IP Library Granted Patent US 11,499,109
Granted Patent B2
US 11,499,109 · App. 17/423,036 · Granted Nov 15, 2022

Fuel composition with lubricity additives

Inventors: Yajnanarayana Halmuthur Jois (Houston, TX); Joseph Michael Russo (Houston, TX)
Assignee: SHELL USA, INC.
C10L10/08C10L1/1881C10L1/191C10L2270/023
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Quick Facts
Patent No.
US 11,499,109
App. No.
17/423,036
Granted
Nov 15, 2022
Kind
B2
Abstract

A fuel composition comprising a fuel and a lubricity additive package, where the lubricity additive package comprises (1) Dodecanoic acid and (2) 1-Lauroyl-rac-glycerol and the fuel is gasoline.

Claims (18)

1. A fuel composition comprising:

a base fuel comprising gasoline or a gasoline-based fuel;

a lubricity additive package; and

wherein the lubricity additive package comprises (1) Dodecanoic acid and (2) 1-Lauroylrac-glycerol, wherein the lubricity additive package is blended with the base fuel at a concentration of 5 ppm to 100 ppm by weight, based on the total weight of the fuel composition, and wherein the treat rate of 1-Lauroyl-rac-glycerol is at least double the treat rate of Dodecanoic acid.

2. The fuel composition according to claim 1 , wherein the fuel composition provides a coefficient of friction ranging from 0.300 to 0.600 as measured according to ASTM D6079-11.

3. The fuel composition according to claim 1 , wherein the fuel composition provides a wear scar diameter ranging from 480 μm to 680 μm as measured according to ASTM D6079-11.

4. The fuel composition according to claim 1 , wherein the lubricity additive package is soluble in the fuel.

5. The fuel composition according to claim 1 , wherein the fuel composition has a sulfur concentration of less than about 50 ppm.

6. A method for improving lubricity of a fuel composition, the method comprising, providing a base fuel comprising gasoline or a gasoline-based fuel;

adding a lubricity additive package to the base fuel;

wherein the lubricity additive package comprises (1) Dodecanoic acid and (2) 1-Lauroyl-rac-glycerol, wherein the lubricating additive package is blended with the base fuel at a concentration of 5 ppm to 100 ppm by weight, based on the total weight of the fuel composition, and wherein the treat rate of 1-Lauroyl-rac-glycerol is at least double the treat rate of Dodecanoic acid.

7. The method according to claim 6 , wherein the fuel composition provides a coefficient of friction ranging from 0.300 to 0.600 as measured according to ASTM D6079-11 after adding the lubricity additive package to the base fuel.

8. The method according to claim 6 , wherein the fuel composition provides a wear scar diameter ranging from 480 μm to 680 μm as measured according to ASTM D6079-11 after adding the lubricity additive package to the base fuel.

9. A method for improving fuel performance of a direct injection engine, wherein the method comprises,

fueling the direct injection engine with a fuel composition comprising a base fuel comprising gasoline or a gasoline-based fuel and a lubricity additive package; and

operating the direct injection engine;

wherein the lubricity additive package comprises (1) Dodecanoic acid and (2) 1-Lauroyl-rac-glycerol wherein the lubricating additive package is blended with the base fuel at a concentration of 5 ppm to 100 ppm by weight, based on the total weight of the fuel composition, and wherein the treat rate of 1-Lauroyl-rac-glycerol is at least double the treat rate of Dodecanoic acid.

10. The method according to claim 9 , wherein the fuel performance exhibited by the direct injection engine after fueling with the fuel composition is measured by the fuel composition providing a coefficient of friction ranging from 0.300 to 0.600 as measured according to ASTM D6079-11 and a wear scar diameter ranging from 480 μm to 680 μm as measured according to ASTM D6079-11.

Assignments (2)
CHANGE OF NAME Recorded Sep 27, 2022
From: SHELL OIL COMPANY
To: SHELL USA, INC.
Reel/Frame 061541/0924 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 4, 2021
From: JOIS, YAJNANARAYANA HALMUTHUR; RUSSO, JOSEPH MICHAEL
To: SHELL OIL COMPANY
Reel/Frame 057080/0001 →
Continuity (2)
Provisional Application 62802237 · Feb 7, 2019
Related Publication 20220064558A1 · Mar 3, 2022