IP Library Granted Patent US 12,263,462
Granted Patent B2
US 12,263,462 · App. 17/396,238 · Granted Apr 1, 2025

Material to separate and pump oxygen

Inventors: Steven Wilson (Phoenix, AZ); Christopher Muhich (Phoenix, AZ); Ellen B. Stechel (Albuquerque, NM); Ivan Ermanoski (Tempe, AZ)
Assignee: Arizona Board of Regents on Behalf of Arizona State University
B01J20/18B01J20/0207B01J20/0211B01J20/0218B01J20/0222B01J20/0225B01J20/0248B01J20/0251B01J20/0292B01J20/2808
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Quick Facts
Patent No.
US 12,263,462
App. No.
17/396,238
Granted
Apr 1, 2025
Kind
B2
Abstract

A material for separating and pumping oxygen is disclosed. The material is a zeolite doped with a chemical element having an electron density of between 30 kJ/mol and 150 kJ/mol. The material is configured for controllable oxygen desorption between 150° C. and 300° C. and pumping the released oxygen into an area having an ambient pressure of less than 100 pascals.

Claims (15)

1. A material for separating and pumping oxygen, the material comprising a synthetic aluminophosphate zeolite doped/substituted with a chemical element hafnium at an ion location within a framework of the zeolite.

2. The material of claim 1 , wherein the chemical element has an adsorption energy of between 40 KJ/mol and 60 KJ/mol.

3. The material of claim 1 , wherein the chemical element has an adsorption energy of between 40 KJ/mol and 50 kJ/mol.

4. The material of claim 1 , wherein the chemical element has an adsorption energy of between 80 KJ/mol and 120 KJ/mol.

5. The material of claim 1 , wherein pores within the zeolite have diameters that are between 4 angstroms and 6 angstroms.

6. The material of claim 1 , wherein pores within the zeolite have diameters that are between 6 angstroms and 12 angstroms.

7. The material of claim 1 , wherein the zeolite is ALPO-5 zeolite.

8. The material of claim 1 , wherein the zeolite is VPI-5.

9. The material of claim 1 , wherein the zeolite is SSZ-51.

10. The material of claim 1 , wherein the zeolite is ALPO-52.

11. The material of claim 1 , wherein the zeolite is configured for controllable oxygen sorption between −20° C. and 80° C.

12. The material of claim 1 , wherein the zeolite is configured for controllable oxygen desorption between 100° C. and 300° C.

13. The material of claim 1 , wherein the hafnium is substituted on site 3 of an ALPO-5 structure.

14. The material of claim 1 , wherein the hafnium is substituted on site 4 of an ALPO-5 structure.

15. The material of claim 1 , wherein the hafnium is substituted on sites 3 and 4 of an ALPO-5 structure.

Assignments (2)
CONFIRMATORY LICENSE Recorded Oct 8, 2021
From: ARIZONA STATE UNIVERSITY-TEMPE CAMPUS
To: UNITED STATES DEPARTMENT OF ENERGY
Reel/Frame 057758/0766 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 5, 2021
From: WILSON, STEVEN; MUHICH, CHRISTOPHER; STECHEL, ELLEN B.; ERMANOSKI, IVAN
To: ARIZONA BOARD OF REGENTS ON BEHALF OF ARIZONA STATE UNIVERSITY
Reel/Frame 057701/0646 →
Continuity (2)
Provisional Application 63063582 · Aug 10, 2020
Related Publication 20220040666A1 · Feb 10, 2022
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