IP Library › Granted Patent US 12,600,666
Granted Patent B2
US 12,600,666 · App. 17/436,709 · Granted Apr 14, 2026

Glass article having an anti-reflective coating

Inventors: Jun Ni (Maumee, OH); Srikanth Varanasi (Ottawa Hills, OH)
Assignee: Pilkington Group Limited
C03C17/3417C03C3/087C03C2217/734
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Quick Facts
Patent No.
US 12,600,666
App. No.
17/436,709
Filed
Sep 7, 2021
Granted
Apr 14, 2026
Kind
B2
Art Unit
1784
USPC
428/432
Abstract

A glass article includes a glass substrate with a coating formed over the glass substrate. The coating includes a first anti-reflective layer deposited over the glass substrate, the first layer having a refractive index of 1.6 or more and a thickness of less than λ/(4*n). A second anti-reflective layer is deposited over the first anti-reflective layer, the second anti-reflective layer having a thickness that is greater than the thickness of the first anti-reflective layer and a refractive index that is less than the refractive index of the first anti-reflective layer. The glass article exhibits a total visible light reflectance of less than 6.0%.

Claims (26)

1 . A glass article comprising a glass substrate and a coating formed over the glass substrate, wherein the coating comprises:

a first anti-reflective layer deposited over the glass substrate, wherein the first layer comprises undoped tin oxide and has a thickness of less than λ/(4*n), where λ equals 550 nm, n equals the refractive index of the first anti-reflective layer, and n is 1.6 or more;

a second anti-reflective layer deposited over the first anti-reflective layer, the second anti-reflective layer having a thickness that is greater than the thickness of the first anti-reflective layer and a refractive index that is less than the refractive index of the first anti-reflective layer; and

an iridescence-suppressing interlayer between the glass substrate and the first anti-reflective layer;

wherein the iridescence-suppressing interlayer comprises a first iridescence-suppressing layer having a refractive index of 1.6 or more and a second iridescence-suppressing layer deposited over the first iridescence-suppressing layer, the second iridescence-suppressing layer having a refractive index that is less than the refractive index of the first iridescence-suppressing layer; and

wherein the glass article exhibits a total visible light reflectance of less than 6.0%.

2 . The glass article of claim 1 , wherein the glass article exhibits a total visible light reflectance of 5.5% or less and/or wherein the glass article exhibits a neutral reflected color.

3 . The glass article of claim 1 , wherein the refractive index of the first anti-reflective layer is 2.0 or more.

4 . The glass article of claim 1 , wherein the thickness of the first anti-reflective layer is less than 70 nm and/or wherein the thickness of the first anti-reflective layer is between 20 nm or more and 60 nm or less.

5 . The glass article of claim 1 , wherein the first anti-reflective layer comprises tin oxide and has a thickness of between 20 or more and 50 nm or less.

6 . The glass article of claim 1 , wherein the second anti-reflective layer has a thickness of 80 nm or more.

7 . The glass article of claim 1 , wherein the refractive index of the second anti-reflective layer is 1.6 or less.

8 . The glass article of claim 1 , wherein the second anti-reflective layer comprises silicon dioxide and/or wherein the second anti-reflective layer is the outermost layer of the glass article.

9 . The glass article of claim 1 , wherein the first iridescence-suppressing layer comprises tin oxide and/or wherein the first iridescence-suppressing layer has a thickness of between 5 nm or more and 25 nm or less.

10 . The glass article of claim 1 , wherein the second iridescence-suppressing layer is deposited directly on the first iridescence-suppressing layer and/or wherein the second iridescence-suppressing layer has a thickness of 5 nm or more and 25 nm or less.

11 . The glass article of claim 1 , wherein the second iridescence-suppressing layer comprises silicon dioxide and/or wherein the first anti-reflective layer is deposited directly on the second iridescence-suppressing layer.

12 . The glass article of claim 1 , wherein the coating consists of the first iridescence-suppressing layer, the iridescence-suppressing second layer, the first anti-reflective layer, and the second anti-reflective layer.

13 . The glass article of claim 1 , wherein the glass article exhibits a total visible light reflectance of from 4.0% to 5.5%.

14 . The glass article of claim 1 , wherein the refractive index of the first anti-reflective layer is between 2.1 and 2.5.

15 . The glass article of claim 1 , wherein the second anti-reflective layer has a thickness of 80 nm or more and 125 nm or less.

16 . The glass article of claim 1 , wherein the second anti-reflective layer has a thickness of 80 nm or more and 110 nm or less.

17 . The glass article of claim 1 , wherein the refractive index of the second anti-reflective layer is from 1.2 to 1.5.

18 . The glass article of claim 1 , wherein the glass article exhibits a sheet resistance of greater than 1.0×10 5 ohm/sq.

19 . The glass article of claim 1 , wherein the thickness of the second anti-reflective layer is in the range of 80 nm to 95 nm.

20 . The glass article of claim 1 , wherein the thickness of the second anti-reflective layer is in the range of 80 nm to 90 nm.

21 . A touch screen electronic device comprising the glass article of claim 1 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 7, 2021
From: NI, JUN; VARANASI, SRIKANTH
To: PILKINGTON GROUP LIMITED
Reel/Frame 057399/0938 →
Continuity (2)
Provisional Application 62818285 · Mar 14, 2019
Related Publication 20220153635A1 · May 19, 2022
References Cited (20)
US 5780149A · McCurdy · 1998 [cited by examiner]
US 5935716A · McCurdy · 1999 [cited by examiner]
US 6074730A · Laird · 2000 [cited by examiner]
US 6165598A · Nelson · 2000 [cited by examiner]
US 6924037B1 · Joret et al. · 2005 [cited by applicant]
US 9957194B2 · Soubeyrand et al. · 2018 [cited by applicant]
US 10377664B2 · Varanasi · 2019 [cited by applicant]
US 11124447B2 · Varanasi · 2021 [cited by examiner]
US 11718070B2 · Varanasi · 2023 [cited by examiner]
US 20130316140A1 · Lu · 2013 [cited by examiner]
US 20170123109A1 · Varanasi · 2017 [cited by examiner]
US 20170204000A1 · Varanasi · 2017 [cited by examiner]
US 20190351814A1 · Furubayashi et al. · 2019 [cited by applicant]
US 20200123047A1 · Mahoney et al. · 2020 [cited by applicant]
US 20220234334A1 · Varanasi · 2022 [cited by examiner]
EP 0933654A2 · 1999 [cited by applicant]
WO WO2015121648A1 · 2015 [cited by applicant]
WO WO2016075435A1 · 2016 [cited by applicant]
WO WO2018185491A1 · 2018 [cited by examiner]
European Patent Office, International Search Report with Written Opinion, issued in PCT/GB2020/050637, 11 pages, Jun. 15, 2020, European Patent Office, Rijswijk, Netherlands. [cited by applicant]