IP Library › Granted Patent US 12,145,879
Granted Patent B2
US 12,145,879 · App. 17/339,088 · Granted Nov 19, 2024

Chemically strengthened glass plate, and cover glass and electronic device comprising chemically strengthened glass

Inventors: Takumi Umada (Tokyo, JP); Kenji Imakita (Tokyo, JP); Yusuke Arai (Tokyo, JP); Qing Li (Tokyo, JP)
Assignee: AGC Inc.
C03C3/083C03C10/0027
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Quick Facts
Patent No.
US 12,145,879
App. No.
17/339,088
Granted
Nov 19, 2024
Kind
B2
Abstract

The present invention relates to a chemically strengthened glass sheet in which a value of SB/(SA×t) is 5.0 mm −1 or more, where SA (MPa·μm) is an integrated value of a compressive stress from a surface of the glass sheet to a depth of 10 μm, SB (MPa·μm) is an integrated value of a compressive stress from the depth of 10 μm to DOL which is a depth at which the compressive stress is zero, and t (mm) is a thickness of the glass sheet.

Claims (24)

1. A chemically strengthened glass sheet, wherein the chemically strengthened glass sheet has a value of SB/(SA×t) of 5.0 mm −1 or more, where SA (MPa·μm) is an integrated value of a compressive stress from a surface of the glass sheet to a depth of 10 μm, SB (MPa·μm) is an integrated value of a compressive stress from the depth of 10 μm to DOL which is a depth at which the compressive stress is zero, t (mm) is a thickness of the glass sheet, and SA is 4,000 MPa·μm or less and SB is 12,000 MPa·μm or more.

2. The chemically strengthened glass sheet according to claim 1 , wherein the DOL is 110 μm or more.

3. The chemically strengthened glass sheet according to claim 1 , wherein the chemically strengthened glass sheet has a four-point bending strength of 600 MPa or more.

4. The chemically strengthened glass sheet according to claim 1 , wherein the chemically strengthened glass sheet has a compressive stress value of 150 MPa or more at a position of a depth of 50 μm from the surface.

5. The chemically strengthened glass sheet according to claim 1 , wherein the chemically strengthened glass sheet has a surface compressive stress value of 500 MPa or more.

6. The chemically strengthened glass sheet according to claim 1 , wherein the chemically strengthened glass sheet has a base composition comprising, in terms of mol % on an oxide basis, 40-60% of SiO 2 , 20-45% of Al 2 O 3 and 5-15% of Li 2 O.

7. The chemically strengthened glass sheet according to claim 1 , wherein the chemically strengthened glass sheet is a crystallized glass comprising one or more crystals selected from the group consisting of a β-spodumene crystal, a lithium metasilicate crystal, and a lithium phosphate crystal.

8. The chemically strengthened glass sheet according to claim 7 , wherein the crystallized glass comprises the β-spodumene crystal comprising, in terms of mass % on an oxide basis, 58-70 mass % of SiO 2 , 15-30 mass % of Al 2 O 3 , 2-10 mass % of Li 2 O, 0-5 mass % of Na 2 O, and 0-2 mass % of K 2 O, and having a total content of Na 2 O and K 2 O of 1-5 mass %.

9. A cover glass, comprising:

the chemically strengthened glass sheet of claim 1 .

10. An electronic device, comprising:

the chemically strengthened glass sheet of claim 1 .

11. The chemically strengthened glass sheet according to claim 1 , wherein a sum (SA+SB) of SA and SB is 15,000 MPa·μm or more.

12. The chemically strengthened glass sheet according to claim 11 , wherein the DOL is 110 μm or more.

13. The chemically strengthened glass sheet according to claim 11 , wherein the chemically strengthened glass sheet has a four-point bending strength of 600 MPa or more.

14. The chemically strengthened glass sheet according to claim 11 , wherein the chemically strengthened glass sheet has a compressive stress value of 150 MPa or more at a position of a depth of 50 μm from the surface.

15. The chemically strengthened glass sheet according to claim 11 , wherein the chemically strengthened glass sheet has a surface compressive stress value of 500 MPa or more.

16. The chemically strengthened glass sheet according to claim 1 , wherein the chemically strengthened glass sheet has a base composition comprising, in terms of mol % on an oxide basis, 40-60% of SiO 2 , 20-45% of Al 2 O 3 and 5-15% of Li 2 O.

17. The chemically strengthened glass sheet according to claim 11 , wherein the chemically strengthened glass sheet is a crystallized glass comprising one or more crystals selected from the group consisting of a β-spodumene crystal, a lithium metasilicate crystal, and a lithium phosphate crystal.

18. The chemically strengthened glass sheet according to claim 17 , wherein the crystallized glass comprises the β-spodumene crystal comprising, in terms of mass % on an oxide basis, 58-70 mass % of SiO 2 , 15-30 mass % of Al 2 O 3 , 2-10 mass % of Li 2 O, 0-5 mass % of Na 2 O, and 0-2 mass % of K 2 O, and having a total content of Na 2 O and K 2 O of 1-5 mass %.

19. A cover glass, comprising:

the chemically strengthened glass sheet of claim 11 .

20. An electronic device, comprising:

the chemically strengthened glass sheet of claim 11 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 4, 2021
From: UMADA, TAKUMI; IMAKITA, KENJI; ARAI, YUSUKE; LI, QING
To: AGC INC.
Reel/Frame 056486/0872 →
Priority Claims (1)
JP 2018-231776 · Dec 11, 2018 · national
Continuity (2)
Continuation PCTJP2019047189 · Dec 3, 2019
Related Publication 20210292225A1 · Sep 23, 2021