Silicone pressure sensitive adhesive composition and methods for the preparation and use thereof
A silicone pressure sensitive adhesive composition is curable to form a silicone pressure sensitive adhesive. The silicone pressure sensitive adhesive composition can be coated on a substrate and cured to form a protective film. The protective film can be adhered to an anti-fingerprint coating on display glass, such as cover glass for a smartphone.
1. A silicone pressure sensitive adhesive composition comprising:
(A) 25 weight % to 35 weight %, based on combined weights of starting materials (A) to (F), of a polydiorganosiloxane gum of unit formula (R M 2 R U SiO 1/2 ) 2 (R M 2 SiO 2/2 ) a , where each R M is an independently selected monovalent hydrocarbon group of 1 to 30 carbon atoms that is free of aliphatic unsaturation; each R U is an independently selected monovalent aliphatically unsaturated hydrocarbon group of 2 to 30 carbon atoms; and subscript a has a value sufficient to give the polydiorganosiloxane gum a number average molecular weight of ≥500,000 g/mol;
(B) 65 weight % to 75 weight %, based on combined weights of starting materials (A) to (F), of a polyorganosilicate resin component comprising
(B-1) a capped resin of unit formula: (R M 3 SiO 1/2 ) Z (SiO 4/2 ) o Z p , where Z is a hydrolyzable group, subscript p is 0 to a value sufficient to give the capped resin a hydrolyzable group content up to 2%, subscripts z and o have values such that z>4, o>1, and a quantity (z+o) has a value sufficient to provide the capped resin with a number average molecular weight of 500 g/mol to 5,000 g/mol;
(B-2) an uncapped resin of unit formula (R M 3 SiO 1/2 ) Z′ (SiO 4/2 ) o′ Z p′ , where subscript p′ has a value sufficient to give the uncapped resin a hydrolyzable group content of >3% to 10%, subscripts z′ and o′ have values such that z′>4, o′>1, and a quantity (z′+o′) has a value sufficient to provide the uncapped resin with a number average molecular weight of 500 g/mol to 5,000 g/mol,
where starting materials (B-1) and (B-2) are present in a weight ratio (B-2):(B-1) of <0.30:1;
where starting materials (A) and (B) are present in a weight ratio of (B):(A) (Resin: Gum Ratio) >2:1;
(C) 0.01 weight % to 5 weight %, based on combined weights of starting materials (A) to (F) of a hydrosilylation reaction catalyst;
(D) 0.1 weight % to 5 weight %, based on combined weights of starting materials (A) to (F) of a polyorganohydrogensiloxane of unit formula: (R M 3 SiO 1/2 ) 2 (R M 2 SiO 2/2 ) e (HR M 2 SiO 2/2 ) f , where subscript e≥0, subscript f≥3 and a quantity (e+f) is 4 to 500;
(E) 0 weight % to 5 weight %, based on combined weights of starting materials (A) to (F), of an anchorage additive;
(F) 0 weight % to 5 weight %, based on combined weights of starting materials (A) to (F) of a hydrosilylation reaction inhibitor; and
(G) 0 weight % to 60 weight %, based on combined weights of all starting materials in the composition of a solvent,
with the proviso that the silicone pressure sensitive composition is free of fluorinated starting materials.
2. The composition of claim 1 , where in starting material (A), the polydiorganosiloxane gum, each R M is an independently selected alkyl group of 1 to 10 carbon atoms; each R U is an independently selected alkenyl group of 2 to 10 carbon atoms; and subscript a has a value sufficient to give the polydiorganosiloxane gum a number average molecular weight of 500,000 to 1,000,000 g/mol.
3. The composition of claim 1 , where in starting material (B-1), the capped resin, each R M is an independently selected alkyl group of 1 to 10 carbon atoms; and subscripts z and o have values such that the quantity (z+o) has a value sufficient to provide the capped resin with a number average molecular weight of 1,000 g/mol to 4,700 g/mol.
4. The composition of claim 1 , where in starting material (B-2), the uncapped resin, each R M is an independently selected alkyl group of 1 to 10 carbon atoms; and subscripts z′ and o′ have values such that the quantity (z′+o′) has a value sufficient to provide the uncapped resin with a number average molecular weight of 1,000 g/mol to 4,700 g/mol.
5. The composition of claim 1 , where starting material (C), the hydrosilylation reaction catalyst, comprises a platinum-organosiloxane complex.
6. The composition of claim 1 , where in starting material (D), the polyorganohydrogensiloxane, each R M is an independently selected alkyl group of 1 to 10 carbon atoms; and the quantity (e+f) has a value sufficient to provide the polyorganohydrogensiloxane with an SiH content of 0.38 weight % to 2.00 weight %.
7. The composition of claim 1 , where each R M is methyl and each R U is selected from the group consisting of vinyl, allyl, and hexenyl.
8. The composition of claim 1 , where starting material (E), the anchorage additive, is present and is selected from the group consisting of (E-1) vinyltriacetoxysilane, (E-2) glycidoxypropyltrimethoxysilane, (E-3) a combination of (E-1) and (E-2), and (E-4) a combination of (E-3) and a polydimethylsiloxane terminated with hydroxyl groups, methoxy groups, or terminated with both a hydroxy group and a methoxy group.
9. The composition of claim 1 , where starting material (E) is not present.
10. The composition of claim 1 , where starting material (F), the hydrosilylation reaction inhibitor, is present and is selected from the group consisting of (F-1) 1-ethynyl-1-cyclohexanol, (F-2) methyl butynol, (F-3) diallyl maleate, and (F-4) a combination of two or more of (F-1), (F-2) and (F-3).
11. The composition of claim 1 , where (G) the solvent is present and is selected from the group consisting of toluene, xylene, heptane, ethyl benzene, and a combination of two or more thereof.
12. A silicone pressure sensitive adhesive prepared by curing the composition of claim 1 .
13. A protective film comprising:
1) the silicone pressure sensitive adhesive of claim 12 , and
2) a first polymeric substrate having a first surface and an opposing second surface, where the silicone pressure sensitive adhesive is disposed on the first surface.
14. A method for preparing protective film comprising:
optionally 1) treating a surface of a substrate,
2) coating
a silicone pressure sensitive adhesive composition comprising:
(A) 25 weight % to 35 weight %, based on combined weights of starting materials (A) to (F), of a polydiorganosiloxane gum of unit formula (R M 2 R U SiO 1/2 ) 2 (R M 2 SiO 2/2 ) a , where each R M is an independently selected monovalent hydrocarbon group of 1 to 30 carbon atoms that is free of aliphatic unsaturation; each R U is an independently selected monovalent aliphatically unsaturated hydrocarbon group of 2 to 30 carbon atoms; and subscript a has a value sufficient to give the polydiorganosiloxane gum a number average molecular weight of ≥500,000 g/mol;
(B) 65 weight % to 75 weight %, based on combined weights of starting materials (A) to (F), of a polyorganosilicate resin component comprising
(B-1) a capped resin of unit formula: (R M 3 SiO 1/2 ) Z (SiO 4/2 ) o Z p , where Z is a hydrolyzable group, subscript p is 0 to a value sufficient to give the capped resin a hydrolyzable group content up to 2%, subscripts z and o have values such that z>4, o>1, and a quantity (z+o) has a value sufficient to provide the capped resin with a number average molecular weight of 500 g/mol to 5,000 g/mol;
(B-2) an uncapped resin of unit formula (R M 3 SiO 1/2 ) Z′ (SiO 4/2 ) o′ Z p′ , where subscript p′ has a value sufficient to give the uncapped resin a hydrolyzable group content of >3% to 10%, subscripts z′ and o′ have values such that z′>4, o′>1, and a quantity (z′+o′) has a value sufficient to provide the uncapped resin with a number average molecular weight of 500 g/mol to 5,000 g/mol,
where starting materials (B-1) and (B-2) are present in a weight ratio (B-2):(B-1) of <0.30:1;
where starting materials (A) and (B) are present in a weight ratio of (B):(A) (Resin: Gum Ratio) >2:1;
(C) 0.01 weight % to 5 weight %, based on combined weights of starting materials (A) to (F) of a hydrosilylation reaction catalyst;
(D) 0.1 weight % to 5 weight %, based on combined weights of starting materials (A) to (F) of a polyorganohydrogensiloxane of unit formula: (R M 3 SiO 1/2 ) 2 (R M 2 SiO 2/2 ) e (HR M 2 SiO 2/2 ) f , where subscript e≥0, subscript f≥3 and a quantity (e+f) is 4 to 500;
(E) 0 weight % to 5 weight %, based on combined weights of starting materials (A) to (F), of an anchorage additive;
(F) 0 weight % to 5 weight %, based on combined weights of starting materials (A) to (F) of a hydrosilylation reaction inhibitor; and
(G) 0 weight % to 60 weight %, based on combined weights of all starting materials in the composition of a solvent,
with the proviso that the silicone pressure sensitive composition is free of fluorinated starting materials;
on the surface of the substrate,
optionally 3) removing some or all of the solvent, when present, and
4) curing the silicone pressure sensitive adhesive composition.
15. A method comprising:
optionally 1) treating a surface of a substrate,
2) coating
a silicone pressure sensitive adhesive composition comprising:
(A) 25 weight % to 35 weight %, based on combined weights of starting materials (A) to (F), of a polydiorganosiloxane gum of unit formula (R M 2 R U SiO 1/2 ) 2 (R M 2 SiO 2/2 ) a , where each R M is an independently selected monovalent hydrocarbon group of 1 to 30 carbon atoms that is free of aliphatic unsaturation; each R U is an independently selected monovalent aliphatically unsaturated hydrocarbon group of 2 to 30 carbon atoms; and subscript a has a value sufficient to give the polydiorganosiloxane gum a number average molecular weight of ≥500,000 g/mol;
(B) 65 weight % to 75 weight %, based on combined weights of starting materials (A) to (F), of a polyorganosilicate resin component comprising
(B-1) a capped resin of unit formula: (R M 3 SiO 1/2 ) Z (SiO 4/2 ) o Z p , where Z is a hydrolyzable group, subscript p is 0 to a value sufficient to give the capped resin a hydrolyzable group content up to 2%, subscripts z and o have values such that z>4, o>1, and a quantity (z+o) has a value sufficient to provide the capped resin with a number average molecular weight of 500 g/mol to 5,000 g/mol;
(B-2) an uncapped resin of unit formula (R M 3 SiO 1/2 ) Z′ (SiO 4/2 ) o′ Z p′ , where subscript p′ has a value sufficient to give the uncapped resin a hydrolyzable group content of >3% to 10%, subscripts z′ and o′ have values such that z′>4, o′>1, and a quantity (z′+o′) has a value sufficient to provide the uncapped resin with a number average molecular weight of 500 g/mol to 5,000 g/mol,
where starting materials (B-1) and (B-2) are present in a weight ratio (B-2):(B-1) of <0.30:1;
where starting materials (A) and (B) are present in a weight ratio of (B):(A) (Resin: Gum Ratio) >2:1;
(C) 0.01 weight % to 5 weight %, based on combined weights of starting materials (A) to (F) of a hydrosilylation reaction catalyst;
(D) 0.1 weight % to 5 weight %, based on combined weights of starting materials (A) to (F) of a polyorganohydrogensiloxane of unit formula: (R M 3 SiO 1/2 ) 2 (R M 2 SiO 2/2 ) e (HR M 2 SiO 2/2 ) f , where subscript e≥0, subscript f≥3 and a quantity (e+f) is 4 to 500;
(E) 0 weight % to 5 weight %, based on combined weights of starting materials (A) to (F), of an anchorage additive;
(F) 0 weight % to 5 weight %, based on combined weights of starting materials (A) to (F) of a hydrosilylation reaction inhibitor; and
(G) 0 weight % to 60 weight %, based on combined weights of all starting materials in the composition of a solvent,
with the proviso that the silicone pressure sensitive composition is free of fluorinated starting materials;
on the surface of the substrate,
optionally 3) removing some or all of the solvent, when present,
4) curing the silicone pressure sensitive adhesive composition, thereby forming a protective film; and
5) applying the protective film on an anti-fingerprint coating for a display glass.