Method for forming nanofiber nonwoven products
A method for tuning characteristics of a polyamide nanofiber nonwoven comprising the step of targeting a specific average nanofiber diameter and/or a specific relative viscosity for the polyamide nanofiber nonwoven. The specific average nanofiber diameter is within a range from 100 nm to 1000 nm and/or the specific relative viscosity is within a range from 5 to 75, e.g., from 15 to 50. The process further comprises the steps of extruding a polyamide composition having a moisture content with a pressurized gas through a fiber forming channel having a channel temperature to form the polyamide nanofiber nonwoven having the target average nanofiber diameter and/or relative viscosity and controlling the moisture content, the pressure of pressurized gas, and/or the channel temperature based on the specific average nanofiber diameter and/or the specific relative viscosity.
1. A method for producing a nanofiber nonwoven product comprising the steps of:
extruding a polyamide composition comprising N6, N66, N6T/66, N612, N6/66, N6I/66, N66/6I/6T, N11, and/or N12, wherein “N” means Nylon, having a moisture content, with a pressurized gas having a pressure ranging from 160 kPa to 220 kPa through a fiber forming channel having a channel temperature ranging from 270° C. to 315° C. to form nanofibers wherein less than 20% of the nanofibers have a fiber diameter of greater than 700 nm; and
collecting the nanofibers on a belt to form the nanofiber nonwoven product, wherein greater than 50% of the fibers in the nanofiber nonwoven product are the nanofibers;
wherein the polyamide nanofiber nonwoven product has an Air Permeability Value of less than 600 CFM/ft 2 , and
wherein the moisture content of the polyamide composition is controlled by drying the polyamide composition to have a moisture content from 0.005 wt. % to 1 wt. %, and rehydrating the dried polyamide composition.
2. The method of claim 1 , wherein the nanofiber nonwoven product has a basis weight of 150 GSM or less.
3. The method of claim 1 , wherein the nanofiber nonwoven product comprises less than 5000 ppm solvent.
4. The method of claim 1 , wherein the average nanofiber diameter of the nanofibers is within a range of 100 nm to 1000 nm.
5. The method of claim 1 , wherein the average nanofiber diameter of the nanofibers is within a range of 200 nm to 700 nm.
6. The method of claim 1 , wherein the relative viscosity of the nanofibers is within a range from 15 to 50.
7. A method for preparing a polyamide nanofiber nonwoven product, comprising:
(a) providing a polyamide composition comprising N6, N66, N6T/66, N612, N6/66, N6I/66, N66/6I/6T, N11, and/or N12, wherein “N” means Nylon, having a moisture content, and having a relative viscosity (RV) from 2 to 330 for spinning;
(b) spinning or melt blowing the polyamide composition at a temperature in the range of 215° C. to 315° C. into a plurality of nanofibers; and
(c) forming the nanofibers into the nanofiber nonwoven product, wherein the nanofiber nonwoven product has a RV from 2 to 330,
wherein polyamide nanofiber nonwoven product comprises from 1 to 20% of the nanofiber diameters are greater than 700 nanometers; and
wherein the polyamide nanofiber nonwoven product has an Air Permeability Value of less than 600 CFM/ft 2 ; and
wherein the moisture content is controlled by drying the polyamide composition to have a moisture content from 0.005 wt. % to 1 wt. %, and rehydrating the dried polyamide composition.
8. The method of claim 7 , wherein the polyamide nanofiber nonwoven product has a basis weight of 150 GSM or less.
9. The method of claim 7 , wherein the polyamide nanofiber nonwoven product comprises less than 5000 ppm solvent.
10. The method of claim 7 , wherein the average nanofiber diameter of the nanofibers is within a range of 100 nm to 1000 nm.
11. The method of claim 7 , wherein the average nanofiber diameter of the nanofibers is within a range of 200 nm to 700 nm.
12. The method of claim 7 , wherein the relative viscosity of the nanofibers is within a range from 15 to 50.
13. The method of claim 7 , wherein polyamide nanofiber nonwoven product comprises from 2 to 17.5% of the nanofiber diameters are greater than 700 nanometers.