Fluorine-containing ether compound, lubricant for magnetic recording medium and magnetic recording medium
This fluorine-containing ether compound is a fluorine-containing ether compound represented by formula (1). R 1 —X—R 2 —CH 2 —R 3 —CH 2 —R 4 (1) (In formula (1), R 1 is an alkenyloxy group of 2 to 8 carbon atoms or an alkynyloxy group of 3 to 8 carbon atoms. R 2 is represented by formula (2) shown below. In formula (2), a represents an integer of 1 to 3. X is represented by formula (3) shown below. In formula (3), b represents an integer of 1 to 5, Y is a divalent linking group that is bonded to a carbon atom in formula (2), and R represents an alkyl group of 1 to 6 carbon atoms or H. R 3 represents a perfluoropolyether chain. R 4 represents a terminal group containing two or three polar groups, wherein each polar group is bonded to a different carbon atom, and the carbon atoms to which the polar groups are bonded are bonded to each other via a linking group containing a carbon atom to which a polar group is not bonded.)
1. A fluorine-containing ether compound represented by a formula (1) shown below:
R 1 —X—R 2 —CH 2 —R 3 —CH 2 —R 4 (1)
wherein in the formula (1), R 1 is an alkenyloxy group of 2 to 8 carbon atoms or an alkynyloxy group of 3 to 8 carbon atoms, R 2 is represented by a formula (2) shown below, in formula (2), a represents an integer of 1 to 3, X is represented by a formula (3) shown below, in formula (3), b represents an integer of 1 to 5, Y is a divalent linking group that is bonded to a carbon atom in formula (2), and R represents an alkyl group of 1 to 6 carbon atoms or H, R 3 represents a perfluoropolyether chain, R 4 represents a terminal group containing two or three polar groups, wherein each polar group is bonded to a different carbon atom, and the carbon atoms to which the polar groups are bonded are bonded to each other via a linking group containing a carbon atom to which a polar group is not bonded
2. The fluorine-containing ether compound according to claim 1 , wherein Y in the formula (3) represents one of O, S and CH 2 .
3. The fluorine-containing ether compound according to claim 1 , wherein R in the formula (3) represents a methyl group or H.
4. The fluorine-containing ether compound according to claim 1 , wherein R 1 in the formula (1) represents one of a vinyloxy group, an allyloxy group, a 3-butenyloxy group, a 4-pentenyloxy group and a propargyloxy group.
5. The fluorine-containing ether compound according to claim 1 , wherein R 3 in the formula (1) is represented by any one of formulas (4) to (6) shown below:
—CF 2 O—(CF 2 CF 2 O) c —(CF 2 O) d —CF 2 — (4)
wherein in the formula (4), c and d indicate an average polymerization degree, and each represents a number from 0 to 30, provided that c and d are not both 0,
—CF(CF 3 )—(OCF(CF 3 )CF 2 ) e —OCF(CF 3 )— (5)
wherein in the formula (5), e indicates an average polymerization degree, and represents a number from 0.1 to 30,
—CF 2 CF 2 O—(CF 2 CF 2 CF 2 O) f —CF 2 CF 2 — (6)
wherein in the formula (6), f indicates an average polymerization degree, and represents a number from 0.1 to 30.
6. The fluorine-containing ether compound according to claim 1 , wherein the polar groups in R 4 in the formula (1) are hydroxyl groups.
7. The fluorine-containing ether compound according to claim 1 , wherein R 4 in the formula (1) is a terminal group represented by any one of formulas (7) to (10) shown below:
wherein in the formula (7), g represents an integer of 1 or 2, and h represents an integer of 1 to 5,
in the formula (8), i represents an integer of 2 to 5,
in the formula (9), j represents an integer of 1 to 5, and
in the formula (10), k represents an integer of 2 to 5.
8. The fluorine-containing ether compound according to claim 1 , having a number average molecular weight within a range from 500 to 10,000.
9. A lubricant for a magnetic recording medium, the lubricant comprising the fluorine-containing ether compound according to claim 1 .
10. A magnetic recording medium comprising at least a magnetic layer, a protective layer and a lubricant layer provided sequentially on a substrate, wherein the lubricant layer comprises the fluorine-containing ether compound according to claim 1 .
11. The magnetic recording medium according to claim 10 , wherein an average thickness of the lubricant layer is within a range from 0.5 nm to 2 nm.