the oilfield operational component, spreading the primer composition onto the oilfield operational component, or dipping the oilfield operational component into the primer composition.

27. The method of claim 26 , wherein applying the primer composition comprises spraying the primer composition onto the oilfield operational component via an atomizing sprayer.

28. The method of claim 23 , wherein applying the first coating composition comprises at least one of spraying the first coating composition onto the primer layer, brushing the first coating composition onto the primer layer, spreading the first coating composition onto the primer layer, or dipping the primer layer into the first coating composition.

29. The method of claim 28 , wherein applying the first coating composition comprises spraying the first coating composition onto the primer layer via an atomizing sprayer.

30. A method for protecting an oilfield operational component exposed to flow of an oilfield fluid, the method comprising:

applying a primer composition to the oilfield operational component;

curing the primer composition, at least partially, so as to form a primer layer, such that the primer layer at least partially mechanically bonds to the oilfield operational component;

applying a first coating composition to the primer layer, the first coating composition including trifunctional silane, silanol fluid, fillers, and titanium dioxide;

curing the first coating composition, at least partially, such that the first coating composition forms a first coating layer at least partially chemically bonded to the primer layer;

applying one or more additional coatings to the first coating layer; and

curing the one or more additional coatings, at least partially, so as to form a second coating layer at least partially chemically bonded to the first coating layer thereby to enhance wear resistance of the oilfield operational component, and so that the primer layer, the first coating layer, and the second coating layer when applied to the oilfield operation component collectively define a coated oilfield operational component, the first coating layer including T- resin units each of which forms one or more bonds with one or more of other T-resin units, silanol fluid, fillers, or the titanium dioxide, such that the coated oilfield operational component exhibits a comparison factor indicative of an increased resistance to wear greater than about 2, the comparison factor being indicative of a first amount of time during which the coated oilfield operational component wears to a first depth divided by a second amount of time during which a portion of the oilfield operational component without the second coating layer, the first coating layer, and the primer layer collectively wears to a second depth equal to the first depth, and

one or more of:

(i) applying the primer composition to the oilfield operational component,

(ii) applying the first coating composition to the primer layer, or

(iii) applying the one or more additional coatings to the first coating layer, including, respectively, one or more of:

(i) spraying the primer composition onto the oilfield operational component,

(ii) spraying the first coating composition onto the primer layer, or

(iii) spraying the one or more additional coatings onto the first coating layer.

Assignments (3)
CHANGE OF NAME Recorded Jun 29, 2022
From: S+S INDUSTRIES LLC
To: S+S INDUSTRIES TECHNOLOGY LLC
Reel/Frame 060529/0987 →
CHANGE OF NAME Recorded Jun 10, 2022
From: FORMULA NO. 37, LLC
To: S+S INDUSTRIES LLC
Reel/Frame 060333/0728 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 12, 2021
From: ANDREWS, GREG; ANDREWS, GEORGE D.; CAPELL, JEFF
To: FORMULA NO. 37, LLC
Reel/Frame 055889/0548 →
Continuity (12)
Provisional Application 63008035 · Apr 10, 2020
Provisional Application 63008038 · Apr 10, 2020
Provisional Application 63008042 · Apr 10, 2020
Provisional Application 63008046 · Apr 10, 2020
Provisional Application 63008049 · Apr 10, 2020
Provisional Application 63065542 · Aug 14, 2020
Provisional Application 63065545 · Aug 14, 2020
Provisional Application 63065565 · Aug 14, 2020
Provisional Application 63065577 · Aug 14, 2020
Provisional Application 63065591 · Aug 14, 2020
Provisional Application 63198044 · Sep 25, 2020
Related Publication 20210317734A1 · Oct 14, 2021