Layered structure for solid-state batteries and process of forming the same
A solid-state battery and process of forming the same is provided. The solid-state battery includes a first metal electrode. The solid-state battery includes a first mixed conductor disposed on the first metal electrode. The first mixed conductor includes a mixture of ionic and electronic conductors. The solid-state battery includes a pure ionic conductor disposed on the first mixed conductor. The solid-state battery includes a second metal electrode disposed on top of the pure ionic conductor.
1. A solid-state battery comprising:
a first metal electrode;
a first mixed conductor disposed on the first metal electrode, wherein the first mixed conductor comprises a mixture of ionic and electronic conductors;
a pure ionic conductor disposed on the first mixed conductor; and
a second metal electrode disposed on top of the pure ionic conductor.
2. The solid-state battery of claim 1 , further comprising a second mixed conductor disposed between the pure ionic conductor and the second metal electrode, wherein the second mixed conductor comprises the mixture of ionic and electronic conductors.
3. The solid-state battery of claim 1 , wherein the first metal electrode and the second metal electrode comprise one or more of Li, a metallic foil, and a metallic powder.
4. The solid-state battery of claim 1 , wherein the mixture of ionic and electronic conductors comprises one or more of a sulfide-based electrolyte, an oxide-based electrolyte, a hydride-based electrolyte, a halide-based electrolyte, a borate-based electrolyte, a phosphate-based electrolyte, a thin film, a polymer-based electrolyte, a carbon-based material, and metallic-based materials.
5. The solid-state battery of claim 4 , wherein the polymer-based electrolyte comprises one or more of a polymer, polyethylene oxide (PEO), polyethylene sulfide (PES), polyphenylene oxide (PPO) and polyacrylonitrile (PAN), polystyrene (PS), polymethacrylates (PMA), poly(ethylene glycol-methyl methacrylate)(PEG-MMA), poly(vinyl alcohol) (PVA) and salt of lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), lithium bis(fluorosulfonyl)amide (LiFSI), lithium hexafluorophosphate (LiPF6), lithium tetrafluoroborate (LiBF4), and lithium perchlorate (LiCIO4).
6. The solid-state battery of claim 1 , wherein the pure ionic conductor comprises one or more of a sulfide-based electrolyte, an oxide-based electrolyte, a hydride-based electrolyte, a halide-based electrolyte, a borate-based electrolyte, a phosphate-based electrolyte, a thin film, and a polymer-based electrolyte.
7. The solid-state battery of claim 6 , wherein the polymer-based electrolyte comprises one or more of a polymer, polyethylene oxide (PEO), polyethylene sulfide (PES), polyphenylene oxide (PPO) and polyacrylonitrile (PAN), polystyrene (PS), polymethacrylates (PMA), poly(ethylene glycol-methyl methacrylate)(PEG-MMA), poly(vinyl alcohol) (PVA) and salt of lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), lithium bis(fluorosulfonyl)amide (LiFSI), lithium hexafluorophosphate (LiPF6), lithium tetrafluoroborate (LiBF4), and lithium perchlorate (LiCIO4).
8. The solid-state battery of claim 1 , wherein the first metal electrode and the second metal electrode comprise Li, wherein the pure ionic conductor comprises Li 3 PS 4 /S/PES@Kevlar, and wherein the first mixed conductor comprises PEO/LiTFSI/CNTs.
9. A solid-state battery comprising:
a first metal electrode;
a first mixed conductor disposed on the first metal electrode, wherein the first mixed conductor comprises a mixture of ionic and electronic conductors;
a pure ionic conductor disposed on the first mixed conductor;
a second mixed conductor disposed on the pure ionic conductor, wherein the second mixed conductor comprises the mixture of ionic and electronic conductors; and
a second metal electrode disposed on top of the second mixed conductor.
10. The solid-state battery of claim 9 , wherein the first metal electrode comprises one or more of Li, a metallic foil, and a metallic powder.
11. The solid-state battery of claim 9 , wherein the mixture of ionic and electronic conductors comprises one or more of a sulfide-based electrolyte, an oxide-based electrolyte, a hydride-based electrolyte, a halide-based electrolyte, a borate-based electrolyte, a phosphate-based electrolyte, a thin film, a polymer-based electrolyte, a carbon-based material, and metallic-based materials.
12. The solid-state battery of claim 9 , wherein the pure ionic conductor comprises one or more of a sulfide-based electrolyte, an oxide-based electrolyte, a hydride-based electrolyte, a halide-based electrolyte, a borate-based electrolyte, a phosphate-based electrolyte, a thin film, and a polymer-based electrolyte.
13. The solid-state battery of claim 9 , wherein the first metal electrode and the second metal electrode comprise Li, wherein the pure ionic conductor comprises Li 3 PS 4 /S/PES@Kevlar, and wherein the first mixed conductor and the second mixed conductor comprise PEO/LiTFSI/CNTs.
14. A solid-state battery comprising:
a first metal electrode;
a first mixed conductor disposed on the first metal electrode, wherein the first mixed conductor comprises a mix-conductor;
a pure ionic conductor disposed on the first mixed conductor;
a second mixed conductor disposed on the pure ionic conductor; and
a second metal electrode disposed on top of the second mixed conductor.
15. The solid-state battery of claim 14 , wherein the second mixed conductor comprises a mixture of ionic and electronic conductors.
16. The solid-state battery of claim 14 , wherein the second mixed conductor comprises the mix-conductor.
17. The solid-state battery of claim 16 , wherein the mix-conductor comprises one or more of a Li-M-O structure and a Li-M-S structure.
18. The solid-state battery of claim 14 , wherein the second mixed conductor comprises a liquid electrolyte.
19. The solid-state battery of claim 18 , wherein the liquid electrolyte comprises one or more of a carbonate-based electrolyte, ether-based electrolyte, and ester-based electrolyte.
20. The solid-state battery of claim 14 , wherein the first metal electrode comprises one or more of Li, a metallic foil, and a metallic powder.
21. The solid-state battery of claim 15 , wherein the mixture of ionic and electronic conductors of the second mixed conductor comprises one or more of a sulfide-based electrolyte, an oxide-based electrolyte, a hydride-based electrolyte, a halide-based electrolyte, a borate-based electrolyte, a phosphate-based electrolyte, a thin film, a polymer-based electrolyte, a carbon-based material, and metallic-based materials.
22. The solid-state battery of claim 14 , wherein the pure ionic conductor comprises one or more of a sulfide-based electrolyte, an oxide-based electrolyte, a hydride-based electrolyte, a halide-based electrolyte, a borate-based electrolyte, a phosphate-based electrolyte, a thin film, and a polymer-based electrolyte.
23. The solid-state battery of claim 14 , wherein the first metal electrode and the second metal electrode comprise Li, wherein the pure ionic conductor comprises Li 3 PS 4 /S/PES@Kevlar, and wherein the second mixed conductor comprises PEO/LiTFSI/CNTs.