Aqueous composition for coating grain-oriented steel
The present patent application relates to an aqueous composition for coating grain oriented steel, comprising aluminium cations, manganese cations, dihydrogen phosphate, hydrogen phosphate and/or phosphate anions, colloidal silica and optionally iron cations, wherein the aluminium cations, expressed as Al 2 O 3 , manganese cations, expressed as MnO, dihydrogen phosphate, hydrogen phosphate and/or phosphate anions, expressed as P 2 O 5 , colloidal silica, expressed as SiO 2 , and optionally iron cations, expressed as FeO, which are present in the composition, give the sum formula of (Al 2 O 3 ) 2 (MnO) 1,8-2,4 (FeO) 0-0,2 (P 2 O 5 ) 5-7 (SiO 2 ) ≥30 .
1. An aqueous composition for coating grain oriented steel, comprising
aluminium cations,
manganese cations,
dihydrogen phosphate, hydrogen phosphate and/or phosphate anions,
colloidal silica, and
optionally iron cations,
wherein the aluminium cations, expressed as Al 2 O 3 , manganese cations, expressed as MnO, dihydrogen phosphate, hydrogen phosphate and/or phosphate anions, expressed as P 2 O 5 , colloidal silica, expressed as SiO 2 , and optionally iron cations, expressed as FeO, which are present in the composition, give a chemical formula of (Al 2 O 3 ) 2 (MnO) 1.8-2.4 (FeO) 0-0.2 (P 2 O 5 ) 5-7 (SiO 2 ) ≥30 .
2. An aqueous composition according to claim 1 , wherein the number of SiO 2 in the chemical formula is 30 to 100.
3. An aqueous composition according to claim 1 , wherein the number of P 2 O 5 in the chemical formula is 5.4 to 6.8.
4. An aqueous composition according to claim 1 , wherein the aqueous composition comprises aluminium hydroxide and/or aluminium phosphate.
5. An aqueous composition according to claim 1 , wherein the aqueous composition comprises manganese (II) oxide, manganese (II) oxalate and/or manganese (II) hydroxide.
6. An aqueous composition according to claim 1 , wherein the aqueous composition comprises iron oxide, iron (II) oxide and/or iron (III) oxalate.
7. An aqueous composition according to claim 1 , wherein the colloidal silica is free of surface charges.
8. An aqueous composition according to claim 1 , wherein the colloidal silica comprises spherical silica particles of a size between 5 and 80 nm.
9. An aqueous composition according to claim 1 , wherein the ratio of the sum of the specific surface area of the particles of the colloidal silica to the total molar number of all metal oxides is 1:10000 to 1:200000.
10. An aqueous composition according to claim 1 , wherein the molar ratio of the sum of the metal ions, expressed as the oxides thereof, to silica in the composition is 1:6.5 to 1:26.5.
11. An aqueous composition according to claim 1 , wherein the molar ratio of the sum of the metal ions, expressed as the oxides thereof, to silica in the composition is 1:9 to 1:13 if a surface is coated with the aqueous composition having a layer thickness of less than 1.5 μm.
12. An aqueous composition according to claim 1 , wherein the molar ratio of the sum of the metal ions, expressed as the oxides thereof, to silica in the composition is 1:10 to 1:14 if a surface is coated with the aqueous composition having a layer thickness of 2 to 10 μm.
13. A method for coating grain oriented steel, comprising the application of an aqueous composition according to claim 1 .
14. A method according to claim 13 , wherein the grain oriented steel is base coated with forsterite.
15. A grain oriented steel obtainable by a method according to claim 13 .
16. A grain oriented steel comprising a coating obtainable by the application of an aqueous composition according to claim 1 .
17. An aqueous composition according to claim 2 , wherein the number of SiO 2 in the chemical formula is 30 to 80.
18. An aqueous composition according to claim 3 , wherein the number of P 2 O 5 in the chemical formula is 5.6 to 6.6.
19. An aqueous composition according to claim 8 , wherein the colloidal silica comprises spherical silica particles of a size between 5 and 60 nm.
20. An aqueous composition according to claim 9 , wherein the ratio of the sum of the specific surface area of the particles of the colloidal silica to the total molar number of all metal oxides is 1:20000 to 1:150000.