Separator laminate for lithium secondary battery, electrode assembly including the same, and lithium secondary battery including the same
The present disclosure relates to a separator for lithium secondary battery, a method for manufacturing same, and a lithium secondary battery including the same. The separator laminate according to one embodiment of the present disclosure includes: a plurality of separators; and adhesive layers located between mutually adjacent separators among the plurality of separators, wherein the adhesive layers are formed along the edges of the mutually adjacent separators so as to have a separation space between the mutually adjacent separators.
1. A lithium secondary battery comprising:
an electrode assembly comprising a negative electrode, a positive electrode, and a separator laminate disposed between the negative electrode and the positive electrode,
wherein the separator laminate comprising: a plurality of separators; and adhesive layers disposed between adjacent separators,
wherein the adhesive layers are disposed along edges of the adjacent separators so as to have a separation space between the adjacent separators,
wherein the separation space is located at center portions of the adjacent separators and does not include a positive electrode or a negative electrode.
2. The lithium secondary battery according to claim 1 , wherein the adhesive layers are in a form of a frame in which the central portion is opened.
3. The lithium secondary battery according to claim 2 , wherein border portions of the separators adjacent to at least one of the adhesive layers are connected and fixed to each other, by at least one of the adhesive layers.
4. The lithium secondary battery according to claim 1 , wherein each of the plurality of separators comprises at least one selected from the group consisting of a single-sided SRS separator, a double-sided SRS separator, a polyolefin fabric, a free-standing organic/inorganic mixed film, and a polymer-based separator.
5. The lithium secondary battery according to claim 4 , wherein at least one of the plurality of separators comprises at least one selected from the group consisting of a single-sided SRS separator, a double-sided SRS separator, and a free-standing organic/inorganic mixed film.
6. The lithium secondary battery according to claim 1 , wherein at least one of the adhesive layers comprises one selected from the group consisting of polyvinylidene fluoride (PVdF), polytetrafluoroethylene (PTFE), styrene butadiene rubber (SBR), polyvinylidene fluoride-co-hexafluoropropylene, polyvinylidene fluoride-co-trichloroethylene, polymethylmethacrylate, polyacrylonitrile, polyvinylpyrrolidone, polyvinylacetate, polyethylene-co-vinyl acetate, polyimide, polyethylene oxide, cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, cyanoethylpullulan, cyanoethylpolyvinylalcohol, cyanoethylcellulose, cyanoethylsucrose, pullulan, carboxyl methyl cellulose, acrylonitrile-styrene-butadiene copolymer, polyimide, and polyvinylalcohol, or a mixture of two or more thereof.
7. The lithium secondary battery according to claim 1 , wherein at least one of the adhesive layers has a thickness of 0.01 μm to 100 μm.
8. The lithium secondary battery according to claim 1 , wherein
an area of the separator laminate is larger than an area of the negative electrode and an area the positive electrode and thus extended outwardly at four corners of the negative electrode and the positive electrode, and
at least one of the adhesive layers of the separator laminate is disposed at a portion not facing the negative electrode or the positive electrode along the edge of the separator included in the separator laminate.
9. The lithium secondary battery according to claim 1 , wherein
the negative electrode is a lithium metal negative electrode comprising:
a lithium-free negative electrode, which is a Li free anode, made of only a copper current collector; or
a copper current collector; and
a lithium metal layer located on the copper current collector.
10. A lithium secondary battery according to claim 1 , wherein the electrode assembly is implemented in a stack process, a lamination and stack process, a stack and folding process, a jelly-roll process, or a zigzag folding process.
11. The lithium secondary battery of claim 1 , wherein
when charging the lithium secondary battery with a constant current of 0.1° C. in a temperature range of 20 to 30° C. until reaching 4.25 V and then discharging the lithium secondary battery with a constant current of 0.5° C. until reaching 3.0 V is referred to as one charge/discharge cycle,
at the point of the time the capacity retention rate according to the following Equation 1 reaches 80%, n is 30 or more:
Capacity retention rate (%)=100*{Discharge capacity after n cycles}/{Discharge capacity after 1 cycle}. [Equation 1]
12. The lithium secondary battery according to claim 1 , wherein the separation space is 50 to 99 area % of the separator.
13. The lithium secondary battery according to claim 1 , wherein at least one of the adhesive layers has a thickness of 0.1 μm to 10 μm.
14. The lithium secondary battery according to claim 1 , wherein a shape of the separation space formed by the adhesive layers is polygonal shape.
15. The lithium secondary battery according to claim 1 , wherein a shape of the separation space formed by the adhesive layers is rectangular shape.
16. The lithium secondary battery according to claim 1 , wherein a shape of the separation space formed by the adhesive layers is circular shape.