CARBON ELECTRODE MATERIAL AND REDOX BATTERY
A carbon electrode material includes carbon fibers (A); carbon particles (B) other than graphite particles; carbon material (C) for binding the carbon fibers (A) and the carbon particles (B) to each other, and the carbon electrode material satisfies: (1) a particle diameter of the carbon particles (B) other than graphite particles is not larger than 1 μm, (2) Lc(B) is not larger than 10 nm when Lc(B) represents a crystallite size, in a c-axis direction, obtained by X-ray diffraction in the carbon particles (B) other than graphite particles, (3) Lc(C)/Lc(A) is 1.0 to 5.0, (4) a meso-pore specific surface area obtained from a nitrogen gas adsorption amount is less than 30 m 2 /g, and (5) a number of oxygen atoms bound to a surface of the carbon electrode material is not less than 1% of a total number of carbon atoms on the surface of the carbon electrode material.
1 - 6 . (canceled)
7 . A carbon electrode material for use in a redox battery, the carbon electrode material comprising:
carbon fibers (A);
carbon particles (B) other than graphite particles;
a carbon material (C) for binding the carbon fibers (A) and the carbon particles (B) to each other,
the carbon electrode material for use in a redox battery satisfying the following requirements.
(1) a particle diameter of the carbon particles (B) other than graphite particles is not larger than 1 μm,
(2) Lc(B) is not larger than 10 nm when Lc(B) represents a crystallite size, in a c-axis direction, obtained by X-ray diffraction in the carbon particles (B) other than graphite particles,
(3) Lc(C)/Lc(A) is 1.0 to 5.0 when Lc(A) and Lc(C) represent crystallite sizes, in the c-axis direction, obtained by X-ray diffraction in the carbon fibers (A) and the carbon material (C), respectively,
(4) a meso-pore specific surface area obtained from a nitrogen gas adsorption amount is less than 30 m 2 /g, and
(5) a number of oxygen atoms bound to a surface of the carbon electrode material is not less than 1% of a total number of carbon atoms on the surface of the carbon electrode material.
8 . The carbon electrode material according to claim 7 , wherein the carbon electrode material is a carbon electrode material for use a negative electrode of a redox battery.
9 . The carbon electrode material according to claim 7 , wherein a mass ratio of the carbon material (C) to the carbon particles (B) is 0.2 to 10.
10 . The carbon electrode material according to claim 7 , wherein a BET specific surface area obtained from a nitrogen adsorption amount is less than 50 m 2 /g.
11 . The carbon electrode material according to claim 7 , wherein a water flow rate is not less than 0.5 mm/sec when a water droplet is dropped.
12 . A redox flow battery comprising the carbon electrode material according to claim 7 .
13 . A redox flow battery comprising a negative electrode having the carbon electrode material according to claim 8 .
14 . A method for producing the carbon electrode material according to claim 7 , the method comprising:
a step of impregnating the carbon fibers (A) with the carbon particles (B) other than graphite particles, and the carbon material (C) having not been carbonized;
a carbonizing step of heating a product obtained in the impregnating step, under an inert gas atmosphere, at a temperature of not lower than 500° C. and lower than 2000° C.;
a primary oxidization step of performing oxidization at a temperature of 500 to 900° C. in a dry process;
a graphitization step of performing heating at a temperature of 1300 to 2300° C. under an inert gas atmosphere; and
a secondary oxidization step of performing oxidization at a temperature of 500 to 900° C. in a dry process,
so as to perform the steps in order, respectively.