Control rods for light water reactors
A control rod for a nuclear fuel assembly is described herein that includes a neutron absorbing material having a melting point greater than 1500° C. that does not form a eutectic with a melting point less than 1500° C., and may further include a cladding material having a melting point greater than 1500° C. The cladding material is selected from the group consisting of silicon carbide, zirconium, a zirconium alloy, tungsten, and molybdenum. The absorbing material is selected from the group consisting of Gd 2 O 3 , Ir, B 4 C, Re, and Hf. The metal cladding or the absorbing material may be coated with an anti-oxidation coating of Cr with or without a Nb intermediate layer.
1. A control rod for a nuclear fuel assembly, the control rod comprising:
a solid metal rod comprising a neutron absorbing material having a melting point greater than 1500° C., wherein the neutron absorbing material has an effective neutron absorption cross-section equal to or greater than 8 Barns; and
a coating on the solid metal rod, wherein the coating and the neutron absorbing material do not form a eutectic that has a melting point less than 1500° C., and wherein the coating comprises:
a chromium layer; and
an intermediate layer between the solid metal rod and the chromium layer, wherein the intermediate layer is in contact with an outer surface of the solid metal rod, wherein the chromium layer is in contact with an outer surface of the intermediate layer, and wherein the intermediate layer is selected from the group consisting of niobium, molybdenum, and tantalum.
2. The control rod recited in claim 1 , wherein the neutron absorbing material is selected from the group consisting of iridium and rhenium.
3. The control rod recited in claim 1 , wherein the chromium layer is an outermost surface of the control rod.
4. The control rod recited in claim 1 , wherein the intermediate layer is molybdenum.
5. The control rod recited in claim 4 , wherein the neutron absorbing material is rhenium.
6. The control rod recited in claim 4 , wherein the neutron absorbing material is iridium.
7. The control rod recited in claim 4 , wherein the neutron absorbing material is hafnium.
8. The control rod recited in claim 1 , wherein the neutron absorbing material is hafnium.