TETRACARBOXYLIC DIANHYDRIDE, POLYIMIDE PRECURSOR RESIN, POLYIMIDE, POLYIMIDE PRECURSOR RESIN SOLUTION, POLYIMIDE SOLUTION, AND POLYIMIDE FILM
A tetracarboxylic dianhydride that is a mixture of stereoisomers of a compound represented by the following general formula (1): [in the formula (1), R 1 , R 2 , and R 3 each independently represent a hydrogen atom or the like and n is an integer of 0 to 12], wherein a content of an isomer (A) represented by a specific general formula is 40% by mol to 98% by mol relative to a total amount of the stereoisomers, a content of an isomer (B) represented by a specific general formula is 2% by mol to 60% by mol relative to the total amount of the stereoisomers, and a summed amount of the isomers (A) and (B) is 42% by mol or more relative to the total amount of the stereoisomers.
1 . A tetracarboxylic dianhydride that is a mixture of stereoisomers of a compound represented by the following general formula (1):
[in the formula (1), R 1 , R 2 , and R 3 each independently represent one selected from the group consisting of a hydrogen atom, alkyl groups having 1 to 10 carbon atoms, and a fluorine atom, and n is an integer of 0 to 12], wherein
a content of an isomer (A) represented by the following general formula (2):
[R 1 , R 2 , R 3 , and n in the formula (2) have the same definitions as those of R 1 , R 2 , R 3 , and n in the general formula (1), respectively] is 40% by mol to 98% by mol relative to a total amount of the stereoisomers,
a content of an isomer (B) represented by the following general formula (3):
[R 1 , R 2 , R 3 , and n in the formula (3) have the same definitions as those of R 1 , R 2 , R 3 , and n in the general formula (1), respectively] is 2% by mol to 60% by mol relative to the total amount of the stereoisomers, and
a summed amount of the isomers (A) and (B) is 42% by mol or more relative to the total amount of the stereoisomers.
2 . A polyimide precursor resin comprising a repeating unit (I) represented by the following general formula (4):
[in the formula (4), R 1 , R 2 , and R 3 each independently represent one selected from the group consisting of a hydrogen atom, alkyl groups having 1 to 10 carbon atoms, and a fluorine atom, n represents an integer of 0 to 12, R 10 represents an arylene group having 6 to 50 carbon atoms, Ys each independently represent one selected from the group consisting of a hydrogen atom, alkyl groups having 1 to 6 carbon atoms, and alkyl silyl groups having 3 to 9 carbon atoms, one of a bonding arm represented by *1 and a bonding arm represented by *2 is bonded to a carbon atom a forming the norbornane ring, the other of the bonding arm represented by *1 and the bonding arm represented by *2 is bonded to a carbon atom b forming the norbornane ring, one of a bonding arm represented by *3 and a bonding arm represented by *4 is bonded to a carbon atom c forming the norbornane ring, and the other of the bonding arm represented by *3 and the bonding arm represented by *4 is bonded to a carbon atom d forming the norbornane ring], wherein
a content of a repeating unit (I-A) having a three-dimensional structure represented by the following general formula (5):
[R 1 , R 2 , R 3 , R 10 , Y, n, a to d, and *1 to *4 in the formula (5) have the same definitions as those of R 1 , R 2 , R 3 , R 10 , Y, n, a to d, and *1 to *4 in the general formula (4), respectively] is 40% by mol to 98% by mol relative to a total amount of the repeating unit (I),
a content of a repeating unit (I-B) having a three-dimensional structure represented by the following general formula (6):
[R 1 , R 2 , R 3 , R 10 , Y, n, a to d, and *1 to *4 in the formula (6) have the same definitions as those of R 1 , R 2 , R 3 , R 10 , Y, n, a to d, and *1 to *4 in the general formula (4), respectively] is 2% by mol to 60% by mol relative to the total amount of the repeating unit (I), and
a summed amount of the repeating units (I-A) and (I-B) is 42% by mol or more relative to the total amount of the repeating unit (1).
3 . A polyimide comprising a repeating unit (II) represented by the following general formula (7):
[in the formula (7), R 1 , R 2 , and R 3 each independently represent one selected from the group consisting of a hydrogen atom, alkyl groups having 1 to 10 carbon atoms, and a fluorine atom, n represents an integer of 0 to 12, and R 10 represents an arylene group having 6 to 50 carbon atoms], wherein
a content of a repeating unit (II-A) having a three-dimensional structure represented by the following general formula (8):
[R 1 , R 2 , R 3 , R 10 , and n in the formula (8) have the same definitions as those of R 1 , R 2 , R 3 , R 10 , and n in the general formula (7), respectively] is 40% by mol to 98% by mol relative to a total amount of the repeating unit (II),
a content of a repeating unit (II-B) having a three-dimensional structure represented by the following general formula (9):
[R 1 , R 2 , R 3 , R 10 , and n in the formula (9) have the same definitions as those of R 1 , R 2 , R 3 , R 10 , and n in the general formula (7), respectively] is 2% by mol to 60% by mol relative to the total amount of the repeating unit (II), and
a summed amount of the repeating units (II-A) and (II-B) is 42% by mol or more relative to the total amount of the repeating unit (II).
4 . A polyimide precursor resin solution comprising the polyimide precursor resin according to claim 2 and an organic solvent.
5 . A polyimide solution comprising the polyimide according to claim 3 and an organic solvent.
6 . A polyimide film that is a cured product of the polyimide precursor resin solution according to claim 4 .
7 . A polyimide film that is a cured product of the polyimide solution according to claim 5 .