Casing material for power storage device, production method therefor, and power storage device
A casing material for a power storage device, including a laminate that includes, in order, at least a base material layer, a barrier layer, and a heat-fusible resin layer. The heat-fusible resin layer includes a single layer or a plurality of layers. The heat-fusible resin layer includes at least one layer having a hardness of at least 70 MPa from a cross-section in the lamination direction of the laminate, measured using a nanoindentation method using an indentation load of 100 μN.
1. A power storage device outer packaging material which comprises a laminate including at least a base material layer, a barrier layer and a heat-sealable resin layer in this order,
the heat-sealable resin layer including a single layer or multiple layers,
the heat-sealable resin layer including at least one layer having a hardness of 70 MPa or more as measured from a cross-section in a lamination direction of the laminate under a load of indentation of 100 μN in a nanoindentation method.
2. The power storage device outer packaging material according to claim 1 , further comprising an adhesive layer between the barrier layer and the heat-sealable resin layer.
3. The power storage device outer packaging material according to claim 2 , wherein the thickness of a layer having a hardness of 70 MPa or more and the largest thickness in the heat-sealable resin layer is larger than the thickness of the adhesive layer.
4. The power storage device outer packaging material according to claim 2 , wherein the adhesive layer is formed of a thermoplastic resin.
5. The power storage device outer packaging material according to claim 2 , wherein the adhesive layer has a logarithmic decrement ΔE of 0.22 or less at 120° ° C. in rigid pendulum measurement.
6. The power storage device outer packaging material according to claim 2 , wherein the heat-sealable resin layer includes a first heat-sealable resin layer and a second heat-sealable resin layer in this order from the surface side of the laminate, and the thickness of the second heat-sealable resin layer is larger than the thickness of the adhesive layer.
7. The power storage device outer packaging material according to claim 1 , wherein the heat-sealable resin layer includes a first heat-sealable resin layer and a second heat-sealable resin layer in this order from the surface side of the laminate, and the thickness of the second heat-sealable resin layer is larger than the thickness of the first heat-sealable resin layer.
8. The power storage device outer packaging material according to claim 1 , wherein the heat-sealable resin layer includes a first heat-sealable resin layer and a second heat-sealable resin layer in this order from the surface side of the laminate, and the first heat-sealable resin layer and the second heat-sealable resin layer are formed of different resins.
9. The power storage device outer packaging material according to claim 1 , wherein
the adhesive layer is provided between the barrier layer and the heat-sealable resin layer,
the heat-sealable resin layer includes a first heat-sealable resin layer and a second heat-sealable resin layer in this order from the surface side of the laminate, and
the adhesive layer, the first heat-sealable resin layer and the second heat-sealable resin layer are co-extruded resin layers.
10. The power storage device outer packaging material according to claim 1 , wherein the heat-sealable resin layer includes the first heat-sealable resin layer forming a surface of the laminate, and a value obtained by measuring a temperature difference T 1 and a temperature difference T 2 in the first heat-sealable resin layer by the following method and dividing the temperature difference T 2 by the temperature difference T 1 is 0.60 or more:
(measurement of temperature difference T 1 )
the temperature difference T 1 between an extrapolated melting start temperature and an extrapolated melting end temperature in the melting peak temperature of the first heat-sealable resin layer is measured by differential scanning calorimetry; and
(measurement of temperature difference T 2 )
the first heat-sealable resin layer is left to stand for 72 hours in an electrolytic solution in which the concentration of lithium hexafluorophosphate is 1 mol/l and the volume ratio of ethylene carbonate, diethyl carbonate, and dimethyl carbonate is 1:1:1 and the resin is then sufficiently dried in an environment at a temperature of 85° C., and the temperature difference T 2 between an extrapolated melting start temperature and an extrapolated melting end temperature in the melting peak temperature of the first heat-sealable resin layer after drying is measured by differential scanning calorimetry.
11. The power storage device outer packaging material according to claim 6 , wherein a lubricant is present on a surface of the first heat-sealable resin layer.
12. A method for producing a power storage device outer packaging material, comprising the step of laminating at least a base material layer, a barrier layer and a heat-sealable resin layer in this order to obtain a laminate,
the heat-sealable resin layer including a single layer or multiple layers,
the heat-sealable resin layer including at least one layer having a hardness of 70 MPa or more as measured from a cross-section in a lamination direction of the laminate under a load of indentation of 100 μN in a nanoindentation method.
13. A power storage device in which a power storage device element including at least a positive electrode, a negative electrode and an electrolyte is stored in a packaging formed of the power storage device outer packaging material according to claim 1 .