Negative electrode for non-aqueous electrolyte secondary battery and non-aqueous electrolyte secondary battery using the same
Provided is a technique capable of further improving the cycle characteristics in a negative electrode for a non-aqueous electrolyte secondary battery in which a silicon-based negative electrode active material and a carbon-based negative electrode active material are used in combination as a negative electrode active material, and constituent components of the electrode are not bound to each other via a binder. The negative electrode for a non-aqueous electrolyte secondary battery according to the present invention has a configuration in which a negative electrode active material layer containing a negative electrode active material is formed on a surface of a current collector. The negative electrode active material contains composite secondary particles in which silicon-based negative electrode active material particles and carbon-based negative electrode active material particles are bound to each other via a binder. Here, the content of the binder in the composite secondary particles is 1% by mass or more with respect to the total mass of the silicon-based negative electrode active material particles and the carbon-based negative electrode active material particles. Further, in the negative electrode active material layer, the composite secondary particles are characterized to exist in a state of being not bound to each other via a binder.
1. A negative electrode for a non-aqueous electrolyte secondary battery in which a negative electrode active material layer is formed on a surface of a current collector, the negative electrode comprising:
the negative electrode active material layer, which contains a negative electrode active material, wherein:
the negative electrode active material contains composite secondary particles comprising negative electrode active material particles bound via a binder,
the negative electrode active material particles of the composite secondary particles include silicon-based negative electrode active material particles and carbon-based negative electrode active material particles, and
a content of the binder in the composite secondary particles is 1% by mass or more with respect to a total mass of the negative electrode active material particles, a content ratio of the silicon-based negative electrode active particles to the carbon-based negative electrode active material particles contained in the composite secondary particles is 10:1 to 1:3 by mass ratio, and the composite secondary particles in the negative electrode active material layer are not bound to each other via a binder.
2. The negative electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein a thickness of the negative electrode active material layer is 200 μm or more.
3. The negative electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the composite secondary particles contained in the negative electrode active material layer comprise 10% to 100% by mass of the total mass of the negative electrode active material.
4. The negative electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein a content of the binder in the composite secondary particles is 5% by mass or more with respect to a total mass of the silicon-based negative electrode active material particles and the carbon-based negative electrode active material particles.
5. The negative electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein a volume average particle diameter D50 of the silicon-based negative electrode active material particles is smaller than a volume average particle diameter D50 of the carbon-based negative electrode active material particles.
6. The negative electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the binder contains poly(meth)acrylic acid.
7. The negative electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the silicon-based negative electrode active material contains a silicon oxide, SiO x , where 0<x≤2.
8. The negative electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the carbon-based negative electrode active material contains hard carbon.
9. The negative electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the negative electrode active material layer further contains hard carbon that does not form the composite secondary particles.
10. A non-aqueous electrolyte secondary battery, comprising:
a power generating element that comprises:
a negative electrode according to claim 1 ,
a positive electrode formed by forming a positive electrode active material layer containing a positive electrode active material on a surface of a current collector, and
an electrolyte layer disposed between the negative electrode and the positive electrode and in which an electrolyte is held by a separator.