Solvothermal synthesis of metal alkanoate and metal oxide nanoparticles
View Patent ↗A facile solvothermal method can be used to synthesize metal alkanoate nanoparticles using a metal nitrate precursor, alcohol/water, and alkanoic acid. The method can produce lanthanide (e.g., La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, or Yb) and transition metal (e.g., Ag, Co, Cu, or Pb) alkanoate nanoparticles (<100 nm) with spherical morphology. These hybrid nanomaterials adopt a lamellar structure consisting of inorganic metal cation layers separated by an alkanoate anion bilayer and exhibit liquid crystalline phases during melting. The metal alkanoate nanoparticles can be calcined to produce metal oxide nanoparticles.
1. A solvothermal method to synthesize metal alkanoate nanoparticles, comprising the steps of:
dissolving a metal nitrate precursor in water to provide an aqueous precursor solution,
dissolving an alkanoic acid in an alcohol to provide an alkanoate solution,
mixing the aqueous metal precursor solution with the alkanoate solution to provide a mixed solution,
heating the mixed solution by microwave irradiation to a reaction temperature to form a metal alkanoate precipitate in a solvent,
isolating the metal alkanoate precipitate from the solvent, and
washing the metal alkanoate precipitate to provide a powder comprising metal alkanoate nanoparticles.
2. The method of claim 1 , wherein the metal comprises a lanthanide.
3. The method of claim 2 , wherein the lanthanide comprises La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, or Yb.
4. The method of claim 1 , wherein the metal comprises a transition metal.
5. The method of claim 4 , wherein the transition metal comprises Ag, Co, Cu, or Pb.
6. The method of claim 1 , wherein the alkanoic acid comprises decanoic acid and the metal alkanoate comprises lanthanide decanoate.
7. The method of claim 1 , wherein the alcohol comprises a short-chain alcohol.
8. The method of claim 7 , wherein the short-chain alcohol comprises methanol, ethanol, propanol, or butanol.
9. The method of claim 1 , wherein the reaction temperature is greater than 80° C.
10. The method of claim 1 , wherein the metal alkanoate comprises a di- or tri-valent metal cation coordinated to the carboxy group of an alkanoate anion with 4 to 22 carbon atoms in the alkyl chain.
11. The method of claim 1 , further comprising calcining the metal alkanoate nanoparticles at a calcination temperature to provide metal oxide nanoparticles.
12. The method of claim 11 , wherein the calcination temperature is greater than 400° C.
13. The method of claim 11 , wherein the metal alkanoate nanoparticles comprise lanthanide alkanoate nanoparticles and the metal oxide nanoparticles comprise lanthanide oxide nanoparticles.