IP Library Granted Patent US 11,787,740
Granted Patent B2
US 11,787,740 · App. 17/302,088 · Granted Oct 17, 2023

Asphalt binders and bituminous compositions comprising naphthenic acid esters

Inventor: Perry Eyster (Brownsburg, IN)
Assignee: Heritage Research Group
C04B26/26C04B24/045C08K5/101C08L95/00C08L2555/22C08L2555/34C08L2555/60
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Quick Facts
Patent No.
US 11,787,740
App. No.
17/302,088
Granted
Oct 17, 2023
Kind
B2
Abstract

Asphalt binders and bituminous compositions comprising additives such as naphthenic acid esters. In certain embodiments the ester compounds may be useful as rheology modifiers for use in bituminous binders in road paving applications.

Claims (33)

1. A composition comprising:

a bituminous binder; and

a rheology modifier comprising at least one naphthenic ester.

2. The composition according to claim 1 , wherein the bituminous binder comprises at least one of a reclaimed asphalt pavement binder, a reclaimed asphalt shingle binder, a virgin binder, or a performance-grade binder.

3. The composition according to claim 2 , wherein the bituminous binder comprises a reclaimed asphalt pavement binder.

4. The composition according to claim 2 , wherein the bituminous binder comprises a reclaimed asphalt shingle binder.

5. The composition according to claim 2 , wherein the bituminous binder comprises a virgin binder.

6. The composition according to claim 2 , wherein the bituminous binder comprises a performance-grade binder.

7. The composition according to claim 6 , wherein the bituminous binder comprises at least one of a PG 58-28 binder, PG 52-34 binder, PG 58-34 binder, PG 64-28 binder, PG 64-22 binder, a PG 58-31 binder, a PG 58-37 binder, a PG 58-40 binder, a PG 64-25 binder, or a PG 64-31 binder.

8. The composition according to claim 1 , wherein the bituminous binder further comprises at least one polymeric material.

9. The composition according to claim 8 , wherein the polymeric material comprises at least one of an elastomer or a rubber.

10. A composition comprising:

a recycled asphalt material containing aged bitumen and an aggregate; and

at least one naphthenic acid ester.

11. The composition of claim 10 , further comprising virgin bitumen binder.

12. The composition according to claim 10 , wherein the at least one naphthenic acid ester is present in about 0.10 to about 1.0 wt. % of the total weight of the recycled asphalt material.

13. The composition according to claim 12 , wherein the at least one naphthenic ester is present in about 0.5 wt. % of the total weight of the recycled asphalt material.

14. A hot-mix asphalt composition comprising:

a recycled asphalt material containing aged bitumen and an aggregate:

virgin binder; and

at least one naphthenic acid triglyceride.

15. The composition of claim 10 , wherein the naphthenic acid ester contains a naphthenic acid residue content of at least 60 wt. %.

16. The composition of claim 15 , wherein the naphthenic acid ester contains a naphthenic acid residue content of at least 75 wt. %.

17. The composition of claim 16 , wherein the naphthenic acid ester contains a naphthenic acid residue content of at least 80 wt. %.

18. A method of preparing a rejuvenated asphalt, comprising:

selecting a reclaimed asphalt; and

contacting it with at least one naphthenic ester.

19. The method of claim 18 , wherein the reclaimed asphalt comprises RAP or RAS.

20. A rejuvenated asphalt comprising a reclaimed asphalt and at least one naphthenic ester.

21. The rejuvenated asphalt of claim 20 , wherein the naphthenic ester comprises about 0.1 to about 5 wt. % of the rejuvenated asphalt.

22. The rejuvenated asphalt of claim 20 , wherein the naphthenic ester comprises about 0.5 to about 1 wt. % of the rejuvenated asphalt.

23. The rejuvenated asphalt of claim 20 , wherein the reclaimed asphalt comprises an aged bitumen.

24. The rejuvenated asphalt of claim 20 , wherein the reclaimed asphalt further comprises an aggregate.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 23, 2021
From: HERITAGE RESEARCH GROUP
To: HERITAGE RESEARCH GROUP, LLC
Reel/Frame 057264/0328 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 23, 2021
From: EYSTER, PERRY
To: HERITAGE RESEARCH GROUP
Reel/Frame 056018/0273 →
Continuity (3)
Continuation PCTUS2019057409 · Oct 22, 2019
Provisional Application 62749917 · Oct 24, 2018
Related Publication 20210238093A1 · Aug 5, 2021