Method of purifying sodium bromide from waste circuit boards pyrolysis coke
A method for purifying sodium bromide by the waste circuit board pyrolysis coke, belonging to the field of purifying sodium bromide and high-value utilization, and more particularly, relating to a method for reducing and purifying crude bromine salt enriched from waste circuit board smelting ash by using waste circuit boards pyrolysis coke. The main steps are as follows: carbonization conversion, purification filtration and vacuum exsolution. The pure sodium bromide crystal was obtained by reducing crude bromine salt enriched from waste circuit board smelting ash by using coke in waste circuit board pyrolysis residues, realizing the resource coupling and high-value utilization of the two wastes, avoiding the secondary pollution in the process of recycling the waste circuit boards. It has the characteristics of simple operation, high resource utilization rate and no tail liquid discharge.
1 . A method for purifying sodium bromide from waste circuit board pyrolysis coke, characterized by the following specific steps:
(1) carbonization conversion: crude bromine salt enriched from waste circuit board smelting ash is mixed with coke separated from waste circuit board pyrolysis residues to form a uniform mixture, the uniform mixture is heated to obtain carbon monoxide and crude sodium bromide, the carbon monoxide is collected and used as raw material of water gas, in which a mass of the coke is 0.1-1.0 kg per kilogram of the crude bromine salt, reaction temperature is 250-450° C., and reaction time is 1.0-2.0 h;
(2) purification filtration: the crude sodium bromide obtained in step (1) is added to distilled water for purification filtration to obtain impurity residues and sodium bromide solution, the impurity residues are centralizedly treated;
(3) vacuum exsolution: the sodium bromide solution obtained in step (2) is treated by vacuum exsolution to obtain sodium bromide crystal and exsolution mother liquor, and the exsolution mother liquor is returned to purification filtration process.
2 . A method for purifying sodium bromide from waste circuit board pyrolysis coke according to claim 1 , characterized in that, in the process of purification filtration, a liquid-solid volume mass ratio is 8:1-3:1 (L/kg), reaction temperature is 50-80° C., and reaction time is 20 -60 min.
3 . A method for purifying sodium bromide from waste circuit board pyrolysis coke according to claim 1 , characterized in that, in the process of vacuum exsolution, reaction time is 30-60 min and reaction temperature is 60-150° C.