Plasma polymerisation apparatus

1. A plasma polymerisation apparatus comprising:

a reaction zone;

at least one gas inlet for supplying at least one monomer in a gaseous form to the reaction zone;

a first electrode and a second electrode spaced apart and configured to generate an electric field in the reaction zone to form a plasma-polymer nanoparticulate material from the at least one monomer;

a plurality of collectors configured to collect the plasma-polymer nanoparticulate material formed in the reaction zone, the plurality of collectors being located adjacent the second electrode and each of the plurality of collectors being three-dimensionally shaped and defining a recess to receive the plasma-polymer nanoparticulate material formed in the reaction zone;

a cooling device located adjacent the second electrode and configured to cool the plurality of collectors; and

a confinement grid for confining the electric field in the reaction zone, wherein the confinement grid extends between the first electrode and the second electrode, wherein the confinement grid comprises a mesh having a plurality of openings, and wherein the confinement grid has a tubular or part-tubular structure and a maximum width that is substantially the same as a maximum width of the first and/or second electrodes.

2. The apparatus of claim 1 , wherein the cooling device is located between the plurality of collectors and the second electrode.

3. The apparatus of claim 1 , wherein the cooling device comprises one or more thermoelectric semiconductor devices.

4. The apparatus of claim 1 , wherein the cooling device is coupled to a rear surface of the plurality of collectors.

5. The apparatus of claim 1 , wherein the plurality of collectors comprises a plurality of vials or wells, or wherein the plurality of collectors is provided by a well plate.

6. The apparatus of claim 1 further comprising a controller to control the formation of the plasma-polymer nanoparticulate material in the reaction zone.

7. The apparatus of claim 6 , wherein the controller controls at least one of: the cooling applied by the cooling device; and plasma input parameters.

8. The apparatus of claim 7 , wherein the plasma input parameters include one or more of power to the first or second electrode, flow rate of gases supplied to the reaction zone and/or pressure of gases in the reaction zone.

9. The apparatus of claim 7 , wherein the controller controls the cooling applied by the cooling device by adjusting a power supplied to the cooling device by a power supply and/or time periods during which power is supplied to the cooling device by the power supply.

10. The apparatus of claim 6 , comprising a user interface, wherein the controller controls based on an input from the user interface.

11. The apparatus of claim 6 , comprising a particle sensor, wherein the controller controls based on an input from the particle sensor.

12. The apparatus of claim 6 , comprising at least one of:

a temperature measuring device, wherein the controller controls based on an input from the temperature measuring device;

and a plasma diagnostic device, wherein the controller controls based on an input from the plasma diagnostic device.

13. The apparatus of claim 1 , wherein the second electrode comprises a recess in which (a) the plurality of collectors is at least partially received; and/or (b) the cooling device is at least partially received.

14. The apparatus of claim 1 , wherein the reaction zone, the first electrode, the second electrode, the plurality of collectors and the cooling device are located in a reaction chamber.

15. The apparatus of claim 1 , wherein each of the plurality of openings has at least one of the following properties:

a maximum dimension of each of the plurality of openings of between about 50 μm and 5 mm; or

a shape that is circular, square, oval, rectangular, triangular, pentagonal or hexagonal.

16. The apparatus of claim 11 , wherein the particle sensor is configured to determine at least one property of the plasma-polymer nanoparticulate material in the reaction zone.

17. The apparatus of claim 16 , wherein the at least one property is one or more of:

a size of nanoparticles of the plasma-polymer nanoparticulate material or aggregates thereof; and

a number of nanoparticles of the plasma-polymer nanoparticulate material or aggregates thereof.

18. A method of collecting plasma-polymer nanoparticulate material comprising:

supplying at least one monomer in a gaseous form to a reaction zone via at least one gas inlet;

generating an electric field in the reaction zone, between a first electrode and a second electrode spaced apart from the first electrode, to form a plasma-polymer nanoparticulate material from the at least one monomer, wherein the electric field is confined in the reaction zone by a confinement grid, wherein the confinement grid extends between the first electrode and the second electrode, wherein the confinement grid comprises a mesh having a plurality of openings, and wherein the confinement grid has a tubular or part-tubular structure and a maximum width that is substantially the same as a maximum width of the first and/or second electrodes;

collecting the plasma-polymer nanoparticulate material formed in the reaction zone in a plurality of collectors adjacent the second electrode, each of the plurality of collectors being three-dimensionally shaped and defining a recess to receive the plasma-polymer nanoparticulate material formed in the reaction zone; and

cooling the plurality of collectors using a cooling device located adjacent the second electrode.