Multilayer electrolyte membrane, membrane electrode assembly, water electrolysis-type hydrogen generator and method of producing multilayer electrolyte membrane
A laminated electrolyte membrane including a first layer including a hydrocarbon polymer electrolyte as a major component, and a second layer including a fluoropolymer electrolyte and polyvinylidene fluoride as major components laminated on at least one side of the first layer, wherein the first layer and the second layer are laminated via a region in which components constituting both layers are mixed in a mixed region.
1. A laminated electrolyte membrane comprising a first layer comprising a hydrocarbon polymer electrolyte as a major component, and a second layer comprising a fluoropolymer electrolyte and polyvinylidene fluoride as major components laminated on at least one side of the first layer, wherein
the first layer and the second layer are laminated via a region in which components constituting both layers are mixed in a mixed region; and wherein
the mixed region has a thickness of 0.2 μm or more and is 80% or less of a total thickness of the first layer and the second layer.
2. The laminated electrolyte membrane according to claim 1 , further comprising a third layer comprising a fluoropolymer electrolyte as a major component laminated on a surface of the second layer opposite the first layer.
3. The laminated electrolyte membrane according to claim 2 , wherein at least one of the first layer, the second layer, and the third layer comprises platinum.
4. The laminated electrolyte membrane according to claim 1 , wherein a content of the polyvinylidene fluoride contained in the second layer is 20 to 90 mass % where a total mass of the fluoropolymer electrolyte and the polyvinylidene fluoride is 100 mass %.
5. The laminated electrolyte membrane according to claim 1 , wherein a thickness of the second layer is 40% or less of a thickness of the first layer.
6. The laminated electrolyte membrane according to claim 1 , wherein a peel strength between the first layer and the second layer is 0.3 N or more.
7. The laminated electrolyte membrane according to claim 1 , wherein the hydrocarbon polymer electrolyte comprises an ionic group-containing polyether ketone polymer as a major component.
8. A catalyst-coated laminated electrolyte membrane, comprising the laminated electrolyte membrane according to claim 1 , an anode catalyst layer on one surface of the laminated electrolyte membrane, and a cathode catalyst layer on the opposite surface of the laminated electrolyte membrane.
9. The catalyst-coated laminated electrolyte membrane according to claim 8 , wherein the second layer is laminated between the first layer and the anode catalyst layer.
10. A membrane electrode assembly in which an anode-side feeder is laminated on the anode catalyst layer of the catalyst-coated laminated electrolyte membrane according to claim 8 and a cathode-side feeder is laminated on the cathode catalyst layer.
11. The membrane electrode assembly according to claim 10 , wherein the anode-side feeder is formed of an inorganic conductive substance.
12. A water electrolysis hydrogen generator comprising the laminated electrolyte membrane according to claim 1 .
13. A water electrolysis hydrogen generator comprising the catalyst-coated laminated electrolyte membrane according to claim 8 .
14. A water electrolysis hydrogen generator comprising the membrane electrode assembly according to claim 10 .