IP Library Granted Patent US 11,931,726
Granted Patent B2
US 11,931,726 · App. 17/275,088 · Granted Mar 19, 2024

Gold-supporting catalyst

Inventors: Toru Murayama (Hachioji, JP); Masatake Haruta (Hachioji, JP); Takashi Takei (Hachioji, JP); Qianqian Zhu (Hachioji, JP); Yasunori Inoue (Hachioji, JP); Fumio Uchida (Osaka, JP); Kenji Maeda (Osaka, JP); Hiroshi Matsuo (Osaka, JP); Yasuo Shibasaki (Sanyo-Onoda, JP)
Assignees: TOKYO METROPOLITAN UNIVERSITY; FUJI CHEMICAL INDUSTRIES, LTD.; Yasuo Shibasaki
B01J23/52B01J21/16B01J35/023B01J35/1014B01J35/1061B01J37/06C01B32/50
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Quick Facts
Patent No.
US 11,931,726
App. No.
17/275,088
Granted
Mar 19, 2024
Kind
B2
Abstract

The invention provides a gold-supporting catalyst comprising gold nanoparticles and a carrier consisting of porous ceramic obtained by firing a mixture comprising an aluminum compound, a lime component, and a plastic clay containing 1% by mass or less of feldspars and quartz, wherein the gold nanoparticles are supported in an amount of 0.01 to 10 parts by mass on the carrier based on 100 parts by mass of the carrier.

Claims (9)

1. A gold-supporting catalyst comprising

gold nanoparticles and

a carrier consisting of porous ceramic obtained by firing a mixture comprising an aluminum compound, a lime component, and a plastic clay containing 1% by mass or less of feldspars and quartz, the porous ceramic having a BET specific surface area of 43 m 2 /g or less,

wherein the gold nanoparticles are supported in an amount of 0.01 to 10 parts by mass on the carrier based on 100 parts by mass of the carrier.

2. The gold-supporting catalyst according to claim 1 ,

wherein an average diameter of the gold nanoparticles is 10 nm or less.

3. The gold-supporting catalyst according to claim 1 ,

wherein the aluminum compound is at least one member selected from the group consisting of aluminum hydroxide, aluminum hydrate, aluminum carbonate, and ammonium dawsonite (NH 4 AlCO 3 (OH) 2 ).

4. A method of using the gold-supporting catalyst of claim 1 comprising introducing a CO-containing gas into the gold-supporting catalyst in an atmosphere of a relative humidity of 0.1 to 100% and a temperature of −100 to 300° C.

Assignments (2)
CHANGE OF NAME Recorded Nov 25, 2024
From: TOKYO METROPOLITAN UNIVERSITY
To: TOKYO METROPOLITAN PUBLIC UNIVERSITY CORPORATION
Reel/Frame 069438/0920 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 10, 2021
From: MURAYAMA, TORU; HARUTA, MASATAKE; TAKEI, TAKASHI; ZHU, QIANQIAN; INOUE, YASUNORI; UCHIDA, FUMIO; MAEDA, KENJI; MATSUO, HIROSHI; SHIBASAKI, YASUO
To: TOKYO METROPOLITAN UNIVERSITY; FUJI CHEMICAL CO., LTD.; SHIBASAKI, YASUO
Reel/Frame 055557/0123 →
Priority Claims (1)
JP 2018-169721 · Sep 11, 2018 · national
Continuity (1)
Related Publication 20210252485A1 · Aug 19, 2021