IP Library Granted Patent US 12,317,973
Granted Patent B2
US 12,317,973 · App. 17/468,926 · Granted Jun 3, 2025

Phosphorescent timepiece component

Inventors: Sophie Napoli (Neuchâtel, CH); Nicolas François (Neuchâtel, CH)
Assignee: The Swatch Group Research and Development Ltd
A44C5/00G04B19/32G04B37/22
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Quick Facts
Patent No.
US 12,317,973
App. No.
17/468,926
Granted
Jun 3, 2025
Kind
B2
Abstract

A timepiece component including a phosphorescent multilayer structure ( 3 ) comprising a front layer ( 1 ) with a transparent or translucent polymer matrix and comprising phosphorescent pigments and a reflective underlying layer ( 2 ).

Claims (25)

1. A timepiece component comprising a phosphorescent multilayer structure comprising a front layer with a transparent or translucent polymer matrix comprising an elastomer matrix, and comprising phosphorescent pigments and a reflective underlying layer,

wherein at least some of the phosphorescent pigments are on an outermost side of the timepiece component, the outermost side facing away from the reflective underlying layer,

wherein the timepiece component forms a watch bracelet,

wherein the front layer is arranged along an entire length of the bracelet, and

wherein the phosphorescent pigments are evenly distributed throughout the front layer.

2. The timepiece component according to claim 1 , wherein the underlying layer comprises a polymer matrix charged with a reflective pigment.

3. The timepiece component according to claim 2 wherein the reflective pigment comprises titanium oxide.

4. The timepiece component according to claim 2 , wherein the polymer matrix of the underlying layer is compatible with the polymer matrix of the front layer.

5. The timepiece component according to claim 4 , wherein the front layer and the underlying layer comprise a fluoroelastomer.

6. The timepiece component according to claim 1 , wherein the front layer has a thickness comprised between 0.03 mm and 1 mm.

7. The timepiece component according to claim 1 , wherein the elastomer matrix includes a material having an elastic modulus less than 100 MPa.

8. The timepiece component according to claim 1 , wherein the front layer and the reflective underlying layer adhere to each other without using an adhesive.

9. A timepiece component comprising a phosphorescent multilayer structure ( 3 ) comprising a front layer ( 1 ) with a transparent or translucent polymer matrix and comprising phosphorescent pigments and a reflective underlying layer ( 2 ),

wherein the front layer ( 1 ) comprises an elastomer matrix, and

wherein the underlying layer ( 2 ) comprises a polymer matrix charged with a reflective pigment.

10. A timepiece component comprising a phosphorescent multilayer structure comprising a front layer with a transparent or translucent polymer matrix comprising an elastomer matrix, and comprising phosphorescent pigments and a reflective underlying layer,

wherein at least some of the phosphorescent pigments are on an outermost side of the timepiece component, the outermost side facing away from the reflective underlying layer,

wherein the front layer and the underlying layer comprise a fluoroelastomers,

wherein the underlying layer comprises a polymer matrix charged with a reflective pigment, and the reflective pigment comprises titanium oxide,

wherein the timepiece component forms a watch bracelet,

wherein the polymer matrix of the underlying layer is compatible with the polymer matrix of the front layer,

wherein the front layer is arranged along an entire length of the bracelet,

wherein the phosphorescent pigments are evenly distributed throughout the front layer,

wherein the front layer has a thickness comprised between 0.03 mm and 1 mm, and

wherein the elastomer matrix includes a material having an elastic modulus less than 100 MPa.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 8, 2021
From: NAPOLI, SOPHIE; FRANÇOIS, NICOLAS
To: THE SWATCH GROUP RESEARCH AND DEVELOPMENT LTD
Reel/Frame 057437/0534 →
Priority Claims (1)
EP 20213368 · Dec 11, 2020 · regional
Continuity (1)
Related Publication 20220183426A1 · Jun 16, 2022
References Cited (33)
US 5698301A · Yonetani · 1997 [cited by examiner]
US 6692432B1 · Yarush · 2004 [cited by examiner]
US 7070843B2 · Bartek · 2006 [cited by examiner]
US 8570149B2 · Rowe · 2013 [cited by examiner]
US 9193209B2 · Dooley · 2015 [cited by examiner]
US 10101009B1 · Martin · 2018 [cited by examiner]
US 20020019312A1 · Ramsden · 2002 [cited by examiner]
US 20030016315A1 · Ueno · 2003 [cited by examiner]
US 20040043248A1 · Bharti · 2004 [cited by examiner]
US 20170086536A1 · de Iuliis et al. · 2017 [cited by examiner]
US 20170162074A1 · Cheatham · 2017 [cited by examiner]
US 20180095427A1 · Francois · 2018 [cited by examiner]
US 20190283309A1 · Kato et al. · 2019 [cited by applicant]
US 20200197755A1 · Gallucci · 2020 [cited by examiner]
US 20210088973A1 · Francois · 2021 [cited by examiner]
CH 716226B1 · 2020 [cited by applicant]
CN 1125172A · 1996 [cited by applicant]
CN 107918271A · 2018 [cited by applicant]
EP 3306419A1 · 2018 [cited by applicant]
EP 3796105A1 · 2021 [cited by applicant]
FR 2979571A1 · 2013 [cited by applicant]
JP 07265111A · 1995 [cited by applicant]
JP 1039050A · 1998 [cited by applicant]
JP 200124343A · 2001 [cited by applicant]
JP 2003304913A · 2003 [cited by applicant]
JP 3185348U · 2013 [cited by applicant]
JP 2019162202A · 2019 [cited by applicant]
WO 2010063945A1 · 2010 [cited by applicant]
WO 2019115249A1 · 2019 [cited by applicant]
Excerpt from Britannica.com entry “Fluoroelastomer” (captured by Internet Achive on Apr. 15, 2019) (Year: 2019). [cited by examiner]
Excerpt form Wikipedia article “Thermoplastic Polyurethane”, captured by the Internet Archive Mar. 1, 2019 (Year: 2019). [cited by examiner]
Jinzhu Tan, Y.J. Chao, J.W. Van Zee, Xiaodong Li, Xinnan Wang, Min Yang, “Assessment of mechanical properties of fluoroelastomer and EPDM in a simulated PEM fuel cell environment by microindentation test”, Materials Sci… [cited by examiner]
European Search Report for EP 20 21 3368, dated May 27, 2021. [cited by applicant]