IP Library › Granted Patent US 11,192,834
Granted Patent B2
US 11,192,834 · App. 17/254,351 · Granted Dec 7, 2021

Process and system for producing para-xylene

Inventor: Thomas Hubertus Maria Housmans (Beek, NL)
Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
C07C2/64C07C4/06C07C7/005
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Quick Facts
Patent No.
US 11,192,834
App. No.
17/254,351
Granted
Dec 7, 2021
Kind
B2
Abstract

A process for producing a para-xylene product from a hydrocarbon feed includes: hydrocracking the hydrocarbon feed in the presence of a catalyst to obtain a hydrocracking product; separating the hydrocracking product to obtain a gas stream and a liquid stream, the liquid stream comprising benzene, toluene, xylene, C 9+ hydrocarbon, or a combination comprising at least one of the foregoing; separating the liquid stream to obtain a toluene stream, wherein toluene is present in the toluene stream in an amount equal to or greater than 70 wt %, preferably equal to or greater than 80 wt %, more preferably equal to or greater than 95 wt %, based on the total weight of the toluene stream; and reacting the toluene stream with methanol to obtain the para-xylene product.

Claims (28)

1. A process for producing para-xylene product from a hydrocarbon feed, comprising:

hydrocracking the hydrocarbon feed in the presence of a catalyst to obtain a hydrocracking product comprising less than 1 weight percent aliphatic hydrocarbons, based on a total weight of the hydrocracking product;

separating the hydrocracking product to obtain a gas stream and a liquid stream, the liquid stream comprising benzene, toluene, xylene, C 9+ hydrocarbons, or a combination comprising at least one of the foregoing;

separating the liquid stream to obtain a toluene stream, wherein toluene is present in the toluene stream in an amount equal to or greater than 70 wt %, based on the total weight of the toluene stream; and

reacting the toluene stream with methanol to obtain the para-xylene product.

2. The process of claim 1 , wherein the hydrocarbon feed comprises hydrogenated depentanized hydrotreated gasoline, naphtha, pyrolysis gasoline, hydrocracked gasoline, coke oven light oil, fluid catalytic cracking gasoline, reformate, kerosene, C 5 -C 12 hydrocarbons, or a combination comprising at least one of the foregoing.

3. The process of claim 1 , wherein the hydrocracking is in the presence of one catalyst.

4. The process of claim 1 , wherein separating the hydrocracking product comprises distilling the hydrocracking product to obtain the liquid stream.

5. The process of claim 1 , wherein the gas stream comprises hydrogen, methane, ethane, propane, butane, or a combination comprising at least one of the foregoing.

6. The process of claim 1 , wherein separating the liquid stream comprises distilling the liquid stream.

7. The process of claim 1 , further comprising, before or during the step of separating the liquid stream to obtain the toluene stream, separating a xylene stream from the liquid stream and transalkylating the xylene stream to obtain para-xylene.

8. The process of claim 1 , further comprising, before or during the step of separating the liquid stream to obtain the toluene stream, separating a C 9+ hydrocarbon stream from the liquid stream.

9. The process of claim 7 , further comprising recycling the C 9+ hydrocarbon stream to the step of hydrocracking.

10. The process of claim 1 , wherein the para-xylene is present in the para-xylene product an amount equal to or greater than 95 wt %, based on the total weight of the para-xylene product.

11. The process of claim 1 , wherein disproportionation, hydrodealkylation, extractive distillation, or a combination of at least one of the foregoing, are not present in the process.

12. The process of claim 1 , wherein the liquid stream comprises less than 1 wt % of C5-C7 aliphatic hydrocarbons, based on the total weight of the liquid stream.

13. The process of claim 1 , wherein the liquid stream comprises less than 1 wt % aliphatic hydrocarbons, based on the total weight of the liquid stream.

14. The process of claim 1 , without processing of the toluene via disproportionation or hydrodealkylation.

15. The process of claim 1 , wherein the hydrocracking was at a temperature of 300° C. to 580° C., and a pressure of 0.3 MPa to 5.0 MPa.

16. A para-xylene product produced by the process of claim 1 .

17. A system for producing a para-xylene product, comprising:

a hydrocracking unit for producing a hydrocracking product;

a first separation unit for separating the hydrocracking product to obtain a gas stream and a liquid stream;

a second separation unit for separating the liquid stream to obtain a toluene stream; and

a methylation unit for reacting the toluene stream with methanol to obtain the para-xylene product,

wherein no unit for separation of aliphatic hydrocarbons from aromatic hydrocarbons is present.

18. The system of claim 17 , wherein no disproportionation unit or hydrodealkylation unit is present between the hydrocracking unit and the methylation unit.

19. The process of claim 1 , wherein separation of aliphatic hydrocarbons from aromatic hydrocarbons is not present in the process.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 21, 2020
From: HOUSMANS, THOMAS HUBERTUS MARIA
To: SABIC GLOBAL TECHNOLOGIES B.V.
Reel/Frame 054812/0292 →
Continuity (2)
Provisional Application 62689401 · Jun 25, 2018
Related Publication 20210323894A1 · Oct 21, 2021
Cited By (1)
US 12,491,484