ASA-based resin composition, molded article including ASA-based resin composition, and method of manufacturing molded article
Disclosed is an ASA resin composition, a molded article including the ASA resin composition, and a method of manufacturing the molded article. Also disclosed is an ASA resin composition including 20 to 47% by weight of an acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer containing acrylate rubber having an average particle diameter of 50 to 150 nm as a core; 23 to 55% by weight of an alkyl methacrylate-aromatic vinyl compound-vinyl cyanide compound copolymer; and 25 to 45% by weight of a poly(alkyl methacrylate) resin, a molded article including the ASA resin composition, and a method of manufacturing the molded article. Also disclosed is an ASA resin composition having excellent colorability and transparency even at a processing thickness of a predetermined value while having excellent mechanical properties and processability, a molded article including the ASA resin composition, and a method of manufacturing the molded article are provided.
1. A resin composition, comprising:
20 to 30% by weight of an aromatic vinyl compound-vinyl cyanide compound graft copolymer comprising acrylate rubber having an average particle diameter of 50 to 150 nm as a core;
30 to 40% by weight of an alkyl methacrylate-aromatic vinyl compound-vinyl cyanide compound copolymer; and
30 to 40% by weight of a poly(alkyl methacrylate) resin,
wherein the aromatic vinyl compound-vinyl cyanide compound graft copolymer comprises 40 to 60% by weight of the acrylate rubber, 25 to 45% by weight of a first aromatic vinyl compound, and 10 to 20% by weight of a first vinyl cyanide compound,
wherein the alkyl methacrylate-aromatic vinyl compound-vinyl cyanide compound copolymer comprises 45 to 65% by weight of an alkyl methacrylate, 25 to 35% by weight of a second aromatic vinyl compound, and 10 to 20% by weight of a second vinyl cyanide compound,
wherein the resin composition has a total rubber content of 10 to 15% by weight, as measured by Fourier-transform infrared spectroscopy (FTIR),
wherein a weight ratio of the graft copolymer to the alkyl methacrylate-aromatic vinyl compound-vinyl cyanide compound copolymer is 1:1 to 1:2,
wherein the resin composition has an Izod impact strength (¼ inch, 23° C.) of 3 to 8 kgf·cm/cm 2 according to ASTM D256, and
wherein the resin composition has a weather resistance of 1.3 or less according to ASTM J1960.
2. The resin composition according to claim 1 , wherein the alkyl methacrylate-aromatic vinyl compound-vinyl cyanide compound copolymer has a weight average molecular weight of 10,000 to 150,000 g/mol, as measured by gel permeation chromatography (GPC).
3. The resin composition according to claim 1 , wherein the poly(alkyl methacrylate) resin is a polymer comprising an alkyl methacrylate containing an alkyl group having 1 to 15 carbon atoms.
4. The resin composition according to claim 1 , wherein the poly(alkyl methacrylate) resin has a weight average molecular weight of 50,000 to 200,000 g/mol, as measured by gel permeation chromatography (GPC).
5. The resin composition according to claim 1 , further comprising one or more of a lubricant, a heat stabilizer, and a UV stabilizer in an amount of 0.05 to 5 parts by weight.
6. A molded article manufactured using the resin composition according to claim 1 .
7. The molded article according to claim 6 , wherein the molded article is an exterior material, a finishing material, a non-painted product, or an extrusion profile.
8. A method of manufacturing a molded article, the method comprising:
kneading and extruding the resin composition according to claim 1 under conditions of 200 to 300° C. and 100 to 500 rpm to prepare a pellet; and
manufacturing a molded article by performing sheet molding or injection molding of the prepared pellet at a molding temperature of 200 to 300° C.