IP Library Granted Patent US 12,416,069
Granted Patent B2
US 12,416,069 · App. 17/335,274 · Granted Sep 16, 2025

Thermomechanically processed, nanostructure aluminum-rare earth element alloys

Inventors: Hunter Bryant Henderson (Livermore, CA); David Weiss (Manitowoc, WI); Ryan T. Ott (Ames, IA); Orlando Rios (Knoxville, TN)
Assignees: Lawrence Livermore National Security, LLC; Eck Industries, Inc.; Iowa State University Research Foundation, Inc.; University of Tennessee Research Foundation
C22C21/10B22F1/05B22F2301/052
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Quick Facts
Patent No.
US 12,416,069
App. No.
17/335,274
Granted
Sep 16, 2025
Kind
B2
Abstract

A product includes a material having aluminum and at least one rare earth element (REE). The material includes the following microstructure features: at least 1 volume % particles of a phase of an aluminum-rare earth element alloy, the particles comprise at least 5 weight % of the at least one rare earth element, the particles have an average aspect ratio less than or equal to 5, and an average interparticle spacing between the particles is less than or equal to 1 μm. A method includes forming a base material, the base material having aluminum and at least one rare earth element (REE), and working the base material to form a product.

Claims (47)

1. A product, comprising:

a material having aluminum and at least one rare earth element (REE),

the material having the following microstructure features:

at least 1 volume % particles of a phase of an aluminum-rare earth element alloy,

wherein the particles comprise at least 5 weight % of the at least one rare earth element,

wherein the particles have an average aspect ratio less than or equal to 5, and

wherein at least 20% by volume of the particles of the aluminum-rare earth element alloy have a particle size above 100 nm.

2. The product of claim 1 , wherein the at least one rare earth element includes cerium (Ce).

3. The product of claim 1 , wherein the at least one rare earth element is selected from the group consisting of: scandium (Sc), yttrium (Y), lanthanum (La), praseodymium (Pr), neodymium (Nd), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu).

4. The product of claim 1 , wherein the at least one rare earth element includes mischmetal.

5. The product of claim 1 , wherein the at least one rare earth element is present in a weight percentage of the material in a range of about 4% to about 20%.

6. The product of claim 1 , wherein the material comprises at least two rare earth elements.

7. The product of claim 1 , wherein the material comprises at least one additional element, wherein the at least one additional element is selected from the group consisting of: magnesium (Mg), copper (Cu), manganese (Mn), and nickel (Ni), wherein the at least one additional element is present in a weight percentage of the material in a range of greater than 0% to about 15%.

8. The product of claim 7 , wherein the material is configured for use in an application selected from the group consisting of: an electric vehicle battery, an internal engine component, a reciprocating component, a piston, a brake rotor, a cylinder head, and a suspension component.

9. The product of claim 1 , wherein the material comprises silicon (Si) present in a weight percentage of the material in a range of greater than 0% to about 25%.

10. The product of claim 1 , wherein the material comprises zinc (Zn) present in a weight percentage of the material in a range of greater than 0% to about 75%.

11. The product of claim 1 , wherein the material comprises at least one additional element selected from the group consisting of: zirconium (Zr), scandium (Sc), titanium (Ti), and chromium (Cr), wherein the at least one additional element is present in a weight percentage of the material in a range of greater than 0% to about 2%.

12. The product of claim 1 , wherein the material comprises at least one additional element selected from the group consisting of: iron (Fe), lithium (Li), and silver (Ag), wherein the at least one additional element is present in a weight percentage of the material in a range of greater than 0% to about 5%.

13. The product of claim 1 , wherein the microstructure features are characterized as having about 80% of an internal particle volume fraction thereof having an internal particle size dispersion in a range from about 5 nm to about 200 nm.

14. A method, comprising:

forming the material having aluminum and at least one rare earth element (REE) as recited in claim 1 ; and

working the material to form the product.

15. The product of claim 1 , wherein the material consists of the aluminum and the at least one rare earth element.

16. The product of claim 1 , wherein the at least one rare earth element is present in a weight percentage of the material in a range of greater than 8% to less than 18%.

17. The product of claim 1 , wherein the material comprises magnesium (Mg) present in a weight percentage of the material in a range of greater than 0% to about 15%.

a material having aluminum and at least one rare earth element (REE),

the material having the following microstructure features:

at least 1 volume % particles of a phase of an aluminum-rare earth element alloy,

wherein the particles comprise at least 5 weight % of the at least one rare earth element,

wherein the particles have an average aspect ratio less than or equal to 5,

wherein an average interparticle spacing between the particles is less than or equal to 1 μm, and

wherein at least 20% by volume of the particles of the aluminum-rare earth element alloy have a particle size above 100 nm.

18. A product, comprising:

a material having aluminum and at least one rare earth element (REE),

the material having the following microstructure features:

at least 1 volume % particles of a phase of an aluminum-rare earth element alloy,

wherein the particles comprise at least 5 weight % of the at least one rare earth element,

wherein an average interparticle spacing between the particles is less than or equal to 1 μm, and

wherein at least 20% by volume of the particles of the aluminum-rare earth element alloy have a particle size above 100 nm.

19. A product, comprising:

a material having aluminum and at least one rare earth element (REE),

the material having the following microstructure features:

at least 1 volume % particles of a phase of an aluminum-rare earth element alloy,

wherein the particles comprise at least 5 weight % of the at least one rare earth element,

wherein an average interparticle spacing between the particles is less than or equal to 1 μm, and

wherein at least 20% by volume of the particles of the aluminum-rare earth element alloy have a particle size above 100 nm.

20. The product of claim 18 , comprising an object selected from the group consisting of: an electric vehicle battery, an internal engine component, a reciprocating component, a piston, a brake rotor, a cylinder head, and a suspension component; at least a portion of the object being formed of the material.

Assignments (8)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 24, 2022
From: RIOS, ORLANDO
To: UT-BATTELLE, LLC
Reel/Frame 059994/0380 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 24, 2022
From: WEISS, DAVID
To: ECK INDUSTRIES INCORPORATED
Reel/Frame 059994/0512 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 19, 2022
From: RIOS, ORLANDO
To: UNIVERSITY OF TENNESSEE RESEARCH FOUNDATION
Reel/Frame 059636/0803 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 19, 2022
From: OTT, RYAN T.
To: IOWA STATE UNIVERSITY RESEARCH FOUNDATION, INC.
Reel/Frame 059640/0131 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 19, 2022
From: HENDERSON, HUNTER BRYANT
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 059636/0397 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 19, 2022
From: WEISS, DAVID
To: ECK INDUSTRIES, INC.
Reel/Frame 059636/0549 →
CONFIRMATORY LICENSE Recorded Jul 22, 2021
From: IOWA STATE UNIVERSITY
To: UNITED STATES DEPARTMENT OF ENERGY
Reel/Frame 056941/0856 →
CONFIRMATORY LICENSE Recorded Jul 2, 2021
From: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
To: U.S DEPARTMENT OF ENERGY
Reel/Frame 056753/0701 →
Continuity (1)
Related Publication 20220380870A1 · Dec 1, 2022
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Cited By (1)
US 12,529,157