Aqueous gel cleaning composition for lipophilic stain removal from vehicle surfaces
A gellable vehicle surface cleaning composition is provided that includes a non-ionic surfactant combined with gelling components of an inorganic gel forming substance and at least one water soluble polymer in a ratio of the inorganic gel forming substance to the hydrophilic polymer of between 0.1-1:1. The non-ionic surfactant and the gelling components are provided in an aqueous solvent system. The aqueous solvent system includes a first solvent having a Kamlet-Taft solvent polarity α (K-T α) value of zero, a second solvent having a K-T α 0.6-0.85 value, and water present at more than 50 total weight percent. A process of for cleaning a vehicle surface with a stain is also provided that includes the composition to the stain on the vehicle surface a composition and after allowing sufficient time for the composition to lift the stain, the stain and the composition are removed from the vehicle surface.
1. A gellable vehicle surface cleaning composition comprising:
a non-ionic surfactant;
gelling components comprising:
an inorganic gel forming substance of a phyllosilicate, natural smectite clay or synthetic layered silicate, or combination thereof; and at least one hydrophilic polymer of an alkali soluble emulsion polymer, a hydrophobically modified alkali-soluble emulsion polymer, butyl acrylate-methacrylic acid-methyl methacrylate copolymer, hydrophobically modified non-ionic polyol, natural gums, or combination thereof, with a ratio of said inorganic gel forming substance: said at least one hydrophilic polymer of between 0.1-1:1; and
an aqueous solvent system in which said non-ionic surfactant and said gelling components are present, said aqueous solvent system comprising a first solvent having a Kamlet-Taft solvent polarity α value of zero, a second solvent having a Kamlet-Taft solvent polarity α 0.6-0.85 value; and water present at more than 50 total weight percent.
2. The composition of claim 1 wherein said non-ionic surfactant has a hydrophile/lipophile balance (HLB) value of between 8 and 14.
3. The composition of claim 1 wherein said non-ionic surfactant comprises at least one alcohol alkoxylates having a formula:
where R is C 4 -C 22 linear or branched chain alkyl or mixtures thereof; x has a value of from 2 to 20; y has a value of from 0 to 15, or
R 1 O—(CH 2 CH 2 O) n —H
where n is average moles of ethylene oxide (EO) from 2.5-9 and R 1 is a C 9 -C 18 alkyl.
4. The composition of claim 1 wherein said non-ionic surfactant comprises lauramidopropylamine oxide and/or myristamidopropylamine oxide.
5. The composition of claim 1 wherein said non-ionic surfactant comprises C 9-11 ethoxylated alcohols having ethylene oxide values from 2.5-9, and combinations thereof.
6. The composition of claim 5 wherein said non-ionic surfactant comprises ethylene oxide 2.5 C 9-11 ethoxylated alcohol is used in combination with one more ethylene oxide 6-9 C 9-11 ethoxylated alcohols.
7. The composition of claim 6 wherein a ratio of ethylene oxide 2.5 C 9-11 ethoxylated alcohol: ethylene oxide 6-9 C 9-11 ethoxylated alcohols is between 0.1-1:1.
8. The composition of claim 1 wherein said non-ionic surfactant is present from 1 to 15 total weight percent.
9. The composition of claim 1 wherein said inorganic gel forming substance is a synthetic phyllosilicate.
10. The composition of claim 1 wherein a ratio of said inorganic gel forming substance: said at least one hydrophilic polymer is between 0.5-0.58:1.
11. The composition of claim 1 wherein said gel forming components are present from 0.1 to 3 total weight percent.
12. The composition of claim 1 wherein said first solvent is orange oil terpenes, cumene, limonene, α-pinene, cineole, p-xylene, or combinations thereof.
13. The composition of claim 1 wherein said second solvent is ethyl lactate, 2-(2-butoxyethoxy)ethanol, hydrophobic glycol ether, 1-butanol, ethylene glycol, 2-propanol, tripropylene glycol n-butyl ether, or combinations thereof.
14. The composition of claim 1 wherein a ratio of water:said first solvent: said second solvent is 1:0.02-0.16:0.06-0.2.
15. A process of cleaning a vehicle surface with a stain comprising:
applying to the stain on the vehicle surface a composition of claim 1 ;
allowing the composition to dwell on the stain; and
removing the stain and the composition from the vehicle surface.
16. The process of claim 15 wherein the applying the composition is spraying or pressurized aerosol.
17. The process of claim 15 wherein the composition gels after the applying.
18. The process of claim 15 wherein the removing is by water washing.
19. The process of claim 15 further comprising washing the vehicle surface after the removing.
20. The process of claim 15 wherein the stain is at least one of grime, brake dust, insect splatter, tar, tree sap, sticker adhesive, or bird droppings.