Process and apparatus for the preparation of alkylene glycol

1. A process for the preparation of an alkylene glycol from an alkene comprising steps of:

a. supplying a gas composition comprising alkylene oxide, alkene, oxygen, carbon dioxide and water vapour to an alkylene oxide absorber through a gas inlet, the absorber comprising an absorption section of vertically stacked trays and a sump at the bottom of the absorber, and allowing the gas composition to pass upwards through the absorption section;

b. supplying a lean absorbent to the top of the absorption section and allowing the lean absorbent to pass downwards through the absorption section;

c. intimately contacting the gas composition with lean absorbent on the trays in the absorption section in the presence of one or more catalysts that promote carboxylation and hydrolysis; and

d. withdrawing fat absorbent from the absorption section and passing the fat absorbent and any liquid condensate through the sump, wherein the sump comprises one or more baffles that define a flow pathway that approximate plug flow between a sump inlet to a sump outlet between the one or more baffles.

2. The process of claim 1 wherein the fat absorbent and any liquid condensate is collected on a tray below the gas inlet.

3. The process of claim 1 wherein the fat absorbent is collected on a tray above the gas inlet and any liquid condensate is collected on a tray below the gas inlet.

4. The process of claim 2 wherein the tray below the gas inlet is directly above the sump and separates the sump from the rest of the absorber.

5. The process of claim 1 wherein the sump comprises at least two baffles.

6. The process of claim 1 wherein the alkylene oxide comprises ethylene oxide (EO) and the amount of EO in the fat absorbent leaving the sump is less than 100 ppm.

7. The process of claim 1 further comprising a heater downstream of the sump outlet to heat the fat absorbent stream to a temperature in the range of from 130 to 170° C.