IP Library › Granted Patent US 12,486,616
Granted Patent B2
US 12,486,616 · App. 17/400,999 · Granted Dec 2, 2025

Methods for controlling color during a metallization process and resulting products

Inventors: Bennett Fisher (Morganton, NC); Carl Jones (Peckville, PA); Jodi Wallis (Carbondale, PA); Dino Aimino (Newark, NY); Thomas Dougal (Old Forge, PA); Greg Gianforcaro (Clemson, SC); David Curry (Valdese, NC)
Assignee: Noble Biomaterials, Inc.
D06P5/10D06B3/10D06B21/00D06M11/83
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,486,616
App. No.
17/400,999
Granted
Dec 2, 2025
Kind
B2
Abstract

System and methods that enables fabric to be metalized and dyed to reach final colors that were previously unobtainable. The systems and methods relate to processes for controlling the color of metalized fabrics. Specifically, for some embodiments, the systems and methods relate to methods of making metalized fabrics that are lighter in color than prior metalized fabrics. Such fabrics may be printed on or dyed using lighter colors than would be possible when using prior metalized fabrics. The systems and methods herein may include dye baths and wash baths that are hotter than prior art processes.

Claims (27)

1 . A method for dying and metalizing fabric, the method comprising:

providing a base fabric;

providing a dye bath including a metal salt, a reducing agent, and a dye maintained at a first predetermined temperature;

providing a washing bath maintained at a second predetermined temperature different from the first predetermined temperature;

dying the base fabric and metalizing at least a portion of the base fabric in the dye bath while maintaining said first predetermined temperature;

washing the base fabric in the washing bath; and

drying the base fabric.

2 . The method of claim 1 , wherein the first predetermined temperature is about 23° C. or greater.

3 . The method of claim 2 , wherein the second predetermined temperature is about 70° C. or greater.

4 . The method of claim 1 , wherein the first predetermined temperature is about 25° C. or greater.

5 . The method of claim 4 , wherein the second predetermined temperature is about 70° C. or greater.

6 . The method of claim 1 , wherein the first predetermined temperature is in a range of about 30° C. to about 40° C.

7 . The method of claim 6 , wherein the second predetermined temperature is about 70° C. or greater.

8 . The method of claim 1 , wherein the second predetermined temperature is about 70° C. or greater.

9 . The method of claim 1 , wherein a majority of the base fabric is metalized.

10 . The method of claim 1 , wherein the base fabric is processed into a garment after the drying.

11 . The method of claim 1 , wherein the metallization begins before the dying is completed.

12 . The method of claim 1 , wherein the dying begins before the metallization is completed.

13 . The method of claim 1 , wherein the metallization and the dying begin substantially simultaneously.

14 . The method of claim 1 , wherein the metalizing at least a portion of the base fabric further includes the use of autocatalysis to coat at least a portion of the fabric with a metal.

15 . The method of claim 1 , wherein the metallization uses silver.

16 . The method of claim 1 , further comprising:

introducing dye and a reducing agent into the dye bath after the base fabric has been introduced into the dye bath; and

maintaining the predetermined first temperature of the dye bath during and after introducing dye and a reducing agent into the dye bath.

17 . The method of claim 16 , wherein the maintaining the predetermined first temperature of the dye bath after introducing the dye and the reducing agent into the dye bath comprises tilling the dye bath using a tiller.

18 . The method of claim 16 , wherein the introduction of the dye and reducing agent into the dye bath is substantially performed at one time.

19 . The method of claim 16 , wherein the introduction of the dye and reducing agent into the dye bath is substantially performed in small increments over time.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 27, 2025
From: FISHER, BENNETT; JONES, CARL; AIMINO, DINO; WALLIS, JODI; DOUGAL, THOMAS
To: NOBLE BIOMATERIALS, INC.
Reel/Frame 072585/0225 →
Continuity (4)
Continuation In Part 17161364 · Jan 28, 2021
Provisional Application 63069543 · Aug 24, 2020
Provisional Application 62966855 · Jan 28, 2020
Related Publication 20210372044A1 · Dec 2, 2021
References Cited (27)
US 4681591A · Okayasu et al. · 1987 [cited by applicant]
US 4925706A · Kistrup et al. · 1990 [cited by applicant]
US 6346491B1 · DeAngelis et al. · 2002 [cited by applicant]
US 10203183B2 · Morag et al. · 2019 [cited by applicant]
US 10519583B2 · Moon · 2019 [cited by applicant]
US 10960654B2 · Morag et al. · 2021 [cited by applicant]
US 20060067965A1 · Chandra et al. · 2006 [cited by applicant]
US 20180030599A1 · Stremsdoerfer · 2018 [cited by examiner]
US 20180066921A1 · Wagner et al. · 2018 [cited by applicant]
US 20190017785A1 · Morag · 2019 [cited by examiner]
CN 107268214A · 2017 [cited by applicant]
JP 2004257643A · 2004 [cited by applicant]
JP 2007063744A · 2007 [cited by applicant]
JP 2007146339A · 2007 [cited by examiner]
JP 2008223189A · 2008 [cited by applicant]
JP 2014061646A · 2014 [cited by applicant]
KR 20050094272A · 2005 [cited by examiner]
KR 1020050094272A · 2005 [cited by applicant]
KR 20120029217A · 2012 [cited by examiner]
KR 1020120029217A · 2012 [cited by applicant]
WO 2007069803A1 · 2007 [cited by applicant]
Yu et al.; Simultaneous Dyeing and Deposition of Silver Nanoparticles on Cotton Fabric through in situ Green Synthesis with Black Rice Extract; Cellulose; 2020 vol. 27 pp. 1829-1843; published Oct. 15, 2019. [cited by examiner]
International Search Report and Written Opinion in PCT/US2021/047319, mailed Dec. 15, 2021, 13 pages. [cited by applicant]
Extended European Search Report in EP21747008.7, mailed Apr. 15, 2024, 9 pages. [cited by applicant]
Extended European Search Report in EP21862558.0, mailed Oct. 16, 2024, 7 pages. [cited by applicant]
Montazer et al., “Simultaneous Dyeing and Antibacterial Finishing of Nylon Fabric Using Acid Dyes and Colloidal Nanosilver.” Fibres & Textiles in Eastern Europe, 2015, vol. 23, No. 2, pp. 100-106. [cited by applicant]
Yu et al., “Simultaneous dyeing and deposition of silver nanoparticles on cotton fabric through in situ green synthesis with black rice extract,” Cellulose, 2020, vol. 27, pp. 1829-1843. [cited by applicant]