Flexible substrate, method for preparing the same, and display device comprising the same
A flexible substrate, a method for preparing the same, and a display device including the same, and more particularly, to a flexible substrate including: a first polymer layer including a first polymer; second polymer layers which include second polymers and are located above and below the first polymer layer; and first interfacial crosslinked layers which are located between the first polymer layer and the second polymer layers and include a first crosslinked polymer having a network structure in which the first polymer and the second polymer are crosslinked, in which the stiffness of the first polymer layer is higher than the stiffness of the second polymer layer and the softness of the second polymer layer is higher than the softness of the first polymer layer, a method for preparing the same, and a display device including the same.
1 . A display device, comprising:
a flexible substrate; and
a display panel disposed on the flexible substrate,
a support plate which is disposed below the flexible substrate,
wherein the flexible substrate includes:
a first polymer layer including a first polymer;
second polymer layers including second polymers and located above and below the first polymer layer; and
first interfacial crosslinked layers located between the first polymer layer and the second polymer layers and including a first crosslinked polymer having a network structure in which the first polymer and the second polymer are crosslinked;
adhesive layers located above the second polymer layer located above the first polymer layer and below the second polymer layer located below the first polymer layer and including a third polymer; and
second interfacial crosslinked layers located between the adhesive layers and the second polymer layers and including a second crosslinked polymer having a network structure in which the third polymer and the second polymer are crosslinked;
wherein the display device is a foldable display device,
wherein the adhesive layer located above the second polymer layer bonds the display panel to the flexible substrate, the adhesive layer located below the second polymer layer bonds the support plate to the flexible substrate,
wherein the first polymer layer has a stiffness greater than that of the second polymer layers and the second polymer layer has a softness greater than that of the first polymer layer,
the first interfacial crosslinked layer is formed by cross linking the first polymer of the first polymer layer and the second polymer of the second polymer layer by interfacial polymerization at the interface where the first polymer layer and the second polymer layer come into contact,
the first polymer includes one or more repeating units selected from Formula A, the second polymer includes one or more repeating units selected from Formula B and the third polymer includes one or more repeating units selected from Formula F as follows as follows,
in Formula A and Formula B, n is independently an integer of 500 to 4000, and x is independently an integer of 300 to 2500, and y is independently an integer of 300 to 2500,
in Formula F, R2 is independently hydrogen or a methyl group, R3 is an alkyl group having 1 to 10 carbon atoms, and o is an integer of 1 to 10, p is an integer of 1 to 10, and 1 is independently an integer of 500 to 3000, and
the first crosslinked polymer is selected from a compound represented by Formula C as follows,
in Formula C, z is an integer of 1 to 10, R1 is independently selected from hydrogen or a methyl group, and A includes one or more repeating units selected from Formula A, and B′ includes one or more repeating units selected from Formula B.
2 . The display device according to claim 1 , wherein the first polymers of the first polymer layer are crosslinked to form a network structure and the second polymers of the second polymer layer are crosslinked to form a network structure.
3 . The display device according to claim 2 , wherein the first polymer having the network structure is selected from a compound represented by Formula D as follows,
in Formula D, A includes one or more repeating units selected from Formula A, z is an integer of 1 to 10, and R1 is independently selected from hydrogen or a methyl group,
in Formula A, n is independently an integer of 500 to 4000.
4 . The display device according to claim 2 , wherein the second polymer having the network structure is selected from a compound represented by
in Formula E, B′ includes one or more repeating units selected from Formula B, z is an integer of 1 to 10, and R1 is independently selected from hydrogen or a methyl group,
in Formula B, n is independently an integer of 500 to 4000, x is independently an integer of 300 to 2500, and y is independently an integer of 300 to 2500.
5 . The display device according to claim 1 , wherein the third polymers of the adhesive layer are crosslinked with each other to form a network structure and the third polymer having the network structure is selected from a compound represented by Formula G as follows,
in Formula G, F′ includes one or more repeating units selected from Formula F, z is an integer of 1 to 10, and R1 is independently selected from hydrogen or a methyl group.
6 . The display device according to claim 1 , wherein the second crosslinked polymer is selected from a compound represented by Formula H as follows,
in Formula H, B′ includes one or more repeating units selected from Formula B, F′ includes one or more repeating units selected from Formula F, z is an integer of 1 to 10, and R1 is independently selected from hydrogen or a methyl group,
in Formula B, n is independently an integer of 500 to 4000, x is independently an integer of 300 to 2500, and y is independently an integer of 300 to 2500,
in Formula F, R2 is independently hydrogen or a methyl group, R3 is an alkyl group having 1 to 10 carbon atoms, o is an integer of 1 to 10, p is an integer of 1 to 10, and 1 is independently an integer of 500 to 3000.