Light emitting diode including a quantum dot complex, method of manufacturing the same and display device including the same
A light emitting element (e.g., light emitting diode) includes a first electrode, a hole transport region on the first electrode, an emission layer on the hole transport region and containing a quantum dot complex, an electron transport region on the emission layer, and a second electrode on the electron transport region, wherein the quantum dot complex contains two or more quantum dots each including a core and a shell surrounding the core, the shell of one quantum dot is combined with a shell of at least one neighboring quantum dot, and the light emitting element (e.g., light emitting diode) may thus have improved luminous efficiency and service life.
1. A light emitting diode comprising:
a first electrode;
a hole transport region on the first electrode;
an emission layer on the hole transport region and comprising a quantum dot complex;
an electron transport region on the emission layer; and
a second electrode on the electron transport region,
wherein the quantum dot complex comprises two or more quantum dots each comprising a core and a shell around the core, and
wherein, of the two or more quantum dots, a shell of one quantum dot is directly combined with a shell of at least one neighboring quantum dot without another material therebetween.
2. The light emitting diode of claim 1 , wherein
the emission layer further comprises low melting point particles, and
the low melting point particles comprise a metal and/or an alloy having a melting point of 1300° C. or less.
3. The light emitting diode of claim 2 , wherein the low melting point particles comprise at least one from among Al, Mg, Zn, Sn, Mn, Cu, and an alloy thereof.
4. The light emitting diode of claim 2 , wherein a weight ratio of the low melting point particles to the two or more quantum dots is about 1:200 to about 1:20.
5. The light emitting diode of claim 2 , wherein each of the low melting point particles has a size of 1 μm or less.
6. The light emitting diode of claim 1 , wherein the shell comprises at least one from among CdS, CdSe, CdTe, ZnS, ZnSe, ZnTe, ZnSeS, ZnTeS, GaAs, GaP, GaSb, HgS, HgSe, HgTe, InAs, InP, InGaP, InSb, AlAs, AIP, and AISb.
7. The light emitting diode of claim 1 , wherein:
the hole transport region comprises an organic material; and
the electron transport region comprises an inorganic material.
8. A display device comprising:
a plurality of light emitting diodes; and
a light conversion layer on the plurality of light emitting diodes and comprising at least one light control unit comprising a quantum dot complex,
wherein the quantum dot complex comprises two or more quantum dots each comprising a core and a shell around the core, and
wherein, of the two or more quantum dots, a shell of one quantum dot is directly combined with a shell of at least one neighboring quantum dot without another material therebetween.
9. The display device of claim 8 , wherein
the light emitting diodes are to emit a first color light, and
the light conversion layer comprises:
a transmission unit to transmit the first color light;
a first light control unit to convert the first color light into a second color light; and
a second light control unit to convert the first color light into a third color light.
10. The display device of claim 8 , wherein
the light control unit further comprises low melting point particles, and
the low melting point particles comprise a metal and/or an alloy having a melting point of 1300° C. or less.
11. The display device of claim 10 , wherein the low melting point particles comprise at least one from among Al, Mg, Zn, Sn, Mn, Cu, and an alloy thereof.
12. The display device of claim 10 , wherein each of the low melting point particles has a size of 1 μm or less.
13. The display device of claim 8 , wherein the shell comprises at least one from among CdS, CdSe, CdTe, ZnS, ZnSe, ZnTe, ZnSeS, ZnTeS, GaAs, GaP, GaSb, HgS, HgSe, HgTe, InAs, InP, InGaP, InSb, AlAs, AIP, and AISb.
14. The display device of claim 9 , further comprising a color filter layer on the light emitting diodes,
wherein the color filter layer comprises:
a first filter to transmit the first color light;
a second filter to transmit the second color light; and
a third filter to transmit the third color light.