Pesticidal compositions and methods
This disclosure relates to the field of molecules having pesticidal utility against pests in phyla Nematoda, Arthropoda, and/or Mollusca, processes to produce such molecules and intermediates used in such processes, compositions containing such molecules, and processes of using such molecules against such pests. These molecules may be used, for example, as nematicides, acaricides, insecticides, miticides, and/or molluscicides. This document discloses molecules having the structure of Formula A.
1. The molecule having the structure of Formula One, Formula Two, or Formula Three:
wherein:
(A) AR 1 is a substituted phenyl having one or more substituents independently selected from C 1 -C 6 haloalkyl and C 1 -C 6 haloalkoxy;
(B) L 1 is selected from the group consisting of:
wherein R 5 is selected from H, C 1 -C 8 alkyl, C 1 -C 8 haloalkyl, C 1 -C 8 alkoxy, C 1 -C 8 haloalkoxy, phenyl, or substituted phenyl, wherein said substituted phenyl has one or more substituents selected from H, F, Cl, Br, I, CN, NO 2 , NR x R y , C 1 -C 8 alkyl, C 1 -C 8 haloalkyl, C 3 -C 8 cycloalkyl, C 3 -C 8 halocycloalkyl, C 3 -C 8 cycloalkoxy, C 3 -C 8 halocycloalkoxy, C 1 -C 8 alkoxy, C 1 -C 8 haloalkoxy, C 2 -C 8 alkenyl, C 3 -C 8 cycloalkenyl, C 2 -C 8 haloalkenyl, C 3 -C 8 halocycloalkenyl, and C 2 -C 8 alkynyl;
(C) Ar 2 is a phenyl;
(D) each R 6 , R 7 , R 8 , and R 9 is selected from H, F, Cl, Br, and C 1 -C 6 alkyl;
(E) Q 1 is O or S;
(F) Q 2 is O or S;
(G) R 2 and R 3 is a 1- to 4-membered saturated or unsaturated, hydrocarbyl link, and together with (Q 2 )(C)(N) forms a 4- to 7-membered cyclic structure, wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO 2 , NR x R y , C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, S(═O) n (C 1 -C 6 alkyl), S(═O) n (C 1 -C 6 haloalkyl), phenyl, and oxo;
(H) R 4 is phenyl, wherein the phenyl may be optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO 2 , NR x R y , C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 3 -C 6 cycloalkyl, C 3 -C 6 halocycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, (C 1 -C 6 alkyl)O(C 1 -C 6 alkyl), (C 1 -C 8 alkyl)O(C 1 -C 8 haloalkyl), (C 1 -C 6 alkyl)S(═O) n (C 1 -C 6 alkyl), C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, S(═O) n (C 1 -C 6 alkyl), S(═O) n (C 1 -C 6 haloalkyl), phenyl, and oxo, or wherein two adjacent substituents form a 5- or 6-membered saturated or unsaturated, hydrocarbyl link, which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen, and wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO 2 , NR x R y , C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, S(═O) n (C 1 -C 6 alkyl), and S(═O) n (C 1 -C 6 haloalkyl);
(I) R x and R y are independently selected from H, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 3 -C 6 cycloalkyl, C 3 -C 6 halocycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, and phenyl; and
(J) n is each individually 0, 1, or 2.
2. The molecule of claim 1 , wherein R 2 and R 3 is 1- to 4-membered saturated or unsaturated, hydrocarbyl link and together with (Q 2 )(C)(N) forms a 5-membered cyclic structure, wherein said hydrocarbyl link is optionally substituted with H, OH, F, Cl, Br, I, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkoxy, or C 1 -C 6 haloalkoxy.
3. The molecule of claim 1 , wherein AR 1 is a substituted phenyl having one or more substituents independently selected from OCF 3 , OCF 2 CF 3 , and CF 3 .
4. The molecule of claim 1 , wherein L 1 is selected from the group consisting of:
wherein R 5 is selected from H, C 1 -C 8 alkyl, C 1 -C 8 haloalkyl, C 1 -C 8 alkoxy, C 1 -C 8 haloalkoxy, phenyl, and substituted phenyl,
wherein said substituted phenyl has one or more substituents selected from H, F, Cl, Br, I, CN, NO 2 , NR x R y , C 1 -C 8 alkyl, C 1 -C 8 haloalkyl, C 3 -C 8 cycloalkyl, C 3 -C 8 halocycloalkyl, C 3 -C 8 cycloalkoxy, C 3 -C 8 halocycloalkoxy, C 1 -C 8 alkoxy, C 1 -C 8 haloalkoxy, C 2 -C 8 alkenyl, C 3 -C 8 cycloalkenyl, C 2 -C 8 haloalkenyl, C 3 -C 8 halocycloalkenyl, and C 2 -C 8 alkynyl.
5. The molecule of claim 1 , wherein each of R 6 , R 7 , R 8 , and R 9 is independently H, F, Cl, or a C 1 -C 6 alkyl.
6. The molecule of claim 1 , wherein R 4 is a substituted phenyl with one or more H, F, Cl, Br, I, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 3 -C 6 cycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, (C 1 -C 6 alkyl)O(C 1 -C 6 alkyl), C 1 -C 6 alkoxy, or C 1 -C 6 haloalkoxy, or wherein two adjacent substituents form a 5- or 6-membered saturated or unsaturated, hydrocarbyl link, which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen, and wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO 2 , NR x R y , C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, S(═O) n (C 1 -C 6 alkyl), and S(═O) n (C 1 -C 6 haloalkyl).
7. The molecule of claim 1 having a structure selected from compounds listed in Table 1
TABLE 1
Structures for Compounds
A1
A2
A3
A4
A5
A6
A7
A8
A9
A10
A11
A12
A13
A14
A15
A16
A17
A18
A19
A20
A21
A22
A23
A24
A25
A26
A27
A28
A29
A30
A31
A32
A33
A34
A35
A36
A37
A38
A39
A40
A41
A42
A43
A44
A45
A46
A47
A48
A49
A50
A51
A52
A53
A54
A55