Porous structure for exhaust gas purification catalyst, exhaust gas purification catalyst using porous structure, and exhaust gas purification method
Provided is a porous structure for exhaust purification catalysts having excellent light-off temperature characteristics. The porous structure for exhaust purification catalysts includes an oxygen storage component and an inorganic porous solid. The porous structure has a pore volume distribution such that the ratio of the pore volume of pores with a diameter of from 15 nm to less than 25 nm to the pore volume of pores with a diameter of from 5 nm to less than 15 nm is 1.3 to 2.5 as measured with a mercury porosimeter. The pore volume distribution preferably has at least one peak top in a pore diameter range of from 15 nm to less than 25 nm.
1. An exhaust gas purification catalyst comprising a substrate and a catalyst layer on the substrate,
the catalyst layer comprising an oxygen storage component and an inorganic porous solid,
the exhaust gas purification catalyst having a pore volume distribution such that a ratio of a pore volume of pores with a diameter of from 15 nm to less than 25 nm to a pore volume of pores with a diameter of from 5 nm to less than 15 nm is 1.4 to 2.5 as measured with a mercury porosimeter,
the pore volume distribution having at least one peak top in a pore diameter range of from 15 nm to less than 25 nm, and
the pore volume distribution having a ratio of a pore volume of pores with a diameter of from 5 nm to less than 15 nm to a pore volume of pores with a diameter of 5 to 200 nm is 15% to 35%, and a ratio of a pore volume of pores with a diameter of from 15 nm to less than 25 nm to a pore volume of pores with a diameter of 5 to 200 nm is 25% to 55%.
2. The exhaust gas purification catalyst according to claim 1 , wherein the pore volume distribution has a ratio of a pore volume of pores with a diameter of from 5 nm to less than 15 nm to the total pore volume is 5% to 35%, and a ratio of a pore volume of pores with a diameter of 15 nm to less than 25 nm to the total pore volume is 10% to 50%.
3. The exhaust gas purification catalyst according to claim 1 , wherein the oxygen storage component is present in a greater amount than the inorganic porous solid.
4. The exhaust gas purification catalyst according to claim 1 , wherein the catalyst layer comprises a catalyst active component.
5. A method for purifying exhaust gas, comprising contacting exhaust gas from an internal combustion engine with the exhaust gas purification catalyst according to claim 1 .