Method for producing cyclic enol ether compound

1. A method for producing a compound represented by general formula (I), the method comprising:

reacting a compound represented by general formula (II) in the presence of a metal catalyst comprising at least one metal element selected from the group consisting of aluminum, zirconium, and titanium, and an alcohol comprising at least one selected from the group consisting of a primary alcohol and a secondary alcohol to obtain the compound represented by general formula (I),

wherein the group -A 1 - (where the front bond denotes a bond that bonds with a carbon atom C 1 while the back bond denotes a bond that bonds with a carbon atom C 2 is an alkylene group with 4 or more and 16 or less of carbon atoms that may optionally contain a hetero atom and that may optionally have a substituent, and

R 1 is hydrogen or an alkyl group with 1 or more and 6 or less of carbon atoms.

2. The method according to claim 1 , wherein the metal catalyst is at least one selected from the group consisting of aluminum alkoxide, zirconium alkoxide, and titanium alkoxide.

3. The method according to claim 1 , wherein the group -A 1 - is an alkylene group with 6 or more and 14 or less of carbon atoms.

4. The method according to claim 1 , wherein R 1 is an alkyl group with 1 or more and 3 or less of carbon atoms.

5. The method according to claim 1 , wherein the alcohol comprises a secondary alcohol.

6. The method according to claim 1 , wherein the alcohol has a boiling point of 100° C. or higher.

7. The method according to claim 1 , wherein the secondary alcohol is cyclohexanol or 2-octanol.

8. The method according to claim 1 , wherein the reacting is performed at a temperature of 100° C. or higher and 250° C. or lower.

9. The method according to claim 1 , wherein a mole ratio of the compound of formula (II) to the alcohol (compound of formula (II): alcohol) is 1:1 to 1:50.

10. The method according to claim 1 ,

wherein a mole ratio of the compound of formula (II) to the metal catalyst (compound of formula (II): metal catalyst) is 1:0.01 to 1:1.2 when the metal catalyst is a metal catalyst comprising zirconium, and

a mole ratio of the compound of formula (II) to the metal catalyst (compound of formula (II) : metal catalyst) is 1:0.5 to 1:1.5 when the metal catalyst is a metal catalyst comprising at least one metal element selected from the group consisting of aluminum and titanium.

11. The method according to claim 1 , wherein the reacting the compound of general formula (II) in the presence of the metal catalyst and the alcohol to obtain the compound of general formula (I) is carried out in the presence of at least one additive selected from an acid and a diol.

12. The method according to claim 11 , wherein the acid is trifluoroacetic acid, and the diol is ethylene glycol.

13. A method for producing a compound represented by general formula (III), the method comprising:

reacting a compound represented by general formula (II) in the presence of a metal catalyst comprising at least one metal element selected from the group consisting of aluminum, zirconium and titanium, and an alcohol comprising at least one selected from the group consisting of a primary alcohol and a secondary alcohol to obtain a compound represented by general formula (I); and

decyclizing the resultant compound represented by general formula (I) to obtain the compound represented by general formula (III),

wherein the group -A 1 - (where the front bond denotes a bond that bonds with a carbon atom C 1 while the back bond denotes a bond that bonds with a carbon atom C 2 is an alkylene group with 4 or more and 16 or less of carbon atoms that may optionally contain a hetero atom and that may optionally have a substituent, and

R 1 is hydrogen or an alkylene group with 1 or more and 6 or less of carbon atoms.