IP Library › Granted Patent US 12,435,287
Granted Patent B2
US 12,435,287 · App. 17/312,989 · Granted Oct 7, 2025

Blending of renewable fuels

Inventors: Jenni Nortio (Porvoo, FI); Kati Sandberg (Porvoo, FI)
Assignee: Neste Oyj
C10L1/08C10L10/14C10L2200/043C10L2200/0484C10L2270/04C10L2290/24
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,435,287
App. No.
17/312,989
Granted
Oct 7, 2025
Kind
B2
Abstract

An aviation fuel composition is disclosed, containing 50-95 vol-% of petroleum-derived jet fuel component, and 5-50 vol-% of renewable middle distillate component. The fuel composition has a viscosity of 12 mm2/s or below at −40° C., 10 mm2/s or below at −30° C., and 8 mm2/s or below at −20° C., as measured in accordance with an EN ISO 3104 (1996) standard. A method for producing the aviation fuel composition is also disclosed. The method containing mixing the petroleum derived jet fuel component and the renewable middle distillate component to obtain the aviation fuel composition, such that the petroleum-derived jet fuel component and the renewable middle distillate component are mixed together in an amount containing 5-50 vol-% of renewable middle distillate component and about 50-95 vol-% of petroleum-derived jet fuel component.

Claims (60)

1. An aviation fuel blend having a measured viscosity of 12 mm 2 /s or below at −40° C., and 10 mm 2 /s or below at −30° C., measured in accordance with an EN ISO 3104 (1996) standard, which measured viscosity is at least 0.032 mm 2 /s lower than a calculated viscosity Cs B for the aviation fuel blend, the calculated viscosity Cs B being calculated for the aviation fuel blend based on viscosities of individual fuels thereof at a respective temperature by using a formula (III):

Cs B =EXP([(VBI B )*LN(1000)]/[1−VBI B ])  (III),

where VBI B =ΣV i VBI i ,

where V i is a volume ratio of an individual fuel, and

VBI i =[LN(Cs i )]/[LN(1000*Cs i )],

where VBi is a viscosity index for an individual fuel, and

Cs i is a viscosity of an individual fuel;

the aviation fuel blend consisting of individual fuels of petroleum-derived jet fuel in an amount of up to 95 vol-% mixed with renewable paraffinic middle distillate fuel in an amount of 5-40 vol-%;

wherein the renewable paraffinic middle distillate fuel is from vegetable oil, animal fat, fish fat, palm oil, rapeseed oil, cooking oil, biogas, algae oil, and/or microbial oil, and/or

wherein the renewable paraffinic middle distillate fuel is from hydrogenated fatty acid materials and/or hydrogenated triglyceride materials;

wherein the petroleum-derived jet fuel complies with at least one aviation fuel standard selected from ASTM D1655, DEFSTAN 91-91, JET A, and JET A-1;

wherein the renewable paraffinic middle distillate fuel is produced via a Fischer-Tropsch process and isomerisation, and/or wherein the renewable paraffinic middle distillate fuel is produced via hydrodeoxygenation and isomerisation, and

wherein the renewable paraffinic middle distillate fuel contains aromatic compounds in an amount of at most 0.5 vol-% and iso-paraffins in an amount of at least 80 vol-%, the rest being other paraffins and the renewable paraffinic middle distillate fuel comprises at least 70 wt-% of C15 to C18 paraffins.

2. The aviation fuel blend as claimed in claim 1 , wherein the viscosities of the individual fuels are measured in accordance with the EN ISO 3104 (1996) standard.

3. The aviation fuel blend according to claim 1 , wherein the renewable paraffinic middle distillate fuel has a distillation range from 130° C. to 320° C.

4. The aviation fuel blend according to claim 3 , wherein the renewable paraffinic middle distillate fuel has a distillation range from 130° C. to 290° C.

5. The aviation fuel blend as claimed in claim 4 , wherein the aviation fuel blend contains 30 vol-% to 40 vol-% of renewable paraffinic middle distillate fuel.

6. The aviation fuel blend as claimed in claim 4 , wherein the aviation fuel blend contains 5 vol-% to 30 vol-% of renewable paraffinic middle distillate fuel.

7. The aviation fuel blend according to claim 3 , wherein the renewable paraffinic middle distillate fuel has distillation range from 170° C. to 320° C.

8. The aviation fuel blend as claimed in claim 7 , wherein the aviation fuel blend contains from 10 vol-% to 15 vol-% of renewable paraffinic middle distillate fuel.

9. The aviation fuel blend as claimed in claim 7 , wherein the aviation fuel blend contains from 10 vol-% to 40 vol-% of the renewable paraffinic middle distillate fuel.

10. The aviation fuel blend as claimed in claim 1 , wherein the renewable paraffinic middle distillate fuel is an iso-paraffinic middle distillate fuel.

11. The aviation fuel blend as claimed in claim 1 , wherein the renewable paraffinic middle distillate fuel contains:

more than 85 wt-% of C15 to C18 paraffins;

less than 20 wt-% of paraffins smaller than C15 paraffins; and

less than 10 wt-% of paraffins larger than C18 paraffins.

12. The aviation fuel blend as claimed in claim 1 ,

wherein the aviation fuel blend has a measured viscosity of 8 mm 2 /s or below at −20° C. measured in accordance with an EN ISO 3104 (1996) standard.

13. The aviation fuel blend as claimed in claim 1 , wherein the renewable paraffinic middle distillate fuel contains:

more than 90 wt-% of C15 to C18 paraffins;

less than 7 wt-% of paraffins smaller than C15 paraffins; and

less than 3 wt-% of paraffins larger than C18 paraffins.

14. The aviation fuel blend as claimed in claim 1 , wherein said other paraffins are n-paraffins and/or cyclic paraffins.

15. The aviation fuel blend as claimed in claim 1 , wherein the renewable paraffinic middle distillate fuel is from biogas, algae oil and/or microbial oil, wherein the renewable paraffinic middle distillate fuel is from waste materials and/or residue materials.

16. A method for producing an aviation fuel blend having a measured viscosity of 12 mm 2 /s or below at −40° C., and 10 mm 2 /s or below at −30° C., measured in accordance with an EN ISO 3104 (1996) standard, which measured viscosity is at least 0.032 mm 2 /s lower than a calculated viscosity Cs B for the aviation fuel blend, the calculated viscosity Cs B being calculated for the aviation fuel blend based on viscosities of the individual fuels thereof at a respective temperature by using a formula (III):

Cs B =EXP([(VBI B )*LN(1000)]/[1−VBI B ])  (III),

where VBI B =ΣV i VBI i ,

where V i is a volume ratio of an individual fuel, and

VBI i =[LN(Cs i )]/[LN(1000*Cs i )],

where VBi is a viscosity index for an individual fuel, and

Cs i is a viscosity of an individual fuel,

the method comprising:

mixing individual fuels of petroleum derived jet fuel, and renewable paraffinic middle distillate fuel, together in an amount consisting of 5-40 vol-% of renewable paraffinic middle distillate fuel and up to 95 vol-% of petroleum-derived jet fuel;

the method also comprising producing the renewable paraffinic middle distillate fuel from vegetable oil, animal fat, fish fat, palm oil, rapeseed oil, cooking oil, biogas, algae oil and/or microbial oil,

and/or

the method also comprising producing the renewable paraffinic middle distillate fuel from hydrogenated fatty acid materials and/or hydrogenated triglyceride materials;

wherein the petroleum-derived jet fuel complies with at least one aviation fuel standard selected from ASTM D1655, DEFSTAN 91-91, JET A, and JET A-1;

wherein the renewable paraffinic middle distillate fuel is produced via a Fischer-Tropsch process and isomerisation, and/or wherein the renewable paraffinic middle distillate fuel is produced via hydrodeoxygenation and isomerisation; and

wherein the renewable paraffinic middle distillate fuel contains aromatic compounds in an amount of at most 0.5 vol-% and iso-paraffins in an amount of at least 80 vol-%, the rest being other paraffins and the renewable paraffinic middle distillate fuel comprises at least 70 wt-% of C15 to C18 paraffins.

17. The method as claimed in claim 16 , wherein the renewable paraffinic middle distillate fuel has distillation range from 130° C. to 320° C.

18. The method as claimed in claim 17 , wherein the renewable paraffinic middle distillate fuel has distillation range from 130° C. to 290° C.

19. The method as claimed in claim 18 , wherein the aviation fuel blend contains 5 vol-% to 30 vol-% of renewable paraffinic middle distillate fuel.

20. The method as claimed in claim 18 , wherein the aviation fuel blend contains 30 vol-% to 40 vol-% of renewable paraffinic middle distillate fuel.

21. The method as claimed in claim 16 , wherein the renewable paraffinic middle distillate fuel has a distillation range from 170° C. to 320° C.

22. The method as claimed in claim 21 , wherein the aviation fuel blend contains from 10 vol-% to 40 vol-% of the renewable paraffinic middle distillate fuel.

23. The method as claimed in claim 21 , wherein the aviation fuel blend contains from 10 vol-% to 15 vol-% of renewable paraffinic middle distillate fuel.

24. The method as claimed in claim 16 , wherein the viscosities of the individual fuels are measured in accordance with the EN ISO 3104 (1996) standard.

25. The method as claimed in claim 16 , wherein the aviation fuel blend has a measured viscosity of 8 mm 2 /s or below at −20° C. measured in accordance with an EN ISO 3104 (1996) standard.

26. The method as claimed in claim 16 , wherein said other paraffins are n-paraffins and/or cyclic paraffins.

27. The method as claimed in claim 16 , wherein the method comprises producing the renewable paraffinic middle distillate fuel from the biogas, the algae oil and/or the microbial oil, the biogas, the algae oil and/or the microbial oil being waste materials and/or residue materials.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 7, 2021
From: NORTIO, JENNI; SANDBERG, KATI
To: NESTE OYJ
Reel/Frame 057731/0071 →
Priority Claims (1)
FI 20186074 · Dec 13, 2018 · national
Continuity (1)
Related Publication 20220064557A1 · Mar 3, 2022
References Cited (29)
US 8975461B2 · Peters · 2015 [cited by examiner]
US 11566193B2 · Sandberg et al. · 2023 [cited by applicant]
US 20080244962A1 · Abhari · 2008 [cited by examiner]
US 20090301930A1 · Brandvold et al. · 2009 [cited by applicant]
US 20130102817A1 · Dahlstrom · 2013 [cited by examiner]
US 20170183593A1 · Sandberg · 2017 [cited by examiner]
US 20170327757A1 · Abhari et al. · 2017 [cited by applicant]
US 20190002778A1 · Sandberg et al. · 2019 [cited by applicant]
CN 106929094A · 2017 [cited by applicant]
CN 108699459A · 2018 [cited by applicant]
WO 2018109278A1 · 2018 [cited by applicant]
Finnish Search Report dated Apr. 4, 2019, issued by the Finnish Patent and Registration Office in the corresponding Finnish Patent Application No. 20186074. [cited by applicant]
International Search Report (PCT/ISA/210) and Written Opinion (PCT/ISA/237) mailed on Feb. 10, 2020, by the European Patent Office as the International Searching Authority for International Application No. PCT/FI2019/05… [cited by applicant]
Notification of Transmittal of The International Preliminary Report on Patentability (PCT Rule 71.1) (Form PCT/IPEA/416), International Preliminary Report on Patentability (PCT Article 36 and Rule 70) (Form PCT/IPEA/409… [cited by applicant]
Chuck, C. J. et al., “The compatibility of potential bioderived fuels with Jet A-1 aviation kerosene”, Applied Energy, vol. 118, pp. 83-91, Jan. 8, 2014. [cited by applicant]
Corporan, E. et al., Alternative Fuels Tests on a C-17 Aircraft: Emissions Characteristics. AFRL-RZ-WP-TR-2011-2004, 33 pages, Dec. 2010. [cited by applicant]
Corporan, E. et al., “Chemical, Thermal Stability, Seal Swell, and Emissions Studies of Alternative Jet Fuels”, Energy Fuels, vol. 25, pp. 955-966, Mar. 2, 2011. [cited by applicant]
Edwards, J. T. et al., “U.S. Air Force Hydroprocessed Renewable Jet (HRJ) Fuel Research”, AFRL-RQ-WP-TR-2013-0108, 92 pages, Jul. 2012. [cited by applicant]
Gutierrez-Antonio, C. et al., “A review on the production processes of renewable jet fuel”, Renewable and Sustainable Energy Reviews, vol. 79, pp. 709-729, May 24, 2017. [cited by applicant]
Hong, T. D. et al., “A study on developing aviation biofuel for the Tropics: Production process—Experimental and theoretical evaluation of their blends with fossil kerosene”, Chemical Engineering and Processing, vol. 74… [cited by applicant]
Kinder, J. D. et al., “Evaluation of Bio-Derived Synthetic Paraffinic Kerosene (Bio-SPK)”, 16 pages, Jun. 2009. [cited by applicant]
Llamas, A. et al., “Biokerosene from coconut and palm kernel oils: Production and properties of their blends with fossil kerosene”, Fuel, vol. 102, pp. 483-490, Jul. 17, 2012. [cited by applicant]
Moses, C. et al., “Qualification of SASOL Semi-synthetic Jet A-1 as Commercial Jet Fuel”, South West Research Institute Pblicatio—SWR, No. SwRl-8531, pp. 1-46, Nov. 1, 1997, XP008095497. [cited by applicant]
Pires, A. P. P. et al., “Chemical Composition and Fuel Properties of Alternative Jet Fuels”, Bioresources, vol. 13, No. 2, pp. 2632-2657, May 2018. [cited by applicant]
Starck, L. et al., “Production of Hydroprocessed Esters and Fatty Acids (HEFA)—Optimisation of Process Yield”, Oil & Gas Science and Technology—Rev. IFP Energies Nouvelles, vol. 71, No. 1, Jan. 22, 2016. [cited by applicant]
Striebich, R. et al., “Dependence of Fuel Properties During Blending of ISO-Paraffinic Kerosene and Petroleum-Derived Jet Fuel”, URL:http://www.dtic.mil/dtic/tr/fulltext/u2/a504691.pdf, Nov. 1, 2008, XP055491760. [cited by applicant]
Wang, W.-C. et al., “Review of Biojet Fuel Conversion Technologies”, National Renewable Energy Laboratory (NREL), Technical Report, 106 pages, Jul. 2016. [cited by applicant]
First Office Action issued on Aug. 15, 2022, by the Chinese Patent Office in corresponding Chinese Patent Application No. 201980077358.5, and an English Translation of the Office Action. (16 pages). [cited by applicant]
Office Action (Notification of the Second Office Action) issued on Mar. 30, 2023, by the Chinese Patent Office in corresponding Chinese Patent Application No. 201980077358.5, and an English Translation of the Office Act… [cited by applicant]