“Flower-like” LI
A method of fabricating nanocomposite anode material embodying a lithium titanate (LTO)-multi-walled carbon nanotube (MWNT) composite intended for use in a lithium-ion battery includes providing multi-walled carbon nanotube (MWNTs), including nanotube surfaces, onto which functional oxygenated carboxylic acid moieties are arranged, generating 3D flower-like, lithium titanate (LTO) microspheres, including thin nanosheets and anchoring the acid-functionalized MWNTs onto surfaces of the 3D LTO microspheres by π-π interaction strategy to realize the nanocomposite anode material.
1. A nanocomposite anode material comprising a lithium titanate (LTO)-multi-walled carbon nanotube (MWNT) composite comprising a 3D-flower like lithium titanite (LTO) microsphere, a linker molecule having a terminal carboxylic acid group bonded to a conjugated aromatic ring, and an acid-functionalized MWNT, wherein the terminal carboxylic acid group of the linker molecule is bonded to the 3D-flower like LTO microsphere and the conjugated aromatic ring of the linker molecule is bonded, via π-π interaction, to an aromatic ring present in the acid-functionalized MWNT.
2. The nanocomposite anode material of claim 1 , wherein the conjugated aromatic ring is a conjugated phenyl ring.
3. The nanocomposite anode material of claim 1 , wherein the aromatic ring present in the acid-functionalized MWNT is a conjugated phenyl ring.
4. The nanocomposite anode material of claim 1 , wherein the linker molecule is 4-mercaptobenzoic acid.
5. The nanocomposite anode material of claim 1 , wherein the acid-functionalized MWNT comprises a MWNT having functional, oxygenated carboxylic acids moieties absorbed on the surface thereof.
6. The nanocomposite anode material of claim 1 , wherein the acid-functionalized MWNT has a diameter from 10 to 30 μm.
7. The nanocomposite anode material of claim 1 , wherein the terminal carboxylic acid group of the linker molecule is bonded to a Ti site on the 3D-flower like LTO microsphere.
8. The nanocomposite anode material of claim 1 , wherein the 3D-flower like LTO microsphere has a crystallite size of 12.6 nm.
9. A lithium-ion battery comprising an anode composed of a nanocomposite anode material comprising a lithium titanate (LTO)-multi-walled carbon nanotube (MWNT) composite comprising a 3D-flower like lithium titanite (LTO) microsphere, a linker molecule having a terminal carboxylic acid group bonded to a conjugated aromatic ring, and an acid-functionalized MWNT, wherein the terminal carboxylic acid group of the linker molecule is bonded to the 3D-flower like LTO microsphere and the conjugated aromatic ring of the linker molecule is bonded, via π-π interaction, to an aromatic ring present in the acid-functionalized MWNT.
10. The lithium-ion battery of claim 9 , wherein the conjugated aromatic ring is a conjugated phenyl ring.
11. The lithium-ion battery of claim 9 , wherein the aromatic ring present in the acid-functionalized MWNT is a conjugated phenyl ring.
12. The lithium-ion battery of claim 9 , wherein the linker molecule is 4-mercaptobenzoic acid.
13. The lithium-ion battery of claim 9 , wherein the acid-functionalized MWNT comprises a MWNT having functional, oxygenated carboxylic acids moieties absorbed on the surface thereof.
14. The lithium-ion battery of claim 9 , wherein the acid-functionalized MWNT has a diameter from 10 to 30 μm.
15. The lithium-ion battery of claim 9 , wherein the terminal carboxylic acid group of the linker molecule is bonded to a Ti site on the 3D-flower like LTO microsphere.
16. The lithium-ion battery of claim 9 , wherein the 3D-flower like LTO microsphere has a crystallite size of 12.6 nm.